A dilatometer is a scientific instrument that measures volume changes caused by a physical or chemical process. A familiar application of a dilatometer is the mercury-in-glass thermometer, in which the change in volume of the liquid column is read from a graduated scale. Because mercury has a fairly constant rate of expansion over ambient temperature ranges, the volume changes are directly related to temperature.
Dilatometers have been used in the fabrication of metallic alloys, study of martensite transformation, compressed and sintered refractory compounds, glasses, ceramic products, composite materials, and plastics. [1]
Dilatometry is also used to monitor the progress of chemical reactions, particularly those displaying a substantial molar volume change (e.g., polymerisation). A specific example is the rate of phase changes. [2]
In food science, dilatometers are used to measure the solid fat index of food oils and butter. [3]
Another common application of a dilatometer is the measurement of thermal expansion. Thermal expansivity is an important engineering parameter, and is defined as:
There are a number of dilatometer types:
For simpler measurements in a temperature range from 0 to 100 °C, where water is heated up and flow or over the sample. If linear coefficients of expansion of a metal is to be measured, hot water will run through a pipe made from the metal. The pipe warms up to the temperature of the water and the relative expansion can be determined as a function of the water temperature.
For the measurement of the volumetric expansion of liquids one takes a large glass container filled with water. In an expansion tank (glass container with an accurate volume scale) with the sample liquid. If one heats the water up, the sample liquid expands and the volume changes is read. However the expansion of the sample container must also be taken into consideration.
The expansion and retraction coefficient of gases cannot be measured using dilatometer, since the pressure plays a role here. For such measurements a gas thermometer is more suitable.
Dilatometers often include a mechanism for controlling temperature. This may be a furnace for measurements at elevated temperatures (temperatures to 2000 °C), or a cryostat for measurements at temperatures below room temperature. Metallurgical applications often involve sophisticated temperature controls capable of applying precise temperature-time profiles for heating and quenching the sample. [9]
Pressure measurement is the measurement of an applied force by a fluid on a surface. Pressure is typically measured in units of force per unit of surface area. Many techniques have been developed for the measurement of pressure and vacuum. Instruments used to measure and display pressure mechanically are called pressure gauges,vacuum gauges or compound gauges. The widely used Bourdon gauge is a mechanical device, which both measures and indicates and is probably the best known type of gauge.
A thermometer is a device that measures temperature or a temperature gradient. A thermometer has two important elements: (1) a temperature sensor in which some change occurs with a change in temperature; and (2) some means of converting this change into a numerical value. Thermometers are widely used in technology and industry to monitor processes, in meteorology, in medicine, and in scientific research.
The melting point of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa.
Laboratory glassware refers to a variety of equipment used in scientific work, and traditionally made of glass. Glass can be blown, bent, cut, molded, and formed into many sizes and shapes, and is therefore common in chemistry, biology, and analytical laboratories. Many laboratories have training programs to demonstrate how glassware is used and to alert first–time users to the safety hazards involved with using glassware.
A calorimeter is an object used for calorimetry, or the process of measuring the heat of chemical reactions or physical changes as well as heat capacity. Differential scanning calorimeters, isothermal micro calorimeters, titration calorimeters and accelerated rate calorimeters are among the most common types. A simple calorimeter just consists of a thermometer attached to a metal container full of water suspended above a combustion chamber. It is one of the measurement devices used in the study of thermodynamics, chemistry, and biochemistry.
Differential scanning calorimetry (DSC) is a thermoanalytical technique in which the difference in the amount of heat required to increase the temperature of a sample and reference is measured as a function of temperature. Both the sample and reference are maintained at nearly the same temperature throughout the experiment. Generally, the temperature program for a DSC analysis is designed such that the sample holder temperature increases linearly as a function of time. The reference sample should have a well-defined heat capacity over the range of temperatures to be scanned.
Sintering or frittage is the process of compacting and forming a solid mass of material by heat or pressure without melting it to the point of liquefaction.
Flow measurement is the quantification of bulk fluid movement. Flow can be measured in a variety of ways. The common types of flowmeters with industrial applications are listed below:
Thermal analysis is a branch of materials science where the properties of materials are studied as they change with temperature. Several methods are commonly used – these are distinguished from one another by the property which is measured:
A hygrometer is an instrument used to measure the amount of water vapor in air, in soil, or in confined spaces. Humidity measurement instruments usually rely on measurements of some other quantities such as temperature, pressure, mass, a mechanical or electrical change in a substance as moisture is absorbed. By calibration and calculation, these measured quantities can lead to a measurement of humidity. Modern electronic devices use temperature of condensation, or changes in electrical capacitance or resistance to measure humidity differences. A crude hygrometer was invented by Leonardo da Vinci in 1480. Major leaps came forward during the 1600s; Francesco Folli invented a more practical version of the device, while Robert Hooke improved a number of meteorological devices including the hygrometer. A more modern version was created by Swiss polymath Johann Heinrich Lambert in 1755. Later, in the year 1783, Swiss physicist and Geologist Horace Bénédict de Saussure invented the first hygrometer using human hair to measure humidity.
