In the small wavelength limit, the total scattering cross-section of an impenetrable sphere is twice its geometrical cross-sectional area (which is the value obtained in classical mechanics). [1]
Several explanations for this phenomenon have been proposed: [2]
In physics, the cross section is a measure of the probability that a specific process will take place when some kind of radiant excitation intersects a localized phenomenon. For example, the Rutherford cross-section is a measure of probability that an alpha-particle will be deflected by a given angle during a collision with an atomic nucleus. Cross section is typically denoted σ (sigma) and is expressed in units of transverse area. In a way, it can be thought of as the size of the object that the excitation must hit in order for the process to occur, but more exactly, it is a parameter of a stochastic process.
Rayleigh scattering, named after the nineteenth-century British physicist Lord Rayleigh, is the predominantly elastic scattering of light or other electromagnetic radiation by particles much smaller than the wavelength of the radiation. For light frequencies well below the resonance frequency of the scattering particle, the amount of scattering is inversely proportional to the fourth power of the wavelength.
In physics, attenuation or, in some contexts, extinction is the gradual loss of flux intensity through a medium. For instance, dark glasses attenuate sunlight, lead attenuates X-rays, and water and air attenuate both light and sound at variable attenuation rates.
Scattering is a term used in physics to describe a wide range of physical processes where moving particles or radiation of some form, such as light or sound, is forced to deviate from a straight trajectory by localized non-uniformities in the medium through which they pass. In conventional use, this also includes deviation of reflected radiation from the angle predicted by the law of reflection. Reflections of radiation that undergo scattering are often called diffuse reflections and unscattered reflections are called specular (mirror-like) reflections. Originally, the term was confined to light scattering. As more "ray"-like phenomena were discovered, the idea of scattering was extended to them, so that William Herschel could refer to the scattering of "heat rays" in 1800. John Tyndall, a pioneer in light scattering research, noted the connection between light scattering and acoustic scattering in the 1870s. Near the end of the 19th century, the scattering of cathode rays and X-rays was observed and discussed. With the discovery of subatomic particles and the development of quantum theory in the 20th century, the sense of the term became broader as it was recognized that the same mathematical frameworks used in light scattering could be applied to many other phenomena.
The Mie solution to Maxwell's equations describes the scattering of an electromagnetic plane wave by a homogeneous sphere. The solution takes the form of an infinite series of spherical multipole partial waves. It is named after Gustav Mie.
In physics, Bragg's law, or Wulff–Bragg's condition, a special case of Laue diffraction, gives the angles for coherent and incoherent scattering from a crystal lattice. When X-rays are incident on an atom, they make the electronic cloud move, as does any electromagnetic wave. The movement of these charges re-radiates waves with the same frequency, blurred slightly due to a variety of effects; this phenomenon is known as Rayleigh scattering. The scattered waves can themselves be scattered but this secondary scattering is assumed to be negligible.
Raman scattering or the Raman effect is the inelastic scattering of photons by matter, meaning that there is an exchange of energy and a change in the light's direction. Typically this involves vibrational energy being gained by a molecule as incident photons from a visible laser are shifted to lower energy. This is called normal Stokes Raman scattering. The effect is exploited by chemists and physicists to gain information about materials for a variety of purposes by performing various forms of Raman spectroscopy. Many other variants of Raman spectroscopy allow rotational energy to be examined and electronic energy levels may be examined if an X-ray source is used in addition to other possibilities. More complex techniques involving pulsed lasers, multiple laser beams and so on are known.
Thomson scattering is the elastic scattering of electromagnetic radiation by a free charged particle, as described by classical electromagnetism. It is the low-energy limit of Compton scattering: the particle's kinetic energy and photon frequency do not change as a result of the scattering. This limit is valid as long as the photon energy is much smaller than the mass energy of the particle: , or equivalently, if the wavelength of the light is much greater than the Compton wavelength of the particle.
