Lead white is a thick, opaque, and heavy white pigment composed primarily of basic lead carbonate, 2PbCO3·Pb(OH)2, with a crystalline molecular structure. [1] : 67 [2] : 43 It was the most widely produced and used white pigment in different parts of the world from antiquity until the nineteenth century, when it was displaced by zinc white and later by titanium white. [1] : 69 Lead white has maintained relatively consistent production methods across times and regions, yet it has a wide range of applications in different contexts, such as home decoration, art production, and cosmetics. [2] : 43–45 Given its affordability and distinctive visual qualities, lead white was particularly favored and generously used by artists in their paintings. [2] : 44 However, most art supply companies now explicitly advise against the use of lead white because of the risk that it poses of lead poisoning. [3] Even after this drawback was known, it continued to be used in paintings and cosmetics. [2] : 45
As one of the oldest synthetically produced pigments, lead white has been artificially produced in different cultures and periods using roughly the same production methods. [1] : 68 A common technique in antiquity involved placing lead shavings above vinegar within specially designed clay pots, allowing the acidic vapors to react with the lead. As early as 300 B.C., such preparation of lead white from metallic lead and vinegar was probably used in China and later introduced to Japan in the seventh century. [1] : 68 [4] : 89 In seventeenth century Holland, the "Dutch" or "stack" method of producing lead white improved slightly upon the ancient process through the additional step of sealing clay pots in a room filled with horse manure or waste tan bark, which provided a source of heat and carbon dioxide, yielding basic lead carbonate through the combined action of the acetic vapors, carbonic acid, and heat. [1] : 68 [5] In England, a monopoly was granted for production of lead white in 1622. [1] : 68–69
Lead white has been widely used in various contexts across different cultures from ancient times to the present. Until the twentieth century, this highly versatile pigment was used in numerous applications, including enamel for ceramic tableware and bathroom fittings, house paints, and wallpapers. [2] : 44 Within the realm of painting, lead white was occasionally used in wall paintings and tempera paintings on paper and silk in early times in China and Japan. [1] : 69 Well into the nineteenth century, it was the sole white pigment used in European easel painting and had been widely adopted by artists due to its affordable costs and distinctive qualities, until the advent of zinc white. [1] : 68–69 [2] : 44 In modern times, titanium dioxide has largely taken the place of lead white due to safety concerns. [1] : 69
The danger of lead poisoning made lead white cosmetics especially hazardous. [2] : 44-46 In eighteenth-century Europe, upper-class men and women powdered their face and body with beauty products to accentuate their white complexion as a sign of their affluence. Lead white, one of the most popular ingredients used in cosmetics to whiten the skin, was favored for its opacity in spite of the well-known risk of lead poisoning. [7] : 39–41 In other cultural contexts such as Greece, China, and Japan, white lead had long been a popular cosmetic foundation to make skin look smooth and pale. [2] : 45 Despite the fatal danger of lead poisoning, the use of white lead in cosmetics persisted for an extended period of time in history across many cultures.
Given its high refractive index and low oil-absorption index, lead white generally requires a small amount of oil to make workable pastes with high hiding power. It has served to delineate forms in underpainting, for the modeling of bodies, and for highlights because of its high opacity and adherence. [1] : 69 [2] : 44 Today, when paintings are X-rayed, the often dense outline of lead white can appear as a kind of skeleton within a painting, indicating the underdrawing. [2] : 44 In addition to being used independently, lead white is frequently used to produce tints of other colors. In combination with blue, it appears often in depictions of the sky, and it is commonly used with red and brown pigments to create flesh tones. [1] : 69 Additionally, admixtures of lead white with other whites such as calcium carbonate and chalk for making opaque watercolor may also be encountered in paintings, especially those created by sixteenth and seventeenth-centuries Dutch artists. [1] : 67
Lead white is compatible with various binding media and has remarkable permanence, being lightfast. [1] : 71 However, its permanence also depends on its relationships to different media. Most of the lead white of European paintings was ground in vegetable drying oil, particularly linseed oil with superior drying properties. Once the mixture has completely dried, it results in a tough and resistant film that is less prone to swelling in organic solvents compared to other oil-pigment mixtures. [1] : 69 While lead white locked in a drying oil film and protected with varnish endures for centuries without blackening, it turns black when used in watercolor, as seen in the highlights of old master drawings, due to the presence of hydrogen sulfide in the air. [1] : 71–72
