Mohamed H. Alkordi | |
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| Nationality | Egyptian |
| Academic background | |
| Education | Alexandria University University of South Florida |
| Academic work | |
| Discipline | Materials Science |
| Institutions | Zewail City of Science and Technology |
Mohamed H. Alkordi is a Professor of Materials Science,co-director of the Center for Material Science and Director of the Research Office at Zewail City of Science and Technology. [1]
Alkordi earned his B.Sc. in Chemistry and Physics from Alexandria University in 2005,and his Ph.D. in chemistry from the University of South Florida,Tampa,Florida,USA,in 2010.
His current research interests are within the realm of innovation and engineering of novel material for mitigating the environmental impact of modern society's activities,focusing on wastewater treatment [2] as well as innovative energy storage and conversion applications. His work is primarily in microporous solids,known as Metal-Organic Frameworks,constructed through the self-assembly of molecular precursors. The permanent porosity of these materials allows for their utilization in a myriad of demanding applications where the chemical space within the pores of such solids can readily be tuned and,further,designed. Of primary interest to his research is to gain a more in-depth understanding of the structure-function relationships pertinent to the nanospace within microporous solids. It is through a better understanding of such fundamental aspects of microporous solids that we can outline blueprint designs to generate novel material tailored to specific applications. Among the applications his group is targeting are wastewater treatment through inventive materials for the capture of heavy metals,organic small molecules,and Perfluorinated compound. Additionally,his research includes designing new material for energy storage (Supercapacitor and Rechargeable battery) and energy conversion through microporous catalysts [3] in electrocatalytic water splitting.
His research accomplishments have been recognized by several awards and honors,including "State Encouragement Award",and "Presidential Excellence Accolade of First Grade" in 2016, [4] Best research article in COMSTECH in 2017, [5] [6] and Selected among world's Top 1% reviewers for Materials Science,awarded by Publons in 2018 and 2019. [7] He also received the Alexander von Humboldt-Georg Forster Experienced Researchers Fellowship in 2019–2023, [8] was selected as a Fellow of the African Academy of Sciences in 2019 [9] and Fellow of the Royal Society of Chemistry in 2021. [10]
Metal–organic frameworks (MOFs) are a class of porous polymers consisting of metal clusters coordinated to organic ligands to form one-,two- or three-dimensional structures. The organic ligands included are sometimes referred to as "struts" or "linkers",one example being 1,4-benzenedicarboxylic acid (BDC).
Zeolitic imidazolate frameworks (ZIFs) are a class of metal-organic frameworks (MOFs) that are topologically isomorphic with zeolites. ZIFs are composed of tetrahedrally-coordinated transition metal ions connected by imidazolate linkers. Since the metal-imidazole-metal angle is similar to the 145°Si-O-Si angle in zeolites,ZIFs have zeolite-like topologies. As of 2010,105 ZIF topologies have been reported in the literature. Due to their robust porosity,resistance to thermal changes,and chemical stability,ZIFs are being investigated for applications such as carbon dioxide capture.
Omar M. Yaghi is the James and Neeltje Tretter Chair Professor of Chemistry at the University of California,Berkeley,an affiliate scientist at Lawrence Berkeley National Laboratory,the Founding Director of the Berkeley Global Science Institute,and an elected member of the US National Academy of Sciences as well as the German National Academy of Sciences Leopoldina.
Jing Li is a Board of Governors Professor of Chemistry and Chemical Biology at Rutgers University,New Jersey,United States. She and her team are engaged in solid-state,inorganic and inorganic-organic hybrid materials research. Her current research focuses on designing and developing new functional materials including metal-organic frameworks and hybrid semiconductors for applications in the field of renewable and sustainable energy,and clean environment.
Covalent organic frameworks (COFs) are a class of porous polymers that form two- or three-dimensional structures through reactions between organic precursors resulting in strong,covalent bonds to afford porous,stable,and crystalline materials. COFs emerged as a field from the overarching domain of organic materials as researchers optimized both synthetic control and precursor selection. These improvements to coordination chemistry enabled non-porous and amorphous organic materials such as organic polymers to advance into the construction of porous,crystalline materials with rigid structures that granted exceptional material stability in a wide range of solvents and conditions. Through the development of reticular chemistry,precise synthetic control was achieved and resulted in ordered,nano-porous structures with highly preferential structural orientation and properties which could be synergistically enhanced and amplified. With judicious selection of COF secondary building units (SBUs),or precursors,the final structure could be predetermined,and modified with exceptional control enabling fine-tuning of emergent properties. This level of control facilitates the COF material to be designed,synthesized,and utilized in various applications,many times with metrics on scale or surpassing that of the current state-of-the-art approaches.
Kenneth S. Suslick is the Marvin T. Schmidt Professor of Chemistry Emeritus at the University of Illinois at Urbana–Champaign. His area of focus is on the chemical and physical effects of ultrasound,sonochemistry,and sonoluminescence. In addition,he has worked in the fields of artificial and machine olfaction,electronic nose technology,chemical sensor arrays,and the use of colorimetric sensor arrays as an optoelectronic nose.