The planet Jupiter has a system of rings known as the rings of Jupiter or the Jovian ring system. It was the third ring system to be discovered in the Solar System, after those of Saturn and Uranus. It was first observed in 1979 by the Voyager 1 space probe and thoroughly investigated in the 1990s by the Galileo orbiter. It has also been observed by the Hubble Space Telescope and from Earth for several years. Ground-based observation of the rings requires the largest available telescopes.
Dynamic light scattering (DLS) is a technique in physics that can be used to determine the size distribution profile of small particles in suspension or polymers in solution. In the scope of DLS, temporal fluctuations are usually analyzed by means of the intensity or photon auto-correlation function. In the time domain analysis, the autocorrelation function (ACF) usually decays starting from zero delay time, and faster dynamics due to smaller particles lead to faster decorrelation of scattered intensity trace. It has been shown that the intensity ACF is the Fourier transformation of the power spectrum, and therefore the DLS measurements can be equally well performed in the spectral domain. DLS can also be used to probe the behavior of complex fluids such as concentrated polymer solutions.
Discrete dipole approximation (DDA), also known as coupled dipole approximation, is a method for computing scattering of radiation by particles of arbitrary shape and by periodic structures. Given a target of arbitrary geometry, one seeks to calculate its scattering and absorption properties by an approximation of the continuum target by a finite array of small polarizable dipoles. This technique is used in a variety of applications including nanophotonics, radar scattering, aerosol physics and astrophysics.
Light scattering by particles is the process by which small particles scatter light causing optical phenomena such as rainbows, the blue color of the sky, and halos.
Mott scattering, also referred to as spin-coupling inelastic Coulomb scattering, is the separation of the two spin states of an electron beam by scattering the beam off the Coulomb field of heavy atoms. It is named after Nevill Francis Mott, who first developed the theory. It is mostly used to measure the spin polarization of an electron beam.
Electrophoretic light scattering is based on dynamic light scattering. The frequency shift or phase shift of an incident laser beam depends on the dispersed particles mobility. In the case of dynamic light scattering, Brownian motion causes particle motion. In the case of electrophoretic light scattering, oscillating electric field performs the same function.
Rutherford backscattering spectrometry (RBS) is an analytical technique used in materials science. Sometimes referred to as high-energy ion scattering (HEIS) spectrometry, RBS is used to determine the structure and composition of materials by measuring the backscattering of a beam of high energy ions impinging on a sample.
Multiangle light scattering (MALS) describes a technique for measuring the light scattered by a sample into a plurality of angles. It is used for determining both the absolute molar mass and the average size of molecules in solution, by detecting how they scatter light. Collimated light from a laser source is most often used, in which case the technique can be referred to as multiangle laser light scattering (MALLS). The insertion of the word “laser” was intended to reassure those used to making light scattering measurements with conventional light sources such as Hg-arc lamps that low angle measurements could now be made. Until the advent of lasers and their associated fine beams of narrow width, the width of conventional light beams used to make such measurements prevented data collection at smaller scattering angles. In recent years, since all commercial light scattering instrumentation use laser sources, this need to mention the light source has been dropped and the term MALS used throughout.
Codes for electromagnetic scattering by spheres - this article list codes for electromagnetic scattering by a homogeneous sphere, layered sphere, and cluster of spheres.
Anomalous diffraction theory is an approximation developed by Dutch astronomer van de Hulst describing light scattering for optically soft spheres.
The T-matrix method is a computational technique of light scattering by nonspherical particles originally formulated by Peter C. Waterman (1928–2012) in 1965. The technique is also known as null field method and extended boundary technique method (EBCM). In the method, matrix elements are obtained by matching boundary conditions for solutions of Maxwell equations.
Rayleigh–Gans approximation, also known as Rayleigh–Gans–Debye approximation and Rayleigh–Gans–Born approximation, is an approximate solution to light scattering by optically soft particles. Optical softness implies that the relative refractive index of particle is close to that of the surrounding medium. The approximation holds for particles of arbitrary shape that are relatively small but can be larger than Rayleigh scattering limits.
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