Humidity is the concentration of water vapor present in the air. Water vapor, the gaseous state of water, is generally invisible to the human eye. Humidity indicates the likelihood for precipitation, dew, or fog to be present.
Coalbed methane extraction is a method for extracting methane from a coal deposit. Coal bed methane (CBM) is one of the factors restricting safe production of coal in underground coal mines. It is also a form of high-quality energy that can be used in many fields such as power generation, heating, and chemical industries. CBM extraction is therefore carried out prior to extraction with a view of increasing the safety of mining coal beds, and as a useful energy resource to be exploited.
Adsorption is the adhesion of atoms, ions or molecules from a gas, liquid or dissolved solid to a surface. This process creates a film of the adsorbate on the surface of the adsorbent. This process differs from absorption, in which a fluid is dissolved by or permeates a liquid or solid. Adsorption is a surface phenomenon, while absorption involves the whole volume of the material, although adsorption does often precede absorption. The term sorption encompasses both processes, while desorption is the reverse of it.
A dehumidifier is an air conditioning device which reduces and maintains the level of humidity in the air. This is done usually for health or thermal comfort reasons, or to eliminate musty odor and to prevent the growth of mildew by extracting water from the air. It can be used for household, commercial, or industrial applications. Large dehumidifiers are used in commercial buildings such as indoor ice rinks and swimming pools, as well as manufacturing plants or storage warehouses. Typical air conditioning systems combine dehumidification with cooling, by operating cooling coils below the dewpoint and draining away the water that condenses.
A desiccant is a hygroscopic substance that is used to induce or sustain a state of dryness (desiccation) in its vicinity; it is the opposite of a humectant. Commonly encountered pre-packaged desiccants are solids that absorb water. Desiccants for specialized purposes may be in forms other than solid, and may work through other principles, such as chemical bonding of water molecules. They are commonly encountered in foods to retain crispness. Industrially, desiccants are widely used to control the level of water in gas streams.
Psychrometrics is the field of engineering concerned with the physical and thermodynamic properties of gas-vapor mixtures.
In chemistry, absorption is a physical or chemical phenomenon or a process in which atoms, molecules or ions enter some bulk phase – liquid or solid material. This is a different process from adsorption, since molecules undergoing absorption are taken up by the volume, not by the surface.
Desorption is the physical process where a previously adsorbed substance is released from a surface. This happens when a molecule gains enough energy to overcome the activation barrier of the bounding energy that keeps it in the surface.
Brunauer–Emmett–Teller (BET) theory aims to explain the physical adsorption of gas molecules on a solid surface and serves as the basis for an important analysis technique for the measurement of the specific surface area of materials. The observations are very often referred to as physical adsorption or physisorption. In 1938, Stephen Brunauer, Paul Hugh Emmett, and Edward Teller presented their theory in the Journal of the American Chemical Society. BET theory applies to systems of multilayer adsorption that usually utilizes a probing gas (called the adsorbate) that do not react chemically with the adsorptive (the material upon which the gas attaches to and the gas phase is called the adsorptive) to quantify specific surface area. Nitrogen is the most commonly employed gaseous adsorbate for probing surface(s). For this reason, standard BET analysis is most often conducted at the boiling temperature of N2 (77 K). Other probing adsorbates are also utilized, albeit less often, allowing the measurement of surface area at different temperatures and measurement scales. These include argon, carbon dioxide, and water. Specific surface area is a scale-dependent property, with no single true value of specific surface area definable, and thus quantities of specific surface area determined through BET theory may depend on the adsorbate molecule utilized and its adsorption cross section.
Moisture vapor transmission rate (MVTR), also water vapor transmission rate (WVTR), is a measure of the passage of water vapor through a substance. It is a measure of the permeability for vapor barriers.
Wood drying reduces the moisture content of wood before its use. When the drying is done in a kiln, the product is known as kiln-dried timber or lumber, whereas air drying is the more traditional method.
