Nickel ternary chalcogenides

Last updated October 01, 2020

The Nickel ternary chalcogenides are a class of chemical compounds that contains nickel, a chalcogenide, and another element. Nickel forms a series of double nickel oxides with other elements, which may be termed "nickelates". These double nickel oxides are not listed on this page. There are also many well defined double compounds with sulfur, selenium and tellurium which are listed here.

formula	name	colour	structure	production	references
NH₄NiS₅	ammonium nickel sulphide	black		NH₄ polysulfide+NiSO₄	^[1]^[2]
K₂Ni₃S₄	potassium nickel tetrasulfide	bronze yellow	Fddd a=10.023 b=26.074 c=5.704	NiSO₄ K₂CO₃ S	^[1]^[3]^[4]
K₂Ni₁₁S₁₀	potassium nickel decasulfide	dark metallic green		NiO+KCNS	^[1] J. Milbauer
Na₂Ni₃S₄	sodium nickel tetrasulfide	dark yellow		NiSO₄ Na₂CO₃ S	^[1] R. Schneider
KNi₂S₂	potassium dinickel disulfide	orange yellow		Ni foil, S, K at 723K	^[5]^[6]
K₂Ni₃Se₄	potassium nickel tetraselenide	gold	Fddd a=10.468 b=26.496 c=5.995		^[7]^[8]
KNi₂Se₂	potassium dinickel diselenide	purple-red	I4/mmmtetragonal a=3.909, c=13.4142	Ni foil, Se shot, K at 723K	^[5]^[9]
CsNi₂Se₂	caesium dinickel diselenide		tetragonal a=3.988, c=14.419	heat elements	^[10]
TlNi₂Se₂	Thallium dinickel diselenide	gold metallic	tetragonal	heat elements together in closed quartz tube	^[11]
Rb₂Ni₃S₄	rubidium nickel tetrasulphide	metallic greenish gold	Fmmm orthorhombic a=9.901 Å, b=13.606 Å and c=5.861 Z=4 layered; ferromagnetic only after water immersion		^[7]^[12]
Rb₂Ni₃Se₄	rubidium nickel tetraselenide	golden metallic	Fddd orthorhombic a = 10.555 Å, b = 27.588 Å, c = 6.031 Å, Z = 8 layered; ferromagnetic only after water immersion	Rb₂CO₃ S Ni	^[13]
Cs₂Ni₃S₄	cesium nickel tetrasulphide	greenish gold	Fmmm a=10.038 b=14.552 c=5.934		^[8]^[13]
Cs₂Ni₃S₄	cesium nickel tetrasulphide	gold	Fmmm a=10.540 b=14.624 c=6.194		^[8]
Cs_0.9Ni_3.1Se₃			Hexagonal P6₃/m a = 9.26301(4) Å and c = 4.34272(2) Å	quasi-one-dimensional electric conductor	^[14]
BaNi₄S₅	Barium nickel pentasulfide	bronze yellow		NiSO₄ K₂CO₃ S	^[1] R. Schneider; I. and L. Bellucci
Pb₂Ni₃S₂	lead nickel disulfide	melt 790°		PbS Ni	^[15] W Guertler; W Guertler H Schack
(Ni,Fe)₉S₈	Pentlandite	bronze yellow melt 870			^[15] T. Scheerer
Fe₂Ni₂S₄	ferrous nickel tetrasulfide	melt 840			^[16] K Bornemann
Fe₂Ni₂S₃	ferrous nickel trisulfide	stable over 575°, melt 886,			^[17] K Bornemann
Fe₃Ni₄S₅	ferrous nickel pentasulfide			below 575	^[17] K Bornemann
Fe₄Ni₂S₅					^[17] K Bornemann
Fe₂Ni₃S₄					^[17] K Bornemann
Fe₃Ni₄S₅					^[17] K Bornemann
Fe₂Ni₂S₃					^[17] K Bornemann
FeNi₂S₄	Violarite	dark violet grey		mineral oxidate
Ni₃Sn₂S₂					^[18]
Ni₃Bi₂S₂				superconducting	^[18]
Ni₃Bi₂Se₂				superconducting	^[18]
NiSnS₃	nickel thiostannate	greenish black	orthorhombic a=6.88 b=7.89 c=11.95 Z=8 V=644	NiCl₂ + SnS₂	^[19]
NiGeS3₃	nickelselenogermanate				^[20]
Ta₂NiS₅			Orthorhombic		^[21]
Ta₂NiSe₅			monoclinic β=90.53		^[21]
Ta₂Ni₂Te₄					^[22]
Ta₂Ni₃Te₅					^[22]