The ubiquity of lead white for much of recorded history makes its occurrences in both western and non-western art widespread. [1] : 78 Several examples, significant for their early date, are Fayum portraits from the second century CE. [8] Over eighty Dutch paintings dating from the mid-fifteenth to the mid-nineteenth centuries have been found to contain lead white. [1] : 78 Lead white can also be found in paintings well into the 20th century, including in the work of major artists such as Picasso. [1] : 78 There are a number of occurrences of lead white as a pigment in East Asian paintings, especially murals or silk paintings. [4] : 89 Most notable among them are the Dunhuang cave paintings found in western China, which date from the ninth or tenth century, as well as the Japanese wall paintings in the Daigo-ji Pagoda and the Korean mural paintings in Anak Tomb No. 3. [1] : 78 [2] : 43
Oil painting is a painting method involving the procedure of painting with pigments with a medium of drying oil as the binder. It has been the most common technique for artistic painting on canvas, wood panel or copper for several centuries, spreading from Europe to the rest of the world. The advantages of oil for painting images include "greater flexibility, richer and denser colour, the use of layers, and a wider range from light to dark". But the process is slower, especially when one layer of paint needs to be allowed to dry before another is applied.
Paint is a material or mixture that, when applied to a solid material and allowed to dry, adds a film-like layer. As art, this is used to create an image or images known as a painting. Paint can be made in many colors and types. Most paints are either oil-based or water-based, and each has distinct characteristics.
A pastel is an art medium that consist of powdered pigment and a binder. It can exist in a variety of forms, including a stick, a square, a pebble, or a pan of color, though other forms are possible. The pigments used in pastels are similar to those used to produce some other colored visual arts media, such as oil paints; the binder is of a neutral hue and low saturation. The color effect of pastels is closer to the natural dry pigments than that of any other process.
Ultramarine is a deep blue color pigment which was originally made by grinding lapis lazuli into a powder. Its lengthy grinding and washing process makes the natural pigment quite valuable—roughly ten times more expensive than the stone it comes from and as expensive as gold.
A pigment is a powder used to add color or change visual appearance. Pigments are completely or nearly insoluble and chemically unreactive in water or another medium; in contrast, dyes are colored substances which are soluble or go into solution at some stage in their use. Dyes are often organic compounds whereas pigments are often inorganic. Pigments of prehistoric and historic value include ochre, charcoal, and lapis lazuli.
Ochre, iron ochre, or ocher in American English, is a natural clay earth pigment, a mixture of ferric oxide and varying amounts of clay and sand. It ranges in colour from yellow to deep orange or brown. It is also the name of the colours produced by this pigment, especially a light brownish-yellow. A variant of ochre containing a large amount of hematite, or dehydrated iron oxide, has a reddish tint known as red ochre.
Vermilion is a color family and pigment most often used between antiquity and the 19th century from the powdered mineral cinnabar. It is synonymous with red orange, which often takes a modern form, but is 11% brighter.
Azurite is a soft, deep-blue copper mineral produced by weathering of copper ore deposits. During the early 19th century, it was also known as chessylite, after the type locality at Chessy-les-Mines near Lyon, France. The mineral, a basic carbonate with the chemical formula Cu3(CO3)2(OH)2, has been known since ancient times, and was mentioned in Pliny the Elder's Natural History under the Greek name kuanos (κυανός: "deep blue," root of English cyan) and the Latin name caeruleum. Copper (Cu2+) gives it its blue color.
Whitewash, calcimine, kalsomine, calsomine, or lime paint is a type of paint made from slaked lime (calcium hydroxide, Ca(OH)2) or chalk (calcium carbonate, CaCO3), sometimes known as "whiting". Various other additives are sometimes used.
Oil paint is a type of slow-drying paint that consists of particles of pigment suspended in a drying oil, commonly linseed oil. For several centuries the oil painting has been perhaps the most prestigious form in Western art, but oil paint has many practical uses, mainly because it is waterproof.
Cobalt glass—known as "smalt" when ground as a pigment—is a deep blue coloured glass prepared by including a cobalt compound, typically cobalt oxide or cobalt carbonate, in a glass melt. Cobalt is a very intense colouring agent and very little is required to show a noticeable amount of colour.
