Microplastic remediation refers to environmental remediation techniques focused on the removal, treatment and containment of microplastics (small plastic particles) from environmental media such as soil, water, or sediment. [1]
Microplastics can be removed using physical, chemical, or biological techniques. [2]
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Microplastic is a type of airborne particulates and is found to prevail in air. [3] [4] [5]
Microplastics can be removed from water by filtration or absorption. Absorption devices include sponges made of cotton and squid bones. [6]
Biochar filtration has been used in wastewater treatment plants. [7]
Efforts to physically remove microplastics from the Great Pacific Garbage Patch have used nets and collection bags. [8]
Microplastics are commonly found in soil. [9] [10] Techniques are under development to achieve reductions in soil microplastics via photodegradation, chemical extraction, or bioremediation. [11] [12] [13]
Indoor air quality (IAQ) is the air quality within buildings and structures. Poor indoor air quality due to indoor air pollution is known to affect the health, comfort, and well-being of building occupants. It has also been linked to sick building syndrome, respiratory issues, reduced productivity, and impaired learning in schools. Common pollutants of indoor air include: secondhand tobacco smoke, air pollutants from indoor combustion, radon, molds and other allergens, carbon monoxide, volatile organic compounds, legionella and other bacteria, asbestos fibers, carbon dioxide, ozone and particulates.
Environmental remediation is the cleanup of hazardous substances dealing with the removal, treatment and containment of pollution or contaminants from environmental media such as soil, groundwater, sediment. Remediation may be required by regulations before development of land revitalization projects. Developers who agree to voluntary cleanup may be offered incentives under state or municipal programs like New York State's Brownfield Cleanup Program. If remediation is done by removal the waste materials are simply transported off-site for disposal at another location. The waste material can also be contained by physical barriers like slurry walls. The use of slurry walls is well-established in the construction industry. The application of (low) pressure grouting, used to mitigate soil liquefaction risks in San Francisco and other earthquake zones, has achieved mixed results in field tests to create barriers, and site-specific results depend upon many variable conditions that can greatly impact outcomes.
Bioremediation broadly refers to any process wherein a biological system, living or dead, is employed for removing environmental pollutants from air, water, soil, flue gasses, industrial effluents etc., in natural or artificial settings. The natural ability of organisms to adsorb, accumulate, and degrade common and emerging pollutants has attracted the use of biological resources in treatment of contaminated environment. In comparison to conventional physicochemical treatment methods bioremediation may offer advantages as it aims to be sustainable, eco-friendly, cheap, and scalable.
Plastic mulch is a product used in plasticulture in a similar fashion to mulch, to suppress weeds and conserve water in crop production and landscaping. Certain plastic mulches also act as a barrier to keep methyl bromide, both a powerful fumigant and ozone depleter, in the soil. Crops grow through slits or holes in thin plastic sheeting. Plastic mulch is often used in conjunction with drip irrigation. Some research has been done using different colors of mulch to affect crop growth. Use of plastic mulch is predominant in large-scale vegetable growing, with millions of acres cultivated under plastic mulch worldwide each year.
Phytoremediation technologies use living plants to clean up soil, air and water contaminated with hazardous contaminants. It is defined as "the use of green plants and the associated microorganisms, along with proper soil amendments and agronomic techniques to either contain, remove or render toxic environmental contaminants harmless". The term is an amalgam of the Greek phyto (plant) and Latin remedium. Although attractive for its cost, phytoremediation has not been demonstrated to redress any significant environmental challenge to the extent that contaminated space has been reclaimed.
Biological augmentation is the addition of archaea or bacterial cultures required to speed up the rate of degradation of a contaminant. Organisms that originate from contaminated areas may already be able to break down waste, but perhaps inefficiently and slowly.
Nonylphenols are a family of closely related organic compounds composed of phenol bearing a 9 carbon-tail. Nonylphenols can come in numerous structures, all of which may be considered alkylphenols. They are used in manufacturing antioxidants, lubricating oil additives, laundry and dish detergents, emulsifiers, and solubilizers. They are used extensively in epoxy formulation in North America but its use has been phased out in Europe. These compounds are also precursors to the commercially important non-ionic surfactants alkylphenol ethoxylates and nonylphenol ethoxylates, which are used in detergents, paints, pesticides, personal care products, and plastics. Nonylphenol has attracted attention due to its prevalence in the environment and its potential role as an endocrine disruptor and xenoestrogen, due to its ability to act with estrogen-like activity. The estrogenicity and biodegradation heavily depends on the branching of the nonyl sidechain. Nonylphenol has been found to act as an agonist of the GPER (GPR30).
Mycoremediation is a form of bioremediation in which fungi-based remediation methods are used to decontaminate the environment. Fungi have been proven to be a cheap, effective and environmentally sound way for removing a wide array of contaminants from damaged environments or wastewater. These contaminants include heavy metals, organic pollutants, textile dyes, leather tanning chemicals and wastewater, petroleum fuels, polycyclic aromatic hydrocarbons, pharmaceuticals and personal care products, pesticides and herbicides in land, fresh water, and marine environments.
Diisobutyl phthalate (DIBP) is a phthalate ester having the structural formula C6H4(COOCH2CH 2)2. It is formed by the esterification of isobutanol and phthalic anhydride. This and other phthalates are used as plasticizers due to their flexibility and durability. They are found in many industrial and personal products, such as lacquers, nail polish and cosmetics. DIBP can be absorbed via oral ingestion and dermal exposure. When it comes to excretion, DIBP is first converted into the hydrolytic monoester monoisobutyl phthalate (MIBP). The primary excretory route is urine, with biliary excretion being noted in minor amounts. DIBP has lower density and freezing point than the related compound dibutyl phthalate (DBP).
