Electro Thermal Dynamic Stripping Process (ET-DSP) is a patented in situ thermal environmental remediation technology, created by McMillan-McGee Corporation, for cleaning contaminated sites. ET-DSP uses readily available three phase electric power to heat the subsurface with electrodes. Electrodes are placed at various depths and locations in the formation. Electric current to each electrode is controlled continuously by computer to uniformly heat the target contamination zone. [2]
The difference between Electrical Resistance Heating (ERH) and ET-DSP is heat transfer due to convection. Water injected around the ET-DSP electrodes is heated and flows radially toward the vacuum extraction wells heating the formation in the process. The difference between ERH and ET-DSP is shown in the governing equations.
The governing equation for electrical resistance heating (ERH) is given by,
where is the bulk heat capacity of the formation, T is the temperature, t is the time, is the thermal conductivity, is the electrical conductivity, I is the electric current and L is the electrode length.
The governing equation for Electro Thermal Dynamic Stripping Process (ET-DSP) is given by,
where is the density of water, is the specific heat of water and Q is the water injection rate.
ET-DSP electrodes are placed into the contaminated zone and are designed so that conventional three-phase power can be used to heat the soil. The distance between electrodes and their location is determined from the heat transfer mechanisms associated with vapor extraction, electrical heating, and fluid movement in the contaminated zone.
To determine the ideal pattern of electrode and extraction wells, a multi-phase, multi-component, 3-D thermal model is used to simulate the process. Numerical modeling is also used to design the power delivery system (PDS), the power requirements from the utility and the project capital requirements.
Electrical heating increases the temperature of the soil and groundwater by conducting current through the resistive connate water that fills the porosity of the soil. The increase in temperature raises the vapor pressure of volatile and semi-volatile contaminants, increasing their ability to volatilize and be recovered through conventional techniques such as soil vapor extraction.
ET-DSP utilizes a system of Time-Distributed Control (TDC) and Inter-Phase Synchronization (IPS) to control the power to the electrodes. This process controls the amount and timing of power sent to individual electrodes. If electrodes are in electrically resistive zones resulting in cold spots, the power to the electrodes can be increased in these areas to uniformly heat the formation. TDC and IPS controls the electrical sine wave of three-phase power to the millisecond such that each phase can be individually manipulated.
Prior to the implementation of the ET-DSP, site information such as surface infrastructure, surrounding land uses, short term site usage during remediation, subsurface lithology, depth to groundwater, plume characterization, type of contaminant, distribution of the contaminant and required time to attain target temperatures is collected. Numerical modeling and analysis simulation software combined with bench-scale experiments are used to determine the optimal thermal remediation strategy for the site.
Numerical modeling is important to determine optimum electrode configuration in terms of pattern type, shape, and separation; power supply requirements; power synchronization; optimal target temperature; and estimated time to attain the targeted temperature.
The power delivery system (PDS) is a computer controlled three-phase current transformer. The PDS can come in a range of KVA (kilovolt amp) ratings and are fully modular for plug and play applications. Each PDS is equipped with voltage tap settings that allow the voltage to be increased to the electrodes in formations with varying resistivity. ET-DSP can heat soil matrixes that range from tight clays to sands and rock.
Electrodes for ET-DSP can be made in diameters up to 12”, lengths up to 10 feet long and are rated for up to 180 °C (356 °F) at more than 50 kW.
Using three phase power synchronization means that electrode patterns are not geometrically limited. The electrode assembly does not overheat the adjacent soils due to an imbedded water circulation system (cooling system) inside each electrode.
Electrodes are fabricated from high temperature resistant materials and are connected to the PDS. Each electrode is installed in a borehole packed with granular graphite which is compressed to the surface of the electrode. Conductors are run from each electrode back to the PDS and can be installed either above or below grade.
The water circulation system (WCS) provides water to the electrodes for the heat transfer due to convection and also cooling. The majority of the electrode’s energy is concentrated at the ends due to the current density. By injecting water at the ends, the water is heated to steam temperatures and is transported throughout the targeted volume. This process dynamically strips more slightly volatile organic compounds (SVOCs) and other non-volatile contaminants such as creosote.
Water is distributed down the inside plumbing of the electrode, exiting the electrode through slots near the base and then washes over the outer surface of the metal. Some of the water is transported out into the subsurface soils to maintain the current pathway. The rest re-enters the electrode through upper slots and is then re-circulated back to the water holding tank.
The amount of water that is directed into the formation is dependent on the permeability of the subsurface soils. Typical injection rates into the formation are usually on the order of 0.1 to 0.2 gpm (gallon per minute) per electrode.
Typically, high vacuum systems like liquid ring pumps, rotary positive blowers, and rotary vane blowers are utilized for the extraction systems. Extraction systems must be capable of handling water (multi-phase extraction) during the extraction process.
Heating can be conducted at and below the groundwater table, and larger quantities of groundwater are extracted and treated through the system. The extraction system is connected to the header and set up to extract both groundwater and hydrocarbon vapors from the subsurface within the electrode array. All recovered groundwater is transferred into the treatment system and then discharged. Contaminant vapors can be discharged into the ambient air or combusted, dependent on local regulatory requirements.