Absorption spectroscopy refers to spectroscopic techniques that measure the absorption of radiation, as a function of frequency or wavelength, due to its interaction with a sample. The sample absorbs energy, i.e., photons, from the radiating field. The intensity of the absorption varies as a function of frequency, and this variation is the absorption spectrum. Absorption spectroscopy is performed across the electromagnetic spectrum.
Many ceramic materials, both glassy and crystalline, have found use as optically transparent materials in various forms from bulk solid-state components to high surface area forms such as thin films, coatings, and fibers. Such devices have found widespread use for various applications in the electro-optical field including: optical fibers for guided lightwave transmission, optical switches, laser amplifiers and lenses, hosts for solid-state lasers and optical window materials for gas lasers, and infrared (IR) heat seeking devices for missile guidance systems and IR night vision.
Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions.
Temperature measurement describes the process of measuring a current local temperature for immediate or later evaluation. Datasets consisting of repeated standardized measurements can be used to assess temperature trends.
A thermodynamic instrument is any device which facilitates the quantitative measurement of thermodynamic systems. In order for a thermodynamic parameter to be truly defined, a technique for its measurement must be specified. For example, the ultimate definition of temperature is "what a thermometer reads". The question follows – what is a thermometer?
Level sensors detect the level of liquids and other fluids and fluidized solids, including slurries, granular materials, and powders that exhibit an upper free surface. Substances that flow become essentially horizontal in their containers because of gravity whereas most bulk solids pile at an angle of repose to a peak. The substance to be measured can be inside a container or can be in its natural form. The level measurement can be either continuous or point values. Continuous level sensors measure level within a specified range and determine the exact amount of substance in a certain place, while point-level sensors only indicate whether the substance is above or below the sensing point. Generally the latter detect levels that are excessively high or low.
An optical dilatometer is a non-contact device able to measure thermal expansions or sintering kinetics of any kind of materials, unlike traditional push rod dilatometer, it can push up to the dilatometric softening of the specimen. It is a device for measuring changes in the dimensions of a specimen, optically, the achieved resolution can result in greater values than those of a conventional pushrod dilatometer. A monochromatic light source, such as a laser, illuminates the specimen. Some of the light is reflected by the specimen and interferes with the incoming light, creating optical interference fringes. As the specimen contracts or expands, there is a proportional movement of the interference fringes, which can be measured using a camera system. The measurement resolution is determined by the wavelength of the light, and is typically 0.5 μm for blue light. Optical dilatometers are used to measure thermal expansion.
Fourier-transform infrared spectroscopy (FTIR) is a technique used to obtain an infrared spectrum of absorption or emission of a solid, liquid, or gas. An FTIR spectrometer simultaneously collects high-resolution spectral data over a wide spectral range. This confers a significant advantage over a dispersive spectrometer, which measures intensity over a narrow range of wavelengths at a time.
A measuring instrument is a device to measure a physical quantity. In the physical sciences, quality assurance, and engineering, measurement is the activity of obtaining and comparing physical quantities of real-world objects and events. Established standard objects and events are used as units, and the process of measurement gives a number relating the item under study and the referenced unit of measurement. Measuring instruments, and formal test methods which define the instrument's use, are the means by which these relations of numbers are obtained. All measuring instruments are subject to varying degrees of instrument error and measurement uncertainty. These instruments may range from simple objects such as rulers and stopwatches to electron microscopes and particle accelerators. Virtual instrumentation is widely used in the development of modern measuring instruments.
Photopyroelectric As known that Photopyroelectric can be regarded as –Photo +Pyroelectric，which means any optical systems using a pyroelectric detector or imaging system, In addition, pyroelectricity could be depicted as the capability of the components formulating the transient voltage when heated or cooled. Once the temperature on which they depend changes, the position of the atom will change slightly in the crystal structure. This process of change can also be referred to as the polarization of the material. As a result, the voltage across the crystal will be triggered by this change in polarization. To further explain, when the temperature in the engine is kept constant for a period of time, the voltage in the photovoltage will gradually disappear due to the leakage current. In this sense, leakage is mainly caused by several ways, for example, electrons going through the crystal, ions going through the air, or current leaking through a voltmeter connected to the crystal.