Triphenyl phosphate (TPhP) is the chemical compound with the formula OP(OC6H5)3. It is the simplest aromatic organophosphate. This colourless solid is the ester (triester) of phosphoric acid and phenol. It is used as a plasticizer and a fire retardant in a wide variety of settings and products.
Fluorotelomer alcohols, or FTOHs, are fluorotelomers with an alcohol functional group. They are volatile precursors to perfluorinated carboxylic acids, such as PFOA and PFNA, and other compounds.
The mercury cycle is a biogeochemical cycle influenced by natural and anthropogenic processes that transform mercury through multiple chemical forms and environments.
Microplastics are particles of any type of plastic less than 5 mm (0.20 in) in length, according to the U.S. National Oceanic and Atmospheric Administration (NOAA) and the European Chemicals Agency. US EPA researchers define microplastics, or MPs, as plastic particles ranging in size from 5 millimeters (mm), which is about the size of a pencil eraser, to 1 nanometer (nm). For comparison, a strand of human hair is about 80,000 nanometers wide.
Cytostasis is the inhibition of cell growth and multiplication. Cytostatic refers to a cellular component or medicine that inhibits cell division and induce cell death.
Three dimensional (3D) bioprinting is the use of 3D printing–like techniques to combine cells, growth factors, bio-inks, and biomaterials to fabricate functional structures that were traditionally used for tissue engineering applications but in recent times have seen increased interest in other applications such as biosensing, and environmental remediation. Generally, 3D bioprinting uses a layer-by-layer method to deposit materials known as bio-inks to create tissue-like structures that are later used in various medical and tissue engineering fields. 3D bioprinting covers a broad range of bioprinting techniques and biomaterials. Currently, bioprinting can be used to print tissue and organ models to help research drugs and potential treatments. Nonetheless, translation of bioprinted living cellular constructs into clinical application is met with several issues due to the complexity and cell number necessary to create functional organs. However, innovations span from bioprinting of extracellular matrix to mixing cells with hydrogels deposited layer by layer to produce the desired tissue. In addition, 3D bioprinting has begun to incorporate the printing of scaffolds which can be used to regenerate joints and ligaments. Apart from these, 3D bioprinting has recently been used in environmental remediation applications, including the fabrication of functional biofilms that host functional microorganisms that can facilitate pollutant removal.
The plastisphere is a human-made ecosystem consisting of organisms able to live on plastic waste. Plastic marine debris, most notably microplastics, accumulates in aquatic environments and serves as a habitat for various types of microorganisms, including bacteria and fungi. As of 2022, an estimated 51 trillion microplastics are floating in the surface water of the world's oceans. A single 5mm piece of plastic can host 1,000s of different microbial species. Some marine bacteria can break down plastic polymers and use the carbon as a source of energy.
Bioremediation of petroleum contaminated environments is a process in which the biological pathways within microorganisms or plants are used to degrade or sequester toxic hydrocarbons, heavy metals, and other volatile organic compounds found within fossil fuels. Oil spills happen frequently at varying degrees along with all aspects of the petroleum supply chain, presenting a complex array of issues for both environmental and public health. While traditional cleanup methods such as chemical or manual containment and removal often result in rapid results, bioremediation is less labor-intensive, expensive, and averts chemical or mechanical damage. The efficiency and effectiveness of bioremediation efforts are based on maintaining ideal conditions, such as pH, RED-OX potential, temperature, moisture, oxygen abundance, nutrient availability, soil composition, and pollutant structure, for the desired organism or biological pathway to facilitate reactions. Three main types of bioremediation used for petroleum spills include microbial remediation, phytoremediation, and mycoremediation. Bioremediation has been implemented in various notable oil spills including the 1989 Exxon Valdez incident where the application of fertilizer on affected shoreline increased rates of biodegradation.
2-Ethylhexyl diphenyl phosphate (Octicizer) is an organophosphate compound. It acts as both a plasticizer and flame retardant in PVC, its wide liquid range also makes it suitable as a flame retardant in hydraulic fluids. It has low acute toxicity in feeding experiments, but has been implicated as a potential hormone mimetic.
Legacy pollution or legacy pollutants are persistent materials in the environment that were created through a polluting industry or process that have polluting effects after the process has finished. Frequently these include persistent organic pollutants, heavy metals or other chemicals residual in the environment long after the industrial or extraction processes that produced them. Often these are chemicals produced by industry and polluted before there was widespread awareness of the toxic effects of the pollutants, and subsequently regulated or banned. Notable legacy pollutants include mercury, PCBs, Dioxins and other chemicals that are widespread health and environmental effects. Sites for legacy pollutants include mining sites, industrial parks, waterways contaminated by industry, and other dump sites.
Microplastics effects on human health are of growing concern and an area of research. The tiny particles known as microplastics (MPs), have been found in various environmental and biological matrices, including air, water, food, and human tissues. Microplastics, defined as plastic fragments smaller than 5 mm, and even smaller particles such as nanoplastics (NP), particles smaller than 1000 nm in diameter, have raised concerns impacting human health. The pervasive presence of plastics in our environment has raised concerns about their long-term impacts on human health. While visible pollution caused by larger plastic items is well-documented, the hidden threat posed by nanoplastics remains under-explored. These particles originate from the degradation of larger plastics and are now found in various environmental matrices, including water, soil, and air. Given their minute size, nanoplastics can penetrate biological barriers and accumulate in human tissues, potentially leading to adverse health effects.