Lead oxychloride

Last updated

Lead oxychlorides are halide compounds of lead with the general formula PbClO(H).

Contents

Occurrence in nature

Lead oxychlorides are found naturally in the minerals hereroite as Pb32O212Cl10, in rickturnerite as Pb7O4(OH)Cl3, in vladkrivovichevite as Pb32O18Cl14, in asisite as Pb7SiO4O4Cl2, in damaraite as Pb3Cl(OH)O2, in hereroite as Pb3Cl(OH)O2, in Mendipite as Pb3Cl2O2, and in the dimorph minerals laurionite and paralaurionite, which are PbCl(OH) members of the matlockite group.

Usage

Historically, the primary use of lead oxychlorides was in a mixture with other lead compounds (e.g. lead carbonate "white lead") as a pigment in lead paints. The lead compounds were first fused, and the product then ground to fine powder. The powder was then suspended in drying oils (e.g. linseed), to produce e.g. Pattinson's white (PbCl2 2Pb(OH)2) or Turner's yellow (PbCl2 5-7PbO). Turner's yellow is also known as Patent yellow, Cassel yellow, Montpelier yellow, Kassler yellow, mineral yellow, and Verona yellow.

In the late 19th century, lead oxychlorides were briefly used in the manufacture of electrodes for lead-acid batteries. Patented by Charles Francis Brush in 1876, [1] the depressions in a ribbed or grooved sheet of lead were filled with pulverized lead oxychloride (later also lead sulfate). In a second step, the grooved sheet was covered with paper and horizontally suspended in a salt or acid solution, to which a zinc plate was then also added. The mixture in the grooved sheet's depressions was then electrolytically reduced to sponge lead, forming a functional lead-acid cell electrode (if subsequently used as a positive electrode, the sponge lead was converted to lead peroxide during the cell's initial "formation" charge). Brush's technique was superseded by the now standard Faure pasting method in 1880.

Related Research Articles

Salt (chemistry) Ionic compound formed of cations and anions

In chemistry, a salt is a solid chemical compound consisting of an ionic assembly of cations and anions. Salts are composed of related numbers of cations and anions so that the product is electrically neutral. These component ions can be inorganic, such as chloride (Cl), or organic, such as acetate ; and can be monatomic, such as fluoride (F) or polyatomic, such as sulfate.

A half reaction is either the oxidation or reduction reaction component of a redox reaction. A half reaction is obtained by considering the change in oxidation states of individual substances involved in the redox reaction.

Magnesium hydroxide chemical compound

Magnesium hydroxide is the inorganic compound with the chemical formula Mg(OH)2. It occurs in nature as the mineral brucite. It is a white solid with low solubility in water (Ksp = 5.61×10−12). Magnesium hydroxide is a common component of antacids, such as milk of magnesia, as well as laxatives.

Lead–acid battery rechargeable battery type often used in cars

The lead–acid battery was invented in 1859 by French physicist Gaston Planté and is the earliest type of rechargeable battery. Despite having a very low energy-to-weight ratio and a low energy-to-volume ratio, its ability to supply high surge currents means that the cells have a relatively large power-to-weight ratio. These features, along with their low cost, make them attractive for use in motor vehicles to provide the high current required by automobile starter motors.

Lead(II) nitrate is an inorganic compound with the chemical formula Pb(NO3)2. It commonly occurs as a colourless crystal or white powder and, unlike most other lead(II) salts, is soluble in water.

Manganese dioxide chemical compound

Manganese(IV) oxide is the inorganic compound with the formula MnO
2
. This blackish or brown solid occurs naturally as the mineral pyrolusite, which is the main ore of manganese and a component of manganese nodules. The principal use for MnO
2
is for dry-cell batteries, such as the alkaline battery and the zinc-carbon battery. MnO
2
is also used as a pigment and as a precursor to other manganese compounds, such as KMnO
4
. It is used as a reagent in organic synthesis, for example, for the oxidation of allylic alcohols. MnO
2
in the α polymorph can incorporate a variety of atoms in the "tunnels" or "channels" between the manganese oxide octahedra. There is considerable interest in α-MnO
2
as a possible cathode for lithium ion batteries.

