Dropwise condensation

Last updated

In dropwise condensation the condensate liquid collects in the form of countless droplets of varying diameters on the condensing surface, instead of forming a continuous film, and does not wet the solid cooling surface. The droplets develop at points of surface imperfections (pit, scratch), called nucleation sites, and grow in size as more vapour condenses on its exposed surface. When the size of droplets is large there comes a time the droplet breakaway from the surface and knock off other droplets and carries it downstream. The moving droplet devours the droplets of smaller size. Dropwise condensation is one of the most effective mechanism of heat transfer and extremely large heat transfer coefficients can be achieved with this mechanism. In dropwise condensation, there is no liquid film to resist heat transfer, and as a result heat transfer coefficients can be achieved more than 10 times larger than those associated with film condensation, although 3-5 times is more common. Heat transfer coefficients are large so designers can achieve a specified heat transfer rate with a smaller surface area and thus a smaller and less expensive condenser.

Dropwise condensation is achieved by adding a promoter chemical into the vapor, and/or roughened surfaces and surface and surface coated with hydrophobic impurities like fatty acids and organic compounds, known as dropwise promoters. Dropwise condensation is provoked artificially with the help of silicons, teflon, assortment of waxes, and fatty acids. These promoters are used to promote dropwise condensation but most promoters are highly unstable and lose their effectiveness with time due to oxidation, fouling and removal of the promoter from the surface. Dropwise condensation can be sustained for a long time by the combined effects of surface coating and periodic injection of the promoter into the vapor. When dropwise surfaces degrade, they convert to filmwise condensation. So most condensers are designed on the assumption that film condensation will take place on the surface eventually. Dropwise condensation is useful in powerplant heat exchangers, thermal desalination, self-cleaning surfaces, and heating and air conditioning.

The total amount of heat transfer through a single droplet is a function of its radius and the size distribution over the condensation surface. The important factors which are involved in the mechanism of heat transfer through a single droplets are:

  1. Thermal conduction through a single droplet
  2. Thermal conduction in the substrate material
  3. Interphase matter transfer at the vapour liquid interface
  4. Curvature of the vapour-liquid interface

Related Research Articles

<span class="mw-page-title-main">Evaporation</span> Type of vaporization of a liquid that occurs from its surface; surface phenomenon

Evaporation is a type of vaporization that occurs on the surface of a liquid as it changes into the gas phase. High concentration of the evaporating substance in the surrounding gas significantly slows down evaporation, such as when humidity affects rate of evaporation of water. When the molecules of the liquid collide, they transfer energy to each other based on how they collide. When a molecule near the surface absorbs enough energy to overcome the vapor pressure, it will escape and enter the surrounding air as a gas. When evaporation occurs, the energy removed from the vaporized liquid will reduce the temperature of the liquid, resulting in evaporative cooling.

<span class="mw-page-title-main">Condensation</span> Condensation is the change of state of matter from a gas phase into a liquid phase.

Condensation is the change of the state of matter from the gas phase into the liquid phase, and is the reverse of vaporization. The word most often refers to the water cycle. It can also be defined as the change in the state of water vapor to liquid water when in contact with a liquid or solid surface or cloud condensation nuclei within the atmosphere. When the transition happens from the gaseous phase into the solid phase directly, the change is called deposition.

<span class="mw-page-title-main">Humidity</span> Concentration of water vapour in the air

Humidity is the concentration of water vapor present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. Humidity indicates the likelihood for precipitation, dew, or fog to be present.

<span class="mw-page-title-main">Water vapor</span> Gaseous phase of water

Water vapor, water vapour or aqueous vapor is the gaseous phase of water. It is one state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from the sublimation of ice. Water vapor is transparent, like most constituents of the atmosphere. Under typical atmospheric conditions, water vapor is continuously generated by evaporation and removed by condensation. It is less dense than most of the other constituents of air and triggers convection currents that can lead to clouds and fog.

<span class="mw-page-title-main">Leidenfrost effect</span> Physical phenomenon

The Leidenfrost effect is a physical phenomenon in which a liquid, close to a surface that is significantly hotter than the liquid's boiling point, produces an insulating vapor layer that keeps the liquid from boiling rapidly. Because of this repulsive force, a droplet hovers over the surface, rather than making physical contact with it. The effect is named after the German doctor Johann Gottlob Leidenfrost, who described it in A Tract About Some Qualities of Common Water.

<span class="mw-page-title-main">Heat transfer</span> Transport of thermal energy in physical systems

Heat transfer is a discipline of thermal engineering that concerns the generation, use, conversion, and exchange of thermal energy (heat) between physical systems. Heat transfer is classified into various mechanisms, such as thermal conduction, thermal convection, thermal radiation, and transfer of energy by phase changes. Engineers also consider the transfer of mass of differing chemical species, either cold or hot, to achieve heat transfer. While these mechanisms have distinct characteristics, they often occur simultaneously in the same system.

<span class="mw-page-title-main">Dehumidifier</span> Device which reduces humidity

A dehumidifier is an air conditioning device which reduces and maintains the level of humidity in the air. This is done usually for health or thermal comfort reasons, or to eliminate musty odor and to prevent the growth of mildew by extracting water from the air. It can be used for household, commercial, or industrial applications. Large dehumidifiers are used in commercial buildings such as indoor ice rinks and swimming pools, as well as manufacturing plants or storage warehouses. Typical air conditioning systems combine dehumidification with cooling, by operating cooling coils below the dewpoint and draining away the water that condenses.

