Dithiole

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1,2-dithiole.svg
1,3-dithiole.svg
Chemical structures of 1,2-dithiole (left) and 1,3-dithole (right)

Dithioles are a type of sulfur-containing heterocycle. The parent members have the formula C3H4S2. Dithioles exist in two isomers:

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1,2-Dithiole chemical compound

In organosulfur chemistry, a 1,2-dithiole is a type of heterocycle. The parent of this class of compounds is 1,2-dithiacyclopentene. The anticancer drug oltipraz is a dithiole.

The molecular formula C3H4S2 may refer to:

Dithiolium salt

Dithiolium salts are compounds of the formula [(RC)3S2]+X (R = H, alkyl, aryl, etc). These salts consist of a planar organic cation with a variety of anions such as halides. The five-membered ring cations are observed in either of two isomers, 1,2- and 1,3-dithiolium cations. These cations differ with respect to the relative positions of the pair of sulfur atoms. Both isomers feature a planar ring, which is aromatic owing to the presence of 6π electrons. For example, the 1,2-ditholium ring can be represented as an allyl cation of the three carbons, with each sulfur atom donating one of its lone pairs of electrons to give a total of three pairs.

Sodium 1,3-dithiole-2-thione-4,5-dithiolate chemical compound

Sodium 1,3-dithiole-2-thione-4,5-dithiolate is the organosulfur compound with the formula Na2C3S5, abbreviated Na2dmit. It is the sodium salt of the conjugate base of the 1,3-dithiole-2-thione-4,5-dithiol. The salt is a precursor to dithiolene complexes and tetrathiafulvalenes.

In organosulfur chemistry, a 1,3-dithiole is a type of heterocycle. The parent of this class of compounds is 1,3-dithiacyclopentene. The ligand dmit2- is a 1,3-dithiole. Heating solutions of Na2dmit gives the isomeric disulfide, a 1,2-dithiole.

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