Extraction wells are placed within the electrode array in order to maximize the recovery of the volatilizing hydrocarbons and are designed to control the groundwater to minimize the potential for offsite migration of the mobilized contaminant. Extraction wells are connected to an extraction header pipe, which is connected to the extraction system. Depending on the contaminant of concern either steel or an approved thermoplastic can be used in the header system.
Groundwater treatment systems remove dissolved contaminants and sediment from the groundwater. The treatment system typically consists of a sedimentation tank and an air stripper or granular activated carbon. Groundwater is transferred from the extraction system into the treatment system where the sediment and the dissolved-phase contaminants are removed. The clean effluent water is then discharged or removed by an approved method.
The Electro Thermal Dynamic Stripping Process (ET-DSP) is currently being used in the Athabasca Oil Sands to thermally recover bitumen and heavy oil by E-T Energy Limited. This electrothermal process converts electromagnetic energy into thermal energy by inducing current through the formation using excitor electrodes. Considerable control can be effected over the path taken by the currents and over the temperature profiles that will develop in the deposit by varying the operating frequency and excitor spacing. [3] Electrothermal processes are virtually free of problems related to very low initial formation injectivity, poor heat transfer and the near impossibility of adequately controlling the movement of injected fluids and gases. [3]
The thermal conductivity of a material is a measure of its ability to conduct heat. It is commonly denoted by , , or .
In fluid mechanics, the Rayleigh number (Ra) for a fluid is a dimensionless number associated with buoyancy-driven flow, also known as free or natural convection. It characterises the fluid's flow regime: a value in a certain lower range denotes laminar flow; a value in a higher range, turbulent flow. Below a certain critical value, there is no fluid motion and heat transfer is by conduction rather than convection.
In electronics and electromagnetism, the electrical resistance of an object is a measure of its opposition to the flow of electric current. The reciprocal quantity is electrical conductance, and is the ease with which an electric current passes. Electrical resistance shares some conceptual parallels with the notion of mechanical friction. The SI unit of electrical resistance is the ohm, while electrical conductance is measured in siemens (S).
A heat pump is a device that transfers heat energy from a source of heat to what is called a thermal reservoir. Heat pumps move thermal energy in the opposite direction of spontaneous heat transfer, by absorbing heat from a cold space and releasing it to a warmer one. A heat pump uses external power to accomplish the work of transferring energy from the heat source to the heat sink. The most common design of a heat pump involves four main components – a condenser, an expansion valve, an evaporator and a compressor. The heat transfer medium circulated through these components is called refrigerant.
Thermal conduction is the transfer of internal energy by microscopic collisions of particles and movement of electrons within a body. The colliding particles, which include molecules, atoms and electrons, transfer disorganized microscopic kinetic and potential energy, jointly known as internal energy. Conduction takes place in all phases: solid, liquid, and gas. The rate at which energy is conducted as the heat between two bodies depends on the temperature difference between the two bodies and the properties of the conductive interface through which the heat is transferred.
Environmental remediation deals with the removal of pollution or contaminants from environmental media such as soil, groundwater, sediment, or surface water. Remedial action is generally subject to an array of regulatory requirements, and may also be based on assessments of human health and ecological risks where no legislative standards exist, or where standards are advisory.
Joule heating, also known as resistive, resistance, or Ohmic heating, is the process by which the passage of an electric current through a conductor produces heat.
A temperature coefficient describes the relative change of a physical property that is associated with a given change in temperature. For a property R that changes when the temperature changes by dT, the temperature coefficient α is defined by the following equation:
In thermodynamics, the thermal efficiency is a dimensionless performance measure of a device that uses thermal energy, such as an internal combustion engine, a steam turbine or a steam engine, a boiler, furnace, or a refrigerator for example. For a heat engine, thermal efficiency is the fraction of the energy added by heat that is converted to net work output. In the case of a refrigeration or heat pump cycle, thermal efficiency is the ratio of net heat output for heating, or removal for cooling, to energy input.
Soil vapor extraction (SVE) is a physical treatment process for in situ remediation of volatile contaminants in vadose zone (unsaturated) soils. SVE is based on mass transfer of contaminant from the solid (sorbed) and liquid phases into the gas phase, with subsequent collection of the gas phase contamination at extraction wells. Extracted contaminant mass in the gas phase is treated in aboveground systems. In essence, SVE is the vadose zone equivalent of the pump-and-treat technology for groundwater remediation. SVE is particularly amenable to contaminants with higher Henry’s Law constants, including various chlorinated solvents and hydrocarbons. SVE is a well-demonstrated, mature remediation technology and has been identified by the U.S. Environmental Protection Agency (EPA) as presumptive remedy.