In crystallography,a periodic graph or crystal net is a three-dimensional periodic graph,i.e.,a three-dimensional Euclidean graph whose vertices or nodes are points in three-dimensional Euclidean space,and whose edges are line segments connecting pairs of vertices,periodic in three linearly independent axial directions. There is usually an implicit assumption that the set of vertices are uniformly discrete,i.e.,that there is a fixed minimum distance between any two vertices. The vertices may represent positions of atoms or complexes or clusters of atoms such as single-metal ions,molecular building blocks,or secondary building units,while each edge represents a chemical bond or a polymeric ligand.
A two-dimensional polymer (2DP) is a sheet-like monomolecular macromolecule consisting of laterally connected repeat units with end groups along all edges. This recent definition of 2DP is based on Hermann Staudinger's polymer concept from the 1920s. According to this,covalent long chain molecules ("Makromoleküle") do exist and are composed of a sequence of linearly connected repeat units and end groups at both termini.
Adam J. Matzger,a researcher in polymers and crystals,is the Charles G. Overberger Collegiate Professor of Chemistry at the University of Michigan.
Hong-Cai (Joe) Zhou is a Chinese–American chemist and academic. He is the Davidson Professor of Science and Robert A. Welch Chair in Chemistry at Texas A&M University. He is also the associate editor of the journal Inorganic Chemistry.
MOF-5 or IRMOF-1 is a cubic metal–organic framework compound with the formula Zn4O(BDC)3,where BDC2− = 1,4-benzodicarboxylate (MOF-5). It was discovered by Omar M. Yaghi. MOF-5 is notable for exhibiting one of the highest surface area to volume ratios among metal–organic frameworks,at 2200 m2/cm3. Additionally,it was the first metal–organic framework studied for hydrogen gas storage.
Omar K. Farha is the Charles E. and Emma H. Morrison Professor in Chemistry at Northwestern University,an Executive Editor for ACS Applied Materials &Interfaces,and President of Numat.
Mircea Dincă is a Romanian-American inorganic chemist. He is a Professor of Chemistry and W. M. Keck Professor of Energy at the Massachusetts Institute of Technology (MIT). At MIT,Dincăleads a research group that focuses on the synthesis of functional metal-organic frameworks (MOFs),which possess conductive,catalytic,and other material-favorable properties.
Jeffrey Robert Long is a professor of chemistry at the University of California,Berkeley known for his work in metal−organic frameworks and molecular magnetism. He was elected to the American Academy of Arts and Sciences in 2019 and is the 2019 F. Albert Cotton Award recipient. His research interests include:the synthesis of inorganic clusters and porous materials,investigating the electronic and magnetic properties of inorganic materials;metal-organic frameworks,and gas storage/capture.
MIL-53 belongs to the class of metal-organic framework (MOF) materials. The first synthesis and the name was established by the group of Gérard Férey in 2002. The MIL-53 structure consists of inorganic [M-OH] chains,which are connected to four neighboring inorganic chains by therephthalate-based linker molecules. Each metal center is octahedrally coordinated by six oxygen atoms. Four of these oxygen atoms originate from four different carboxylate groups and the remaining two oxygen atoms belong to two different μ-OH moieties,which bridge neighboring metal centers. The resulting framework structure contains one-dimensional diamond-shaped pores. Many research group have investigated the flexibility of the MIL-53 structure. This flexible behavior,during which the pore cross-section changes reversibly,was termed 'breathing effect' and describes the ability of the MIL-53 framework to respond to external stimuli.
HKUST-1,which is also called MOF-199,is a material in the class of metal-organic frameworks (MOFs). Metal-organic frameworks are crystalline materials,in which metals are linked by ligands to form repeating coordination motives extending in three dimensions. The HKUST-1 framework is built up of dimeric metal units,which are connected by benzene-1,3,5-tricarboxylate linker molecules. The paddlewheel unit is the commonly used structural motif to describe the coordination environment of the metal centers and also called secondary building unit (SBU) of the HKUST-1 structure. The paddlewheel is built up of four benzene-1,3,5-tricarboxylate linkers molecules,which bridge two metal centers. One water molecules is coordinated to each of the two metal centers at the axial position of the paddlewheel unit in the hydrated state,which is usually found if the material is handled in air. After an activation process,these water molecules can be removed and the coordination site at the metal atoms is left unoccupied. This unoccupied coordination site is called coordinatively unsaturated site (CUS) and can be accessed by other molecules.
Wendy Lee Queen is an American chemist and material scientist. Her research interest focus on development design and production of hybrid organic/inorganic materials at the intersection of chemistry,chemical engineering and material sciences. As of 2020 she is a tenure-track assistant professor at the École polytechnique fédérale de Lausanne (EPFL) in Switzerland,where she directs the Laboratory for Functional Inorganic Materials.
Jorge Gascon is a Professor of Chemical Engineering at King Abdullah University of Science and Technology,director of the KAUST Catalysis Center. and a group leader of Advanced Catalytic Materials group
Kenneth J. Balkus,Jr. is an American chemist and materials scientist. He is professor of chemistry and former department chair at The University of Texas at Dallas. He is a Fellow of the American Chemical Society and a recipient of the ACS Doherty Award. His well known work is synthesis of zeolite UTD-1,the first high-silica zeolite to contain a one-dimensional,extra-large 14-ring pore system. Other notable work include rare-earth metal organic frameworks. He is editor to Journal of Porous Materials,Springer. He is also co-founder of DB Therapeutics,a company developing cancer therapies.
Carboxylate–based metal–organic frameworks are metal–organic frameworks that are based on organic molecules comprising carboxylate functional groups.
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