Leaded copper is a metal alloy of copper with lead. A small amount of lead makes the copper easier to machine. Alloys with a larger amount of lead are used for bearings. Brass and bronze alloys of copper may have lead added and are then also sometimes referred to as leaded copper alloys. [1] Leaded copper and its alloys have been used since ancient times.
Leaded copper alloys are used to make electrical connectors and mechanical bearings, especially in the automotive industry where high performance and reliability are required. Mechanical bearings can have high lead content. Such high lead content alloys are unsuitable for welding or brazing. [2]
Alloys with around 2-4% lead are used for machined copper applications, where the lead content lubricates the copper and makes it easier to machine. These include high-quality electrical connectors where a high current capacity and low electrical resistance are required. Such connectors are used in industrial automation and the automotive industry. [3] [1] Brasses (copper alloyed with zinc) may also be leaded for the same reason. [4]
High-strength casting copper alloys typically contain less than 2% lead. [1] Bearing alloys are often cast or sintered onto a steel backing. Softer alloys with a higher lead content are also used, for example in bushes where conformance to the opposite bearing surface is important. [5] [6]
Some casting alloys have over 20% lead content but, due to their toxicity, they are no longer used. [4]
When lead alloys wear, lead is released into the environment. It is a toxic heavy metal and in recent times the use of leaded copper alloys has been reduced. [1]
Signs of leaded copper use are found in the manufacture of ancient Egyptian faience. By 1500 BC leaded copper could be found across the Old World from East Asia to Africa and Europe. [7]
Enigmatic entries in a Chinese manuscript, the Kao Gong Ji dating from around 300 BC, were deciphered by scholars in 2022, and seem to indicate that a pre-prepared copper-lead alloy named Xi may have been used in the preparation of ancient bronzes. Another copper-tin-lead alloy named Jin was also tentatively identified as a pre-prepared component of Chinese bronzes. This part of the manuscript relates to an attempt to standardise the quality of bronze manufacture. [8] [9]
An alloy is a mixture of chemical elements of which in most cases at least one is a metallic element, although it is also sometimes used for mixtures of elements; herein only metallic alloys are described. Most alloys are metallic and show good electrical conductivity, ductility, opacity, and luster, and may have properties that differ from those of the pure elements such as increased strength or hardness. In some cases, an alloy may reduce the overall cost of the material while preserving important properties. In other cases, the mixture imparts synergistic properties such as corrosion resistance or mechanical strength.
Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally 66% copper and 34% zinc. In use since prehistoric times, it is a substitutional alloy: atoms of the two constituents may replace each other within the same crystal structure.
Bronze is an alloy consisting primarily of copper, commonly with about 12–12.5% tin and often with the addition of other metals and sometimes non-metals, such as phosphorus, or metalloids, such as arsenic or silicon. These additions produce a range of alloys that may be harder than copper alone, or have other useful properties, such as strength, ductility, or machinability.
Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys.
Pewter is a malleable metal alloy consisting of tin (85–99%), antimony, copper (2%), bismuth, and sometimes silver. In the past it was an alloy of tin and lead, but most modern pewter, in order to prevent lead poisoning, is not made with lead. Pewter has a low melting point, around 170–230 °C (338–446 °F), depending on the exact mixture of metals. The word pewter is possibly a variation of "spelter", a term for zinc alloys.
Copper is a chemical element; it has symbol Cu and atomic number 29. It is a soft, malleable, and ductile metal with very high thermal and electrical conductivity. A freshly exposed surface of pure copper has a pinkish-orange color. Copper is used as a conductor of heat and electricity, as a building material, and as a constituent of various metal alloys, such as sterling silver used in jewelry, cupronickel used to make marine hardware and coins, and constantan used in strain gauges and thermocouples for temperature measurement.
An ingot is a piece of relatively pure material, usually metal, that is cast into a shape suitable for further processing. In steelmaking, it is the first step among semi-finished casting products. Ingots usually require a second procedure of shaping, such as cold/hot working, cutting, or milling to produce a useful final product. Non-metallic and semiconductor materials prepared in bulk form may also be referred to as ingots, particularly when cast by mold based methods. Precious metal ingots can be used as currency, or as a currency reserve, as with gold bars.