<span class="mw-page-title-main">Heat pipe</span> Heat-transfer device that employs phase transition

A heat pipe is a heat-transfer device that employs phase transition to transfer heat between two solid interfaces.

<span class="mw-page-title-main">Chiller</span> Machine that removes heat from a liquid coolant via vapor compression

A chiller is a machine that removes heat from a liquid coolant via a vapor-compression, adsorption refrigeration, or absorption refrigeration cycles. This liquid can then be circulated through a heat exchanger to cool equipment, or another process stream. As a necessary by-product, refrigeration creates waste heat that must be exhausted to ambience, or for greater efficiency, recovered for heating purposes. Vapor compression chillers may use any of a number of different types of compressors. Most common today are the hermetic scroll, semi-hermetic screw, or centrifugal compressors. The condensing side of the chiller can be either air or water cooled. Even when liquid cooled, the chiller is often cooled by an induced or forced draft cooling tower. Absorption and adsorption chillers require a heat source to function.

<span class="mw-page-title-main">Reflow oven</span>

A reflow oven is a machine used primarily for reflow soldering of surface mount electronic components to printed circuit boards (PCBs).

<span class="mw-page-title-main">Superheated steam</span> Steam whose temperature can be decreased without immediately condensing

Superheated steam is steam at a temperature higher than its vaporization point at the absolute pressure where the temperature is measured.

<span class="mw-page-title-main">Ultrahydrophobicity</span> Material property of extreme resistance to wetting

In chemistry and materials science, ultrahydrophobic surfaces are highly hydrophobic, i.e., extremely difficult to wet. The contact angles of a water droplet on an ultrahydrophobic material exceed 150°. This is also referred to as the lotus effect, after the superhydrophobic leaves of the lotus plant. A droplet striking these kinds of surfaces can fully rebound like an elastic ball. Interactions of bouncing drops can be further reduced using special superhydrophobic surfaces that promote symmetry breaking, pancake bouncing or waterbowl bouncing.

<span class="mw-page-title-main">Steam-electric power station</span>

The steam-electric power station is a power station in which the electric generator is steam driven. Water is heated, turns into steam and spins a steam turbine which drives an electrical generator. After it passes through the turbine, the steam is condensed in a condenser. The greatest variation in the design of steam-electric power plants is due to the different fuel sources.

<span class="mw-page-title-main">Evaporator</span> Machine transforming a liquid into a gas

An evaporator is a type of heat exchanger device that facilitates evaporation by utilizing conductive and convective heat transfer to provide the necessary thermal energy for phase transition from liquid to vapor. Within evaporators, a circulating liquid is exposed to an atmospheric or reduced pressure environment, causing it to boil at a lower temperature compared to normal atmospheric boiling.

<span class="mw-page-title-main">Condenser (laboratory)</span> Laboratory apparatus used to condense vapors

In chemistry, a condenser is laboratory apparatus used to condense vapors – that is, turn them into liquids – by cooling them down.

<span class="mw-page-title-main">Condenser (heat transfer)</span> System for condensing gas into liquid by cooling

In systems involving heat transfer, a condenser is a heat exchanger used to condense a gaseous substance into a liquid state through cooling. In so doing, the latent heat is released by the substance and transferred to the surrounding environment. Condensers are used for efficient heat rejection in many industrial systems. Condensers can be made according to numerous designs and come in many sizes ranging from rather small (hand-held) to very large. For example, a refrigerator uses a condenser to get rid of heat extracted from the interior of the unit to the outside air.

Membrane distillation (MD) is a thermally driven separation process in which separation is driven by phase change. A hydrophobic membrane presents a barrier for the liquid phase, allowing the vapour phase to pass through the membrane's pores. The driving force of the process is a partial vapour pressure difference commonly triggered by a temperature difference.

A climbing/falling film plate evaporator is a specialized type of evaporator in which a thin film of liquid is passed over a rising and falling plate to allow the evaporation process to occur. It is an extension of the falling film evaporator, and has application in any field where the liquid to be evaporated cannot withstand extended exposure to high temperatures, such as the concentration of fruit juices.

A rising film or vertical long tube evaporator is a type of evaporator that is essentially a vertical shell and tube heat exchanger. The liquid being evaporated is fed from the bottom into long tubes and heated with steam condensing on the outside of the tube from the shell side. This is to produce steam and vapour within the tube bringing the liquid inside to a boil. The vapour produced then presses the liquid against the walls of the tubes and causes the ascending force of this liquid. As more vapour is formed, the centre of the tube will have a higher velocity which forces the remaining liquid against the tube wall forming a thin film which moves upwards. This phenomenon of the rising film gives the evaporator its name.

The low-temperature distillation (LTD) technology is the first implementation of the direct spray distillation (DSD) process. The first large-scale units are now in operation for desalination. The process was first developed by scientists at the University of Applied Sciences in Switzerland, focusing on low-temperature distillation in vacuum conditions, from 2000 to 2005.

References