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References

1 2 3 4 5 Mellor p443
↑ Ephraim, Fritz (17 September 1923). "Über Nickelsulfid". Berichte der Deutschen Chemischen Gesellschaft (A and B Series) (in German). 56 (8): 1885–1886. doi:10.1002/cber.19230560825.
↑ Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle". Zeitschrift für anorganische und allgemeine Chemie (in German). 375 (1): 1–7. doi:10.1002/zaac.19703750102.
↑ Schneider, R. (1874). "Ueber neue Schwefelsalze". Annalen der Physik und Chemie. 227 (3): 437–450. Bibcode:1874AnP...227..437S. doi:10.1002/andp.18742270306.
1 2 Hlukhyy, Viktor; Trots, Dmytro; Fässler, Thomas F. (13 January 2017). "First-Order Phase Transition in BaNi2Ge2 and the Influence of the Valence Electron Count on Distortion of the ${\ce {ThCr2 Si2}}$ Structure Type". Inorganic Chemistry. 56 (3): 1173–1185. doi:10.1021/acs.inorgchem.6b02190. PMID 28085271.
↑ Neilson, James R.; McQueen, Tyrel M.; Llobet, Anna; Wen, Jiajia; Suchomel, Matthew R. (24 January 2013). "Charge density wave fluctuations, heavy electrons, and superconductivity in ${\ce {KNi2 S2}}$ ". Physical Review B. 87 (4): 045124. arXiv: 1212.4744 . Bibcode:2013PhRvB..87d5124N. doi:10.1103/PhysRevB.87.045124. S2CID 119117667.
1 2 Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle". Zeitschrift für anorganische und allgemeine Chemie. 375 (1): 1–7. doi:10.1002/zaac.19703750102.
1 2 3 Bronger, W.; Rennau, R.; Schmitz, D. (May 1991). "Schichtstrukturen ternärer Chalkogenide ${\ce {A2M3X4}}$ (A ? K, Rb, Cs; M ? Ni, Pd, Pt; X ? S, Se)". Zeitschrift für anorganische und allgemeine Chemie. 597 (1): 27–32. doi:10.1002/zaac.19915970105.
↑ Neilson, James R.; McQueen, Tyrel M. (9 May 2012). "Bonding, Ion Mobility, and Rate-Limiting Steps in Deintercalation Reactions with ${\ce {ThCr2Si2}}$ -type ${\ce {KNi2 Se2}}$ ". Journal of the American Chemical Society. 134 (18): 7750–7757. doi:10.1021/ja212012k. PMID 22530571.
↑ Huimin Chen; Yang, Jinhu; Cao, Chao; Li, Lin; Su, Qiping; Chen, Bin; Wang, Hangdong; Mao, Qianhui; Xu, Binjie; Du, Jianhua; Minghu Fang (1 April 2016). "Superconductivity in a new layered nickel selenide ${\ce {CsNi2Se2}}$ ". Superconductor Science and Technology. 29 (4): 045008. arXiv: 1508.05167 . Bibcode:2016SuScT..29d5008C. doi:10.1088/0953-2048/29/4/045008. S2CID 119179572.
↑ Wang, Hangdong; Dong, Chiheng; Mao, Qianhui; Khan, Rajwali; Zhou, Xi; Li, Chenxia; Chen, Bin; Yang, Jinhu; Su, Qiping; Fang, Minghu (12 November 2013). "Multiband Superconductivity of Heavy Electrons in a ${\ce {TlNi2Se2}}$ Single Crystal". Physical Review Letters. 111 (20): 207001. arXiv: 1303.4658 . Bibcode:2013PhRvL.111t7001W. doi:10.1103/PhysRevLett.111.207001. PMID 24289702. S2CID 28240997.
↑ Hasegawa, Takumi; Inui, Mitsutaka; Hondou, Katsuhiro; Fujiwara, Yishihiro; Kato, Tetsuya; Iio, Katsunori (February 2004). "Raman spectroscopy on ternary transition metal chalcogenide ${\ce {Rb2Ni3S4}}$ ". Journal of Alloys and Compounds. 364 (1–2): 199–207. doi:10.1016/S0925-8388(03)00503-6.
1 2 Bronger, Welf; Rennau, R. M.; Schmitz, D. (April 1996). "Darstellung und Kristallstruktur von ${\ce {Rb2Ni3Se4}}$ ". Zeitschrift für anorganische und allgemeine Chemie. 622 (4): 627–629. doi:10.1002/zaac.19966220409.
↑ Sun, Fan; Guo, Zhongnan; Liu, Ning; Wu, Dan; Lin, Jiawei; Cheng, Erjian; Ying, Tianping; Li, Shiyan; Yuan, Wenxia (16 March 2018). " ${\ce {Cs}}_{0.9}{\ce {Ni}}_{3.1}{\ce {Se3}}$ : A Ni-Based Quasi-One-Dimensional Conductor with Spin-Glass Behavior". Inorganic Chemistry. 57 (7): 3798–3804. doi:10.1021/acs.inorgchem.7b03143. PMID 29546755.
1 2 Mellor p444
↑ Mellor p445
1 2 3 4 5 6 Mellor p446
1 2 3 Rommel, Stefan Michael; Krach, Alexander; Peter, Philipp; Weihrich, Richard (25 April 2016). "Conversion Reactions of Solids: From a Surprising Three-Step Mechanism towards Directed Product Formation". Chemistry. 22 (18): 6333–6339. doi:10.1002/chem.201505209. PMID 26997587.
↑ Mamedova, N. A.; Ragimov, S. S.; Sadykhov, F. M.; Aliev, I. I. (17 February 2012). "Preparation and physicochemical study of nickel(II) thiostannate in the ${\ce {NiCl2-SnS2-H2O}}$ system". Russian Journal of Inorganic Chemistry. 57 (2): 160–162. doi:10.1134/S0036023612020179. S2CID 94801906.
↑ Popescu, M. A. (2001-11-30). Non-Crystalline Chalcogenicides. Springer Science & Business Media. p. 73. ISBN 9781402003592.
1 2 Di Salvo, F.J.; Chen, C.H.; Fleming, R.M.; Waszczak, J.V.; Dunn, R.G.; Sunshine, S.A.; Ibers, James A. (February 1986). "Physical and structural properties of the new layered compounds ${\ce {Ta2NiS5}}$ and ${\ce {Ta2NiSe5}}$ ". Journal of the Less Common Metals. 116 (1): 51–61. doi:10.1016/0022-5088(86)90216-X.
1 2 Tremel, Wolfgang (July 1991). "Isolated and Condensed Ta2Ni2 Clusters in the Layered Tellurides ${\ce {Ta2Ni2Te4}}$ and ${\ce {Ta2Ni3Te5}}$ ". Angewandte Chemie International Edition in English. 30 (7): 840–843. doi:10.1002/anie.199108401.