The white metals are a series of often decorative bright metal alloys used as a base for plated silverware, ornaments or novelties, as well as any of several lead-based or tin-based alloys used for things like bearings, jewellery, miniature figures, fusible plugs, some medals and metal type. The term is also used in the antiques trade for an item suspected of being silver, but not hallmarked.
Phosphor bronze is a member of the family of copper alloys. It is composed of copper that is alloyed with 0.5–11% of tin and 0.01–0.35% phosphorus, and may contain other elements to confer specific properties. The tin increases the corrosion resistance and strength of the alloy, while the phosphorus increases its wear resistance and stiffness.
Babbitt metal or bearing metal is any of several alloys used for the bearing surface in a plain bearing.
Bell metal or bell bronze is an alloy used for making bells and related instruments, such as cymbals. It is a form of bronze with a higher tin content than most other bronzes, usually in approximately a 4:1 ratio of copper to tin. The higher tin content increases the rigidity of the metal, and increases the resonance. Historically, it was preferred for early cannons. Today, it also has industrial uses, being specified for valve bodies, piston rings, bearings, and bushings.
Gun metal, also known as red brass in the United States, is a type of bronze – an alloy of copper, tin, and zinc. Proportions vary but 88% copper, 8–10% tin, and 2–4% zinc is an approximation. Originally used chiefly for making guns, it has largely been replaced by steel for that purpose. Gunmetal casts and machines well, and is resistant to corrosion from steam and salt water. It is used to make steam and hydraulic castings, valves, gears, statues, and various small objects, such as buttons. It has a tensile strength of 221 megapascals (32,100 psi) to 310 megapascals (45,000 psi), a specific gravity of 8.7, a Brinell hardness of 65 to 74, and a melting point of around 1,000 degrees Celsius.
Panchaloha, also called Pañcadhātu, is a term for traditional five-metal alloys of sacred significance, used for making Hindu temple murti and jewelry.
Arsenical bronze is an alloy in which arsenic, as opposed to or in addition to tin or other constituent metals, is combined with copper to make bronze. The use of arsenic with copper, either as the secondary constituent or with another component such as tin, results in a stronger final product and better casting behavior.
Bismuth bronze or bismuth brass is a copper alloy which typically contains 1-3% bismuth by weight, although some alloys contain over 6% Bi. This bronze alloy is very corrosion-resistant, a property which makes it suitable for use in environments such as the ocean. Bismuth bronzes and brasses are more malleable, thermally conductive, and polish better than regular brasses. The most common industrial application of these metals is as bearings, however the material has been in use since the late nineteenth century as kitchenware and mirrors. Bismuth bronze was also found in ceremonial Inca knives at Machu Picchu. Recently, pressure for the substitution of hazardous metals has increased and with it bismuth bronze is being marketed as a green alternative to leaded bronze bearings and bushings.
Group 11, by modern IUPAC numbering, is a group of chemical elements in the periodic table, consisting of copper (Cu), silver (Ag), gold (Au), and roentgenium (Rg), although no chemical experiments have yet been carried out to confirm that roentgenium behaves like the heavier homologue to gold. Group 11 is also known as the coinage metals, due to their usage in minting coins—while the rise in metal prices mean that silver and gold are no longer used for circulating currency, remaining in use for bullion, copper remains a common metal in coins to date, either in the form of copper clad coinage or as part of the cupronickel alloy. They were most likely the first three elements discovered. Copper, silver, and gold all occur naturally in elemental form.
C41100 Lubaloy is a wrought copper alloy that is composed mainly of copper and zinc. Lubaloy possesses many favorable characteristics making it, and other types of brass, a popular choice in manufacturing. It is a source material in many processes including the creation of electrical components and bullet-making. There are both positive and negative health effects that are associated with the use of this material.
Diehl Metall is a corporate division of the Diehl Stiftung & Co. KG, a worldwide operating industrial group with its head office in Röthenbach an der Pegnitz near Nuremberg, Germany. The production units of Diehl Metall are situated at 13 locations in Europe, Asia, South America and the US. With 3,420 employees the company generated a turnover of €917 million in 2017. Diehl Metall produces semi-finished products, forgings and rolled products, high-precision stamped parts with plating technologies as well as Schempp+Decker press-fit zones and metal-plastic compound systems. The company provides material development and production, sheet metal forming and forging technology as well as plating, press-fit, overmolding and assembling technology completely in-house.