Moisture analysis covers a variety of methods for measuring moisture content in solids, liquids, or gases. For example, moisture is a common specification in commercial food production. There are many applications where trace moisture measurements are necessary for manufacturing and process quality assurance. Trace moisture in solids must be known in processes involving plastics, pharmaceuticals and heat treatment. Fields that require moisture measurement in gasses or liquids include hydrocarbon processing, pure semiconductor gases, bulk pure or mixed gases, dielectric gases such as those in transformers and power plants, and natural gas pipeline transport.
In thermodynamics and chemical engineering, the vapor–liquid equilibrium (VLE) describes the distribution of a chemical species between the vapor phase and a liquid phase.
Capillary condensation is the "process by which multilayer adsorption from the vapor [phase] into a porous medium proceeds to the point at which pore spaces become filled with condensed liquid from the vapor [phase]." The unique aspect of capillary condensation is that vapor condensation occurs below the saturation vapor pressure, Psat, of the pure liquid. This result is due to an increased number of van der Waals interactions between vapor phase molecules inside the confined space of a capillary. Once condensation has occurred, a meniscus immediately forms at the liquid-vapor interface which allows for equilibrium below the saturation vapor pressure. Meniscus formation is dependent on the surface tension of the liquid and the shape of the capillary, as shown by the Young-Laplace equation. As with any liquid-vapor interface involving a meniscus, the Kelvin equation provides a relation for the difference between the equilibrium vapor pressure and the saturation vapor pressure. A capillary does not necessarily have to be a tubular, closed shape, but can be any confined space with respect to its surroundings.
Supercritical adsorption also referred to as the adsorption of supercritical fluids, is the adsorption at above-critical temperatures. There are different tacit understandings of supercritical fluids. For example, “a fluid is considered to be ‘supercritical’ when its temperature and pressure exceed the temperature and pressure at the critical point”. In the studies of supercritical extraction, however, “supercritical fluid” is applied for a narrow temperature region of 1-1.2 or to +10 K, which is called the supercritical region.
Dynamic vapor sorption (DVS) is a gravimetric technique that measures how quickly and how much of a solvent is absorbed by a sample: such as a dry powder absorbing water. It does this by varying the vapor concentration surrounding the sample and measuring the change in mass which this produces. Water vapor is most commonly used, but it is also possible to use a wide range of organic solvents.
Water activity (aw) is the partial vapor pressure of water in a solution divided by the standard state partial vapor pressure of water. In the field of food science, the standard state is most often defined as pure water at the same temperature. Using this particular definition, pure distilled water has a water activity of exactly one. Water activity is the thermodynamic activity of water as solvent and the relative humidity of the surrounding air after equilibration. As temperature increases, aw typically increases, except in some products with crystalline salt or sugar.
A thermal wheel, also known as a rotary heat exchanger, or rotary air-to-air enthalpy wheel, energy recovery wheel, or heat recovery wheel, is a type of energy recovery heat exchanger positioned within the supply and exhaust air streams of air-handling units or rooftop units or in the exhaust gases of an industrial process, in order to recover the heat energy. Other variants include enthalpy wheels and desiccant wheels. A cooling-specific thermal wheel is sometimes referred to as a Kyoto wheel.
The Cromer cycle is a thermodynamic cycle that uses a desiccant to interact with higher relative humidity air leaving a cold surface. When a system is taken through a series of different states and finally returned to its initial state, a thermodynamic cycle is said to have occurred. The desiccant absorbs moisture from the air leaving the cold surface, releasing heat and drying the air, which can be used in a process requiring dry air. The desiccant is then dried by an air stream at a lower relative humidity, where the desiccant gives up its moisture by evaporation, increasing the air's relative humidity and cooling it. This cooler, moister air can then be presented to the same cold surface as above to take it below its dew point and dry it further, or it can be expunged from the system.
