In particle physics, the Dirac equation is a relativistic wave equation derived by British physicist Paul Dirac in 1928. In its free form, or including electromagnetic interactions, it describes all spin-1⁄2 massive particles such as electrons and quarks for which parity is a symmetry. It is consistent with both the principles of quantum mechanics and the theory of special relativity, and was the first theory to account fully for special relativity in the context of quantum mechanics. It was validated by accounting for the fine details of the hydrogen spectrum in a completely rigorous way.
In physics, the Navier–Stokes equations are certain partial differential equations which describe the motion of viscous fluid substances, named after French engineer and physicist Claude-Louis Navier and Anglo-Irish physicist and mathematician George Gabriel Stokes. They were developed over several decades of progressively building the theories, from 1822 (Navier) to 1842–1850 (Stokes).
The vorticity equation of fluid dynamics describes the evolution of the vorticity ω of a particle of a fluid as it moves with its flow; that is, the local rotation of the fluid. The governing equation is:
In physics, the Hamilton–Jacobi equation, named after William Rowan Hamilton and Carl Gustav Jacob Jacobi, is an alternative formulation of classical mechanics, equivalent to other formulations such as Newton's laws of motion, Lagrangian mechanics and Hamiltonian mechanics. The Hamilton–Jacobi equation is particularly useful in identifying conserved quantities for mechanical systems, which may be possible even when the mechanical problem itself cannot be solved completely.
In differential geometry, the four-gradient is the four-vector analogue of the gradient from vector calculus.
Scale analysis is a powerful tool used in the mathematical sciences for the simplification of equations with many terms. First the approximate magnitude of individual terms in the equations is determined. Then some negligibly small terms may be ignored.
In electrochemistry, the Cottrell equation describes the change in electric current with respect to time in a controlled potential experiment, such as chronoamperometry. Specifically it describes the current response when the potential is a step function in time. It was derived by Frederick Gardner Cottrell in 1903. For a simple redox event, such as the ferrocene/ferrocenium couple, the current measured depends on the rate at which the analyte diffuses to the electrode. That is, the current is said to be "diffusion controlled." The Cottrell equation describes the case for an electrode that is planar but can also be derived for spherical, cylindrical, and rectangular geometries by using the corresponding laplace operator and boundary conditions in conjunction with Fick's second law of diffusion.
Acoustic streaming is a steady flow in a fluid driven by the absorption of high amplitude acoustic oscillations. This phenomenon can be observed near sound emitters, or in the standing waves within a Kundt's tube. Acoustic streaming was explained first by Lord Rayleigh in 1884. It is the less-known opposite of sound generation by a flow.
Equatorial waves are oceanic and atmospheric waves trapped close to the equator, meaning that they decay rapidly away from the equator, but can propagate in the longitudinal and vertical directions. Wave trapping is the result of the Earth's rotation and its spherical shape which combine to cause the magnitude of the Coriolis force to increase rapidly away from the equator. Equatorial waves are present in both the tropical atmosphere and ocean and play an important role in the evolution of many climate phenomena such as El Niño. Many physical processes may excite equatorial waves including, in the case of the atmosphere, diabatic heat release associated with cloud formation, and in the case of the ocean, anomalous changes in the strength or direction of the trade winds.
In the finite element method for the numerical solution of elliptic partial differential equations, the stiffness matrix represents the system of linear equations that must be solved in order to ascertain an approximate solution to the differential equation.
In cyclic voltammetry, the Randles–Ševčík equation describes the effect of scan rate on the peak current ip. For simple redox events such as the ferrocene/ferrocenium couple, ip depends not only on the concentration and diffusional properties of the electroactive species but also on scan rate.
In fluid dynamics, the Burgers vortex or Burgers–Rott vortex is an exact solution to the Navier–Stokes equations governing viscous flow, named after Jan Burgers and Nicholas Rott. The Burgers vortex describes a stationary, self-similar flow. An inward, radial flow, tends to concentrate vorticity in a narrow column around the symmetry axis. At the same time, viscous diffusion tends to spread the vorticity. The stationary Burgers vortex arises when the two effects balance.
Menter's Shear Stress Transport turbulence model, or SST, is a widely used and robust two-equation eddy-viscosity turbulence model used in Computational Fluid Dynamics. The model combines the k-omega turbulence model and K-epsilon turbulence model such that the k-omega is used in the inner region of the boundary layer and switches to the k-epsilon in the free shear flow.
In quantum probability, the Belavkin equation, also known as Belavkin-Schrödinger equation, quantum filtering equation, stochastic master equation, is a quantum stochastic differential equation describing the dynamics of a quantum system undergoing observation in continuous time. It was derived and henceforth studied by Viacheslav Belavkin in 1988.
A Levich constant (B) is often used in order to simplify the Levich equation. Furthermore, B is readily extracted from rotating disk electrode experimental data.
In electrochemistry, protein film voltammetry is a technique for examining the behavior of proteins immobilized on an electrode. The technique is applicable to proteins and enzymes that engage in electron transfer reactions and it is part of the methods available to study enzyme kinetics.
In fluid dynamics, Stokes problem also known as Stokes second problem or sometimes referred to as Stokes boundary layer or Oscillating boundary layer is a problem of determining the flow created by an oscillating solid surface, named after Sir George Stokes. This is considered one of the simplest unsteady problem that have exact solution for the Navier-Stokes equations. In turbulent flow, this is still named a Stokes boundary layer, but now one has to rely on experiments, numerical simulations or approximate methods in order to obtain useful information on the flow.
In fluid dynamics, Beltrami flows are flows in which the vorticity vector and the velocity vector are parallel to each other. In other words, Beltrami flow is a flow where Lamb vector is zero. It is named after the Italian mathematician Eugenio Beltrami due to his derivation of the Beltrami vector field, while initial developments in fluid dynamics were done by the Russian scientist Ippolit S. Gromeka in 1881.
The Koutecký–Levich equation models the measured electric current at an electrode from an electrochemical reaction in relation to the kinetic activity and the mass transport of reactants.
The Shvab–Zeldovich formulation is an approach to remove the chemical-source terms from the conservation equations for energy and chemical species by linear combinations of independent variables, when the conservation equations are expressed in a common form. Expressing conservation equations in common form often limits the range of applicability of the formulation. The method was first introduced by V. A. Shvab in 1948 and by Yakov Zeldovich in 1949.
