In fluid dynamics, the Knudsen equation is used to describe how gas flows through a tube in free molecular flow. When the mean free path of the molecules in the gas is larger than or equal to the diameter of the tube, the molecules will interact more often with the walls of the tube than with each other. For typical tube dimensions, this occurs only in high or ultrahigh vacuum.
The equation was developed by Martin Hans Christian Knudsen (1871–1949), a Danish physicist who taught and conducted research at the Technical University of Denmark.
For a cylindrical tube, the Knudsen equation is: [1]
where:
| Quantity | Description |
|---|---|
| q | volume flow rate at unit pressure (volume×pressure/time) |
| ΔP | pressure drop from the beginning of the tube to the end |
| d | diameter of the tube |
| l | length of the tube |
| ρ1 | ratio of density and pressure |
For nitrogen (or air) at room temperature, the conductivity (in liters per second) of a tube can be calculated from this equation: [2]
Fick's laws of diffusion describe diffusion and were first posited by Adolf Fick in 1855 on the basis of largely experimental results. They can be used to solve for the diffusion coefficient, D. Fick's first law can be used to derive his second law which in turn is identical to the diffusion equation.
The Mach number, often only Mach, is a dimensionless quantity in fluid dynamics representing the ratio of flow velocity past a boundary to the local speed of sound. It is named after the Austrian physicist and philosopher Ernst Mach.
A rectifier is an electrical device that converts alternating current (AC), which periodically reverses direction, to direct current (DC), which flows in only one direction. The reverse operation is performed by an inverter.
The kinetic theory of gases is a simple, historically significant classical model of the thermodynamic behavior of gases, with which many principal concepts of thermodynamics were established. The model describes a gas as a large number of identical submicroscopic particles, all of which are in constant, rapid, random motion. Their size is assumed to be much smaller than the average distance between the particles. The particles undergo random elastic collisions between themselves and with the enclosing walls of the container. The basic version of the model describes the ideal gas, and considers no other interactions between the particles.
The speed of sound is the distance travelled per unit of time by a sound wave as it propagates through an elastic medium. At 20 °C (68 °F), the speed of sound in air is about 343 metres per second, or one kilometre in 2.91 s or one mile in 4.69 s. It depends strongly on temperature as well as the medium through which a sound wave is propagating. At 0 °C (32 °F), the speed of sound in air is about 331 m/s. More simply, the speed of sound is how fast vibrations travel.
In physics, mean free path is the average distance over which a moving particle travels before substantially changing its direction or energy, typically as a result of one or more successive collisions with other particles.
In fluid dynamics, the Darcy–Weisbach equation is an empirical equation that relates the head loss, or pressure loss, due to friction along a given length of pipe to the average velocity of the fluid flow for an incompressible fluid. The equation is named after Henry Darcy and Julius Weisbach. Currently, there is no formula more accurate or universally applicable than the Darcy-Weisbach supplemented by the Moody diagram or Colebrook equation.
In physics and chemistry, effusion is the process in which a gas escapes from a container through a hole of diameter considerably smaller than the mean free path of the molecules. Such a hole is often described as a pinhole and the escape of the gas is due to the pressure difference between the container and the exterior. Under these conditions, essentially all molecules which arrive at the hole continue and pass through the hole, since collisions between molecules in the region of the hole are negligible. Conversely, when the diameter is larger than the mean free path of the gas, flow obeys the Sampson flow law.
Space charge is an interpretation of a collection of electric charges in which excess electric charge is treated as a continuum of charge distributed over a region of space rather than distinct point-like charges. This model typically applies when charge carriers have been emitted from some region of a solid—the cloud of emitted carriers can form a space charge region if they are sufficiently spread out, or the charged atoms or molecules left behind in the solid can form a space charge region.
The Knudsen number (Kn) is a dimensionless number defined as the ratio of the molecular mean free path length to a representative physical length scale. This length scale could be, for example, the radius of a body in a fluid. The number is named after Danish physicist Martin Knudsen (1871–1949).
Darcy's law is an equation that describes the flow of a fluid through a porous medium. The law was formulated by Henry Darcy based on results of experiments on the flow of water through beds of sand, forming the basis of hydrogeology, a branch of earth sciences. It is analogous to Ohm's law in electrostatics, linearly relating the volume flow rate of the fluid to the hydraulic head difference via the hydraulic conductivity.
An orifice plate is a device used for measuring flow rate, for reducing pressure or for restricting flow.
Direct simulation Monte Carlo (DSMC) method uses probabilistic Monte Carlo simulation to solve the Boltzmann equation for finite Knudsen number fluid flows.
In physics, Knudsen diffusion, named after Martin Knudsen, is a means of diffusion that occurs when the scale length of a system is comparable to or smaller than the mean free path of the particles involved. An example of this is in a long pore with a narrow diameter (2–50 nm) because molecules frequently collide with the pore wall. As another example, consider the diffusion of gas molecules through very small capillary pores. If the pore diameter is smaller than the mean free path of the diffusing gas molecules, and the density of the gas is low, the gas molecules collide with the pore walls more frequently than with each other, leading to Knudsen diffusion.
Diffusivity, mass diffusivity or diffusion coefficient is usually written as the proportionality constant between the molar flux due to molecular diffusion and the negative value of the gradient in the concentration of the species. More accurately, the diffusion coefficient times the local concentration is the proportionality constant between the negative value of the mole fraction gradient and the molar flux. This distinction is especially significant in gaseous systems with strong temperature gradients. Diffusivity derives its definition from Fick's law and plays a role in numerous other equations of physical chemistry.
In fluid dynamics, the Darcy friction factor formulae are equations that allow the calculation of the Darcy friction factor, a dimensionless quantity used in the Darcy–Weisbach equation, for the description of friction losses in pipe flow as well as open-channel flow.
In nonideal fluid dynamics, the Hagen–Poiseuille equation, also known as the Hagen–Poiseuille law, Poiseuille law or Poiseuille equation, is a physical law that gives the pressure drop in an incompressible and Newtonian fluid in laminar flow flowing through a long cylindrical pipe of constant cross section. It can be successfully applied to air flow in lung alveoli, or the flow through a drinking straw or through a hypodermic needle. It was experimentally derived independently by Jean Léonard Marie Poiseuille in 1838 and Gotthilf Heinrich Ludwig Hagen, and published by Poiseuille in 1840–41 and 1846. The theoretical justification of the Poiseuille law was given by George Stokes in 1845.
Diffusion is the net movement of anything generally from a region of higher concentration to a region of lower concentration. Diffusion is driven by a gradient in Gibbs free energy or chemical potential. It is possible to diffuse "uphill" from a region of lower concentration to a region of higher concentration, as in spinodal decomposition. Diffusion is a stochastic process due to the inherent randomness of the diffusing entity and can be used to model many real-life stochastic scenarios. Therefore, diffusion and the corresponding mathematical models are used in several fields beyond physics, such as statistics, probability theory, information theory, neural networks, finance, and marketing.
Chapman–Enskog theory provides a framework in which equations of hydrodynamics for a gas can be derived from the Boltzmann equation. The technique justifies the otherwise phenomenological constitutive relations appearing in hydrodynamical descriptions such as the Navier–Stokes equations. In doing so, expressions for various transport coefficients such as thermal conductivity and viscosity are obtained in terms of molecular parameters. Thus, Chapman–Enskog theory constitutes an important step in the passage from a microscopic, particle-based description to a continuum hydrodynamical one.
In surface chemistry, the Hertz–Knudsen equation, also known as Knudsen-Langmuir equation describes evaporation rates, named after Heinrich Hertz and Martin Knudsen.
