Nickel ternary chalcogenides

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The nickel ternary chalcogenides are a class of chemical compounds that contain nickel, one other metallic element, and a chalcogenide. Nickel combined with another metal and oxygen forms a series of double nickel oxides which are referred to as "nickelates" or, more precisely, "oxonickelates". This page lists the many other well-defined double compounds of nickel with sulfur, selenium and tellurium; double nickel oxides are listed elsewhere.

formulanamecolourstructureproductionreferences
NH4NiS5ammonium nickel sulphideblackNH4 polysulfide+NiSO4 [1] [2]
K2Ni3S4potassium nickel tetrasulfidebronze yellowFddd a=10.023 b=26.074 c=5.704NiSO4 K2CO3 S [1] [3] [4]
K2Ni11S10potassium nickel decasulfidedark metallic greenNiO+KCNS [1] J. Milbauer
Na2Ni3S4sodium nickel tetrasulfidedark yellowNiSO4 Na2CO3 S [1] R. Schneider
KNi2S2potassium dinickel disulfideorange yellowNi foil, S, K at 723K [5] [6]
K2Ni3Se4potassium nickel tetraselenidegoldFddd a=10.468 b=26.496 c=5.995 [7] [8]
KNi2Se2potassium dinickel diselenidepurple-redI4/mmmtetragonal a=3.909, c=13.4142Ni foil, Se shot, K at 723K [5] [9]
CsNi2Se2caesium dinickel diselenidetetragonal a=3.988, c=14.419heat elements [10]
TlNi2Se2Thallium dinickel diselenidegold metallictetragonalheat elements together in closed quartz tube [11]
Rb2Ni3S4rubidium nickel tetrasulphidemetallic greenish goldFmmm orthorhombic a=9.901 Å, b=13.606 Å and c=5.861 Z=4 layered; ferromagnetic only after water immersion [7] [12]
Rb2Ni3Se4rubidium nickel tetraselenidegolden metallicFddd orthorhombic a = 10.555 Å, b = 27.588 Å, c = 6.031 Å, Z = 8 layered; ferromagnetic only after water immersionRb2CO3 S Ni [13]
Cs2Ni3S4cesium nickel tetrasulphidegreenish goldFmmm a=10.038 b=14.552 c=5.934 [8] [13]
Cs2Ni3S4cesium nickel tetrasulphidegoldFmmm a=10.540 b=14.624 c=6.194 [8]
Cs0.9Ni3.1Se3Hexagonal P63/m a = 9.26301(4) Å and c = 4.34272(2) Åquasi-one-dimensional electric conductor [14]
BaNi4S5Barium nickel pentasulfidebronze yellowNiSO4 K2CO3 S [1] R. Schneider; I. and L. Bellucci
Pb2Ni3S2lead nickel disulfidemelt 790°PbS Ni [15] W Guertler; W Guertler H Schack
(Ni,Fe)9S8Pentlanditebronze yellow melt 870 [15] T. Scheerer
Fe2Ni2S4ferrous nickel tetrasulfidemelt 840 [16] K Bornemann
Fe2Ni2S3ferrous nickel trisulfidestable over 575°, melt 886, [17] K Bornemann
Fe3Ni4S5ferrous nickel pentasulfidebelow 575 [17] K Bornemann
Fe4