HydroGeoSphere (HGS) is a 3D control-volume finite element groundwater model, and is based on a rigorous conceptualization of the hydrologic system consisting of surface and subsurface flow regimes. The model is designed to take into account all key components of the hydrologic cycle. For each time step, the model solves surface and subsurface flow, solute and energy transport equations simultaneously, and provides a complete water and solute balance.
A thermal blanket is a device used in thermal desorption to clean soil contamination. The primary function of a thermal blanket is to heat the soil to the boiling point of the contaminants so that they break down. A vacuum pulls the resulting gas into a separate air cleaner that may use various methods, such as carbon filters and high-heat ovens, to completely destroy the contaminants. Aside from evaporation and volatilization, the contaminants may also be removed from the soil through other mechanisms such as steam distillation, pyrolysis, oxidation, and other chemical reactions.
Electrical resistance heating (ERH) is an intensive in situ environmental remediation method that uses the flow of alternating current electricity to heat soil and groundwater and evaporate contaminants. Electric current is passed through a targeted soil volume between subsurface electrode elements. The resistance to electrical flow that exists in the soil causes the formation of heat; resulting in an increase in temperature until the boiling point of water at depth is reached. After reaching this temperature, further energy input causes a phase change, forming steam and removing volatile contaminants. ERH is typically more cost effective when used for treating contaminant source areas.
A solid oxide electrolyzer cell (SOEC) is a solid oxide fuel cell that runs in regenerative mode to achieve the electrolysis of water by using a solid oxide, or ceramic, electrolyte to produce hydrogen gas and oxygen. The production of pure hydrogen is compelling because it is a clean fuel that can be stored easily, thus making it a potential alternative to batteries, which have a low storage capacity and create high amounts of waste materials. Electrolysis is currently the most promising method of hydrogen production from water due to high efficiency of conversion and relatively low required energy input when compared to thermochemical and photocatalytic methods.
The heat dissipation in integrated circuits problem has gained an increasing interest in recent years due to the miniaturization of semiconductor devices. The temperature increase becomes relevant for cases of relatively small-cross-sections wires, because such temperature increase may affect the normal behavior of semiconductor devices.
The vaporizing droplet problem is a challenging issue in fluid dynamics. It is part of many engineering situations involving the transport and computation of sprays: fuel injection, spray painting, aerosol spray, flashing releases… In most of these engineering situations there is a relative motion between the droplet and the surrounding gas. The gas flow over the droplet has many features of the gas flow over a rigid sphere: pressure gradient, viscous boundary layer, wake. In addition to these common flow features one can also mention the internal liquid circulation phenomenon driven by surface-shear forces and the boundary layer blowing effect.
In situ thermal desorption (ISTD) is an intensive thermally enhanced environmental remediation technology that uses thermal conductive heating (TCH) elements to directly transfer heat to environmental media. The ISTD/TCH process can be applied at low (<100 °C), moderate (~100 °C) and higher (>100 °C) temperature levels to accomplish the remediation of a wide variety of contaminants, both above and below the water table. ISTD/TCH is the only major in situ thermal remediation (ISTR) technology capable of achieving subsurface target treatment temperatures above the boiling point of water and is effective at virtually any depth in almost any media. TCH works in tight soils, clay layers, and soils with wide heterogeneity in permeability or moisture content that are impacted by a broad range of volatile and semi-volatile organic contaminants.
CFD stands for computational fluid dynamics. As per this technique, the governing differential equations of a flow system or thermal system are known in the form of Navier–Stokes equations, thermal energy equation and species equation with an appropriate equation of state. In the past few years, CFD has been playing an increasingly important role in building design, following its continuing development for over a quarter of a century. The information provided by CFD can be used to analyse the impact of building exhausts to the environment, to predict smoke and fire risks in buildings, to quantify indoor environment quality, and to design natural ventilation systems.
Computational Fluid Dynamics (CFD) modeling and simulation for phase change materials (PCMs) is a technique to analyze the performance and behavior of PCMs. The CFD models have been successful in studying and analyzing the air quality, natural ventilation and stratified ventilation, air flow initiated by buoyancy forces and temperature space for the systems integrated with PCMs. Simple shapes like flat plates, cylinders or annular tubes, fins, macro- and micro-encapsulations with containers of different shape are often modeled in CFD software's to study.
Aquifer thermal energy storage (ATES) is the storage and recovery of thermal energy in the subsurface. ATES is applied to provide heating and cooling to buildings. Storage and recovery of thermal energy is achieved by extraction and injection of groundwater from aquifers using groundwater wells. Systems commonly operate in a seasonal mode. The groundwater that is extracted in summer, is used for cooling by transferring heat from the building to the groundwater by means of a heat exchanger. Subsequently, the heated groundwater is injected back into the aquifer, which creates a storage of heated groundwater. In wintertime, the flow direction is reversed such that the heated groundwater is extracted and can be used for heating. Therefore, operating an ATES system uses the subsurface as a temporal storage to buffer seasonal variations in heating and cooling demand. When replacing traditional fossil fuel dependent heating and cooling systems, ATES can serve as a cost-effective technology to reduce the primary energy consumption of a building and the associated CO2 emissions.