Exfoliation corrosion (metallurgy)

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In metallurgy, exfoliation corrosion (also called lamellar corrosion [1] ) is a severe type [2] of intergranular corrosion that raises surface grains from metal by forming corrosion products at grain boundaries under the surface. It is frequently found on extruded sections where grain thickness is not as thick as the rolled grain. It can affect aircraft structures,[ citation needed ] marine vessels, heaters [1] and other objects.

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Corrosion Gradual destruction of materials by chemical reaction with its environment

Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual destruction of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.

Passivation, in physical chemistry and engineering, refers to coating a material so it becomes "passive," that is, less readily affected or corroded by the environment. Passivation involves creation of an outer layer of shield material that is applied as a microcoating, created by chemical reaction with the base material, or allowed to build by spontaneous oxidation in the air. As a technique, passivation is the use of a light coat of a protective material, such as metal oxide, to create a shield against corrosion. Passivation of silicon is used during fabrication of microelectronic devices. In electrochemical treatment of water, passivation reduces the effectiveness of the treatment by increasing the circuit resistance, and active measures are typically used to overcome this effect, the most common being polarity reversal, which results in limited rejection of the fouling layer.

Spall Material fragments removed from a surface weakened by an impact, corrosion, or weathering

Spall are fragments of a material that are broken off a larger solid body. It can be produced by a variety of mechanisms, including as a result of projectile impact, corrosion, weathering, cavitation, or excessive rolling pressure. Spalling and spallation both describe the process of surface failure in which spall is shed.

Lamellar armour Armour made of overlapping scales, without a solid backing

Lamellar armour is a type of body armour, made from small rectangular plates of iron or steel, leather (rawhide), or bronze laced into horizontal rows. Lamellar armour was used over a wide range of time periods in Central Asia, Eastern Asia, Western Asia, and Eastern Europe. The earliest evidence for lamellar armour comes from sculpted artwork of the Neo-Assyrian Empire in the Near East.

Exfoliation can refer to:

Primer (paint) Preparatory coating put on materials before painting

A primer or undercoat is a preparatory coating put on materials before painting. Priming ensures better adhesion of paint to the surface, increases paint durability, and provides additional protection for the material being painted.

Superalloy Alloy with higher durability than normal metals

A superalloy, or high-performance alloy, is an alloy with the ability to operate at a high fraction of its melting point. Several key characteristics of a superalloy are excellent mechanical strength, resistance to thermal creep deformation, good surface stability, and resistance to corrosion or oxidation.

Microstructure Very small scale structure of material

Microstructure is the very small scale structure of a material, defined as the structure of a prepared surface of material as revealed by an optical microscope above 25× magnification. The microstructure of a material can strongly influence physical properties such as strength, toughness, ductility, hardness, corrosion resistance, high/low temperature behaviour or wear resistance. These properties in turn govern the application of these materials in industrial practice.

Fouling Accumulation of unwanted material on solid surfaces

Fouling is the accumulation of unwanted material on solid surfaces. The fouling materials can consist of either living organisms (biofouling) or a non-living substance. Fouling is usually distinguished from other surface-growth phenomena in that it occurs on a surface of a component, system, or plant performing a defined and useful function and that the fouling process impedes or interferes with this function.

Chromium(II) carbide Chemical compound

Chromium(II) carbide is a ceramic compound that exists in several chemical compositions: Cr3C2, Cr7C3, and Cr23C6. At standard conditions it exists as a gray solid. It is extremely hard and corrosion resistant. It is also a refractory compound, which means that it retains its strength at high temperatures as well. These properties make it useful as an additive to metal alloys. When chromium carbide crystals are integrated into the surface of a metal it improves the wear resistance and corrosion resistance of the metal, and maintains these properties at elevated temperatures. The hardest and most commonly used composition for this purpose is Cr3C2.

Intergranular corrosion

Intergranular corrosion (IGC), also known as intergranular attack (IGA), is a form of corrosion where the boundaries of crystallites of the material are more susceptible to corrosion than their insides.

Exfoliation joint

Exfoliation joints or sheet joints are surface-parallel fracture systems in rock, and often leading to erosion of concentric slabs. (See Joint ).

Exfoliation (cosmetology) Removal of dead skin cells from the epidermis

Exfoliation involves the removal of the oldest dead skin cells from the skin's surface. The word comes from the Latin word exfoliare. Exfoliation is involved in all facials and can be achieved by mechanical or chemical means, such as microdermabrasion or chemical peels. Exfoliants are often advertised as treatments that promote beauty, youthful appearance, or health.

Corrosion fatigue is fatigue in a corrosive environment. It is the mechanical degradation of a material under the joint action of corrosion and cyclic loading. Nearly all engineering structures experience some form of alternating stress, and are exposed to harmful environments during their service life. The environment plays a significant role in the fatigue of high-strength structural materials like steel, aluminum alloys and titanium alloys. Materials with high specific strength are being developed to meet the requirements of advancing technology. However, their usefulness depends to a large extent on the degree to which they resist corrosion fatigue.

Glacial polish Rock surface type

Glacial polish is a characteristic of rock surfaces where glaciers have passed over bedrock, typically granite or other hard igneous or metamorphic rock. Moving ice will carry pebbles and sand grains removed from upper levels which in turn grind a smooth or grooved surface upon the underlying rock. The presence of such polish indicates that the glaciation was relatively recent or was subsequently protected by deposition, as such polish will be subsequently lost due to weathering processes.

Directional solidification

Directional solidification(DS) and progressive solidification are types of solidification within castings. Directional solidification is solidification that occurs from farthest end of the casting and works its way towards the sprue. Progressive solidification, also known as parallel solidification, is solidification that starts at the walls of the casting and progresses perpendicularly from that surface.

Dry lubricants or solid lubricants are materials that, despite being in the solid phase, are able to reduce friction between two surfaces sliding against each other without the need for a liquid oil medium.

Keratolysis exfoliativa is a sometimes harmless, sometimes painful skin condition that can affect the focal surface of the fingers and/or the palm or soles of the feet. It is often misdiagnosed as chronic contact dermatitis or psoriasis. It is characterized by dry skin and superficial, air-filled blisters. These blisters can be peeled off very easily and will leave reddish, tender areas. The loss of this corneal layer of the skin, which protects the underlying layers, leaves the skin more vulnerable to dryness and cracking.

Mass finishing is a group of manufacturing processes that allow large quantities of parts to be simultaneously finished. The goal of this type of finishing is to burnish, deburr, clean, radius, de-flash, descale, remove rust, polish, brighten, surface harden, prepare parts for further finishing, or break off die cast runners. The two main types of mass finishing are tumble finishing, also known as barrel finishing, and vibratory finishing. Both involve the use of a cyclical action to create grinding contact between surfaces. Sometimes the workpieces are finished against each other; however, usually a finishing medium is used. Mass finishing can be performed dry or wet; wet processes have liquid lubricants, cleaners, or abrasives, while dry processes do not. Cycle times can be as short as 10 minutes for nonferrous workpieces or as long as 2 hours for hardened steel.

Aluminium 7150 alloy is a heat treatable wrought alloy. It is used in the aerospace industry for manufacturing aircraft components. Heat treatment can improve its anti-corrosion properties with a low corresponding decrease in strength.

References

  1. 1 2 "Lamellar Corrosion or Exfoliation?".
  2. "Exfoliation Corrosion".