Lead(II) sulfate chemical compound

Lead(II) sulfate (PbSO4) is a white solid, which appears white in microcrystalline form. It is also known as fast white, milk white, sulfuric acid lead salt or anglesite.

Lead(II) chloride chemical compound

Lead(II) chloride (PbCl2) is an inorganic compound which is a white solid under ambient conditions. It is poorly soluble in water. Lead(II) chloride is one of the most important lead-based reagents. It also occurs naturally in the form of the mineral cotunnite.

Copper(II) oxide chemical compound

Copper(II) oxide or cupric oxide is the inorganic compound with the formula CuO. A black solid, it is one of the two stable oxides of copper, the other being Cu2O or cuprous oxide. As a mineral, it is known as tenorite. It is a product of copper mining and the precursor to many other copper-containing products and chemical compounds.

Lead(II,IV) oxide chemical compound

Lead(II,IV) oxide, also called red lead or minium, is the inorganic compound with the formula Pb3O4. A bright red or orange solid, it is used as pigment, in the manufacture of batteries, and rustproof primer paints. It is an example of a mixed valence compound, being composed of both Pb(II) and Pb(IV) in the ratio of two to one.

Lead dioxide chemical compound

Lead(IV) oxide is the inorganic compound with the formula PbO2. It is an oxide where lead is in an oxidation state of +4. It is a dark-brown solid which is insoluble in water. It exists in two crystalline forms. It has several important applications in electrochemistry, in particular as the positive plate of lead acid batteries.

Lead(II) hydroxide, Pb(OH)2, is a hydroxide of lead, with lead in oxidation state +2. It is doubtful that such a simple compound exists. Lead basic carbonate (PbCO3·2Pb(OH)2) or lead(II) oxide (PbO) is encountered in practice where lead hydroxide is expected. This has been a subject of considerable confusion in the past.

Calcium hypochlorite is an inorganic compound with formula Ca(ClO)2. It is the main active ingredient of commercial products called bleaching powder, chlorine powder, or chlorinated lime, used for water treatment and as a bleaching agent. This compound is relatively stable and has greater available chlorine than sodium hypochlorite (liquid bleach). It is a white solid, although commercial samples appear yellow. It strongly smells of chlorine, owing to its slow decomposition in moist air. It is not highly soluble in hard water, and is more preferably used in soft to medium-hard water. It has two forms: dry (anhydrous); and hydrated (hydrous).

Iron(III) oxide-hydroxide chemical compound

Iron(III) oxide-hydroxide or ferric oxyhydroxide is the chemical compound of iron, oxygen, and hydrogen with formula FeO(OH).

Antimony oxychloride chemical compound

Antimony oxychloride, known since the 15th century, has been known by a plethora of alchemical names. Since the compound functions as both an emetic and a laxative, it was originally used as a purgative.

Lead(II) chromate chemical compound

Lead(II) chromate (PbCrO4) is a chemical compound, a chromate of lead. It has a vivid yellow color and is insoluble in water, and as a result, is used in paints under the name chrome yellow.

Dicopper chloride trihydroxide chemical compound

Dicopper chloride trihydroxide is the chemical compound with the formula Cu2(OH)3Cl. It is often referred to as tribasic copper chloride (TBCC), copper trihydroxyl chloride or copper hydroxychloride. It is a greenish crystalline solid encountered in mineral deposits, metal corrosion products, industrial products, art and archeological objects, and some living systems. It was originally manufactured on an industrial scale as a precipitated material used as either a chemical intermediate or a fungicide. Since 1994, a purified, crystallized product has been produced at the scale of thousands of tons per year, and used extensively as a nutritional supplement for animals.

Compounds of lead exist in two main oxidation states: +2 and +4. The former is more common. Inorganic lead(IV) compounds are typically strong oxidants or exist only in highly acidic solutions.

Wiklundite is a rare and complex arsenite-silicate mineral with the formula Pb2(Mn2+,Zn)3(Fe3+,Mn2+)2(Mn2+,Mg)19(As3+O3)2(Si,As5+O4)6(OH)18Cl6. The mineral characterizes in a large c unit cell parameter. It was found in Långban, Sweden - a home for many rare and exotic minerals.

References