Distemper is a decorative paint and a historical medium for painting pictures, and contrasted with tempera. The binder may be glues of vegetable or animal origin. Soft distemper is not abrasion resistant and may include binders such as chalk, ground pigments, and animal glue. Hard distemper is stronger and wear-resistant and can include casein or linseed oil as binders.
Foundation is a liquid, cream, or powder makeup applied to the face and neck to create an even, uniform color to the complexion, cover flaws and, sometimes, to change the natural skin tone. Some foundations also function as a moisturizer, sunscreen, astringent or base layer for more complex cosmetics. Foundation applied to the body is generally referred to as "body painting" or "body makeup".
Venetian ceruse or Venetian white, also known as blanc de céruse de Venise and Spirits of Saturn, was a 16th-century cosmetic used as a skin whitener. It was in great demand and considered the best available at the time, supposedly containing the best quality white lead sourced from Venice, the global merchant capital at the time. It is similar to the regular ceruse, although it was marketed as better, more exclusive and more expensive than the regular ceruse variant. The regular ceruse white pigment is a basic lead carbonate of chemical formula 2 PbCO
3·Pb(OH)
2 while the mineral cerussite is a simple carbonate of lead.
Mummy brown, also known as Egyptian brown or Caput Mortuum, was a rich brown bituminous pigment with good transparency, sitting between burnt umber and raw umber in tint. The pigment was made from the flesh of mummies mixed with white pitch and myrrh. Mummy brown was extremely popular from the mid-eighteenth to the nineteenth centuries. However, fresh supplies of mummies diminished, and artists were less satisfied with the pigment's permanency and finish. By 1915, demand had significantly declined. Suppliers ceased to offer it by the middle of the twentieth century.
White lead is the basic lead carbonate 2PbCO3·Pb(OH)2. It is a complex salt, containing both carbonate and hydroxide ions. White lead occurs naturally as a mineral, in which context it is known as hydrocerussite, a hydrate of cerussite. It was formerly used as an ingredient for lead paint and a cosmetic called Venetian ceruse, because of its opacity and the satiny smooth mixture it made with dryable oils. However, it tended to cause lead poisoning, and its use has been banned in most countries.
Minium, also known as red lead or red lead oxide, is a bright orange red pigment that was widely used in the Middle Ages for the decoration of manuscripts and for painting. Often mistaken for less poisonous cinnabar and vermillion, minium was one of the earliest pigments artificially prepared and is still in use today. It was made by roasting white lead pigment in the air; the white lead would gradually turn yellow, then into an orange lead tetroxide. Minium's color varied depending upon how long the mineral was roasted.
Lead-tin yellow is a yellow pigment, of historical importance in oil painting, sometimes called the "Yellow of the Old Masters" because of the frequency with which it was used by those famous painters.
A colorant is any substance that changes the spectral transmittance or reflectance of a material. Synthetic colorants are those created in a laboratory or industrial setting. The production and improvement of colorants was a driver of the early synthetic chemical industry, in fact many of today's largest chemical producers started as dye-works in the late 19th or early 20th centuries, including Bayer AG(1863). Synthetics are extremely attractive for industrial and aesthetic purposes as they have they often achieve higher intensity and color fastness than comparable natural pigments and dyes used since ancient times. Market viable large scale production of dyes occurred nearly simultaneously in the early major producing countries Britain (1857), France (1858), Germany (1858), and Switzerland (1859), and expansion of associated chemical industries followed. The mid-nineteenth century through WWII saw an incredible expansion of the variety and scale of manufacture of synthetic colorants. Synthetic colorants quickly became ubiquitous in everyday life, from clothing to food. This stems from the invention of industrial research and development laboratories in the 1870s, and the new awareness of empirical chemical formulas as targets for synthesis by academic chemists. The dye industry became one of the first instances where directed scientific research lead to new products, and the first where this occurred regularly.
Green pigments are the materials used to create the green colors seen in painting and the other arts. Most come from minerals, particularly those containing compounds of copper. Green pigments reflect the green portions of the spectrum of visible light, and absorb the others. Important green pigments in art history include Malachite and Verdigris, found in tomb paintings in Ancient Egypt, and the Green earth pigments popular in the Middle Ages. More recent greens, such as Cobalt Green, are largely synthetic, made in laboratories and factories.