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[m443-1] 1 2 3 4 5 Mellor p443

[2] Ephraim, Fritz (17 September 1923). "Über Nickelsulfid". Berichte der Deutschen Chemischen Gesellschaft (A and B Series) (in German). 56 (8): 1885–1886. doi:10.1002/cber.19230560825.

[3] Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle". Zeitschrift für anorganische und allgemeine Chemie (in German). 375 (1): 1–7. doi:10.1002/zaac.19703750102.

[4] Schneider, R. (1874). "Ueber neue Schwefelsalze". Annalen der Physik und Chemie. 227 (3): 437–450. Bibcode:1874AnP...227..437S. doi:10.1002/andp.18742270306.

[banige-5] 1 2 Hlukhyy, Viktor; Trots, Dmytro; Fässler, Thomas F. (13 January 2017). "First-Order Phase Transition in BaNi2Ge2 and the Influence of the Valence Electron Count on Distortion of the ${\ce {ThCr2 Si2}}$ Structure Type". Inorganic Chemistry. 56 (3): 1173–1185. doi:10.1021/acs.inorgchem.6b02190. PMID 28085271.

[6] Neilson, James R.; McQueen, Tyrel M.; Llobet, Anna; Wen, Jiajia; Suchomel, Matthew R. (24 January 2013). "Charge density wave fluctuations, heavy electrons, and superconductivity in ${\ce {KNi2 S2}}$ ". Physical Review B. 87 (4): 045124. arXiv: 1212.4744 . Bibcode:2013PhRvB..87d5124N. doi:10.1103/PhysRevB.87.045124. S2CID 119117667.

[bronger70-7] 1 2 Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle". Zeitschrift für anorganische und allgemeine Chemie. 375 (1): 1–7. doi:10.1002/zaac.19703750102.

[brong91-8] 1 2 3 Bronger, W.; Rennau, R.; Schmitz, D. (May 1991). "Schichtstrukturen ternärer Chalkogenide ${\ce {A2M3X4}}$ (A ? K, Rb, Cs; M ? Ni, Pd, Pt; X ? S, Se)". Zeitschrift für anorganische und allgemeine Chemie. 597 (1): 27–32. doi:10.1002/zaac.19915970105.

[9] Neilson, James R.; McQueen, Tyrel M. (9 May 2012). "Bonding, Ion Mobility, and Rate-Limiting Steps in Deintercalation Reactions with ${\ce {ThCr2Si2}}$ -type ${\ce {KNi2 Se2}}$ ". Journal of the American Chemical Society. 134 (18): 7750–7757. doi:10.1021/ja212012k. PMID 22530571.

