Assumptions and Derivations
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The Hille equation relates the maximum ionic conductance of an ion channel to its length and radius (or diameter), with the commonly used version implicitly takes into account a hemispherical cap. [1] As it is ultimately based on a macroscopic continuum model, it does not take into account molecular interactions, and real conductances are often several times less than the predicted maximal flux.
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The Hille equation predicts the following maximum conductance for a pore with length , radius , in a solvent with resistivity :
Rearranging the terms, the maximal flux based on length and diameter can be shown to be:
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Fick's laws of diffusion describe diffusion and were first posited by Adolf Fick in 1855 on the basis of largely experimental results. They can be used to solve for the diffusion coefficient, D. Fick's first law can be used to derive his second law which in turn is identical to the diffusion equation.
In mathematics and physics, Laplace's equation is a second-order partial differential equation named after Pierre-Simon Laplace, who first studied its properties. This is often written as
In fluid mechanics, the Grashof number is a dimensionless number which approximates the ratio of the buoyancy to viscous forces acting on a fluid. It frequently arises in the study of situations involving natural convection and is analogous to the Reynolds number.
The gravitational binding energy of a system is the minimum energy which must be added to it in order for the system to cease being in a gravitationally bound state. A gravitationally bound system has a lower gravitational potential energy than the sum of the energies of its parts when these are completely separated—this is what keeps the system aggregated in accordance with the minimum total potential energy principle.
A solenoid is a type of electromagnet formed by a helical coil of wire whose length is substantially greater than its diameter, which generates a controlled magnetic field. The coil can produce a uniform magnetic field in a volume of space when an electric current is passed through it.
In physics, the screened Poisson equation is a Poisson equation, which arises in the Klein–Gordon equation, electric field screening in plasmas, and nonlocal granular fluidity in granular flow.
The DLVO theory explains the aggregation and kinetic stability of aqueous dispersions quantitatively and describes the force between charged surfaces interacting through a liquid medium. It combines the effects of the van der Waals attraction and the electrostatic repulsion due to the so-called double layer of counterions. The electrostatic part of the DLVO interaction is computed in the mean field approximation in the limit of low surface potentials - that is when the potential energy of an elementary charge on the surface is much smaller than the thermal energy scale, . For two spheres of radius each having a charge separated by a center-to-center distance in a fluid of dielectric constant containing a concentration of monovalent ions, the electrostatic potential takes the form of a screened-Coulomb or Yukawa potential,
A radiation zone, or radiative region is a layer of a star's interior where energy is primarily transported toward the exterior by means of radiative diffusion and thermal conduction, rather than by convection. Energy travels through the radiation zone in the form of electromagnetic radiation as photons.
Collision theory is a principle of chemistry used to predict the rates of chemical reactions. It states that when suitable particles of the reactant hit each other with the correct orientation, only a certain amount of collisions result in a perceptible or notable change; these successful changes are called successful collisions. The successful collisions must have enough energy, also known as activation energy, at the moment of impact to break the pre-existing bonds and form all new bonds. This results in the products of the reaction. The activation energy is often predicted using the Transition state theory. Increasing the concentration of the reactant brings about more collisions and hence more successful collisions. Increasing the temperature increases the average kinetic energy of the molecules in a solution, increasing the number of collisions that have enough energy. Collision theory was proposed independently by Max Trautz in 1916 and William Lewis in 1918.
In geometry, the area enclosed by a circle of radius r is πr2. Here the Greek letter π represents the constant ratio of the circumference of any circle to its diameter, approximately equal to 3.14159.
In physics, the Einstein relation is a previously unexpected connection revealed independently by William Sutherland in 1904, Albert Einstein in 1905, and by Marian Smoluchowski in 1906 in their works on Brownian motion. The more general form of the equation in the classical case is
In neurobiology, the length constant (λ) is a mathematical constant used to quantify the distance that a graded electric potential will travel along a neurite via passive electrical conduction. The greater the value of the length constant, the farther the potential will travel. A large length constant can contribute to spatial summation—the electrical addition of one potential with potentials from adjacent areas of the cell.
The second polar moment of area, also known as "polar moment of inertia" or even "moment of inertia", is a quantity used to describe resistance to torsional deformation (deflection), in objects with an invariant cross-section and no significant warping or out-of-plane deformation. It is a constituent of the second moment of area, linked through the perpendicular axis theorem. Where the planar second moment of area describes an object's resistance to deflection (bending) when subjected to a force applied to a plane parallel to the central axis, the polar second moment of area describes an object's resistance to deflection when subjected to a moment applied in a plane perpendicular to the object's central axis. Similar to planar second moment of area calculations, the polar second moment of area is often denoted as . While several engineering textbooks and academic publications also denote it as or , this designation should be given careful attention so that it does not become confused with the torsion constant, , used for non-cylindrical objects.
The Kelvin equation describes the change in vapour pressure due to a curved liquid–vapor interface, such as the surface of a droplet. The vapor pressure at a convex curved surface is higher than that at a flat surface. The Kelvin equation is dependent upon thermodynamic principles and does not allude to special properties of materials. It is also used for determination of pore size distribution of a porous medium using adsorption porosimetry. The equation is named in honor of William Thomson, also known as Lord Kelvin.
In astrophysics, the Tolman–Oppenheimer–Volkoff (TOV) equation constrains the structure of a spherically symmetric body of isotropic material which is in static gravitational equilibrium, as modelled by general relativity. The equation is
The Navarro–Frenk–White (NFW) profile is a spatial mass distribution of dark matter fitted to dark matter halos identified in N-body simulations by Julio Navarro, Carlos Frenk and Simon White. The NFW profile is one of the most commonly used model profiles for dark matter halos.
In physics, Gauss's law for gravity, also known as Gauss's flux theorem for gravity, is a law of physics that is equivalent to Newton's law of universal gravitation. It is named after Carl Friedrich Gauss. It states that the flux of the gravitational field over any closed surface is proportional to the mass enclosed. Gauss's law for gravity is often more convenient to work from than Newton's law.
In nonideal fluid dynamics, the Hagen–Poiseuille equation, also known as the Hagen–Poiseuille law, Poiseuille law or Poiseuille equation, is a physical law that gives the pressure drop in an incompressible and Newtonian fluid in laminar flow flowing through a long cylindrical pipe of constant cross section. It can be successfully applied to air flow in lung alveoli, or the flow through a drinking straw or through a hypodermic needle. It was experimentally derived independently by Jean Léonard Marie Poiseuille in 1838 and Gotthilf Heinrich Ludwig Hagen, and published by Poiseuille in 1840–41 and 1846. The theoretical justification of the Poiseuille law was given by George Stokes in 1845.
An LC circuit can be quantized using the same methods as for the quantum harmonic oscillator. An LC circuit is a variety of resonant circuit, and consists of an inductor, represented by the letter L, and a capacitor, represented by the letter C. When connected together, an electric current can alternate between them at the circuit's resonant frequency:
The vaporizing droplet problem is a challenging issue in fluid dynamics. It is part of many engineering situations involving the transport and computation of sprays: fuel injection, spray painting, aerosol spray, flashing releases… In most of these engineering situations there is a relative motion between the droplet and the surrounding gas. The gas flow over the droplet has many features of the gas flow over a rigid sphere: pressure gradient, viscous boundary layer, wake. In addition to these common flow features one can also mention the internal liquid circulation phenomenon driven by surface-shear forces and the boundary layer blowing effect.
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