[10] Huimin Chen; Yang, Jinhu; Cao, Chao; Li, Lin; Su, Qiping; Chen, Bin; Wang, Hangdong; Mao, Qianhui; Xu, Binjie; Du, Jianhua; Minghu Fang (1 April 2016). "Superconductivity in a new layered nickel selenide ${\ce {CsNi2Se2}}$ ". Superconductor Science and Technology. 29 (4): 045008. arXiv: 1508.05167 . Bibcode:2016SuScT..29d5008C. doi:10.1088/0953-2048/29/4/045008. S2CID 119179572.

[11] Wang, Hangdong; Dong, Chiheng; Mao, Qianhui; Khan, Rajwali; Zhou, Xi; Li, Chenxia; Chen, Bin; Yang, Jinhu; Su, Qiping; Fang, Minghu (12 November 2013). "Multiband Superconductivity of Heavy Electrons in a ${\ce {TlNi2Se2}}$ Single Crystal". Physical Review Letters. 111 (20): 207001. arXiv: 1303.4658 . Bibcode:2013PhRvL.111t7001W. doi:10.1103/PhysRevLett.111.207001. PMID 24289702. S2CID 28240997.

[12] Hasegawa, Takumi; Inui, Mitsutaka; Hondou, Katsuhiro; Fujiwara, Yishihiro; Kato, Tetsuya; Iio, Katsunori (February 2004). "Raman spectroscopy on ternary transition metal chalcogenide ${\ce {Rb2Ni3S4}}$ ". Journal of Alloys and Compounds. 364 (1–2): 199–207. doi:10.1016/S0925-8388(03)00503-6.

[bronger96-13] 1 2 Bronger, Welf; Rennau, R. M.; Schmitz, D. (April 1996). "Darstellung und Kristallstruktur von ${\ce {Rb2Ni3Se4}}$ ". Zeitschrift für anorganische und allgemeine Chemie. 622 (4): 627–629. doi:10.1002/zaac.19966220409.

[14] Sun, Fan; Guo, Zhongnan; Liu, Ning; Wu, Dan; Lin, Jiawei; Cheng, Erjian; Ying, Tianping; Li, Shiyan; Yuan, Wenxia (16 March 2018). " ${\ce {Cs}}_{0.9}{\ce {Ni}}_{3.1}{\ce {Se3}}$ : A Ni-Based Quasi-One-Dimensional Conductor with Spin-Glass Behavior". Inorganic Chemistry. 57 (7): 3798–3804. doi:10.1021/acs.inorgchem.7b03143. PMID 29546755.

[m444-15] 1 2 Mellor p444

[m445-16] Mellor p445

[m446-17] 1 2 3 4 5 6 Mellor p446

[romm-18] 1 2 3 Rommel, Stefan Michael; Krach, Alexander; Peter, Philipp; Weihrich, Richard (25 April 2016). "Conversion Reactions of Solids: From a Surprising Three-Step Mechanism towards Directed Product Formation". Chemistry. 22 (18): 6333–6339. doi:10.1002/chem.201505209. PMID 26997587.

[19] Mamedova, N. A.; Ragimov, S. S.; Sadykhov, F. M.; Aliev, I. I. (17 February 2012). "Preparation and physicochemical study of nickel(II) thiostannate in the ${\ce {NiCl2-SnS2-H2O}}$ system". Russian Journal of Inorganic Chemistry. 57 (2): 160–162. doi:10.1134/S0036023612020179. S2CID 94801906.

[20] Popescu, M. A. (2001-11-30). Non-Crystalline Chalcogenicides. Springer Science & Business Media. p. 73. ISBN 9781402003592.

[disalv-21] 1 2 Di Salvo, F.J.; Chen, C.H.; Fleming, R.M.; Waszczak, J.V.; Dunn, R.G.; Sunshine, S.A.; Ibers, James A. (February 1986). "Physical and structural properties of the new layered compounds ${\ce {Ta2NiS5}}$ and ${\ce {Ta2NiSe5}}$ ". Journal of the Less Common Metals. 116 (1): 51–61. doi:10.1016/0022-5088(86)90216-X.

[tremel-22] 1 2 Tremel, Wolfgang (July 1991). "Isolated and Condensed Ta2Ni2 Clusters in the Layered Tellurides ${\ce {Ta2Ni2Te4}}$ and ${\ce {Ta2Ni3Te5}}$ ". Angewandte Chemie International Edition in English. 30 (7): 840–843. doi:10.1002/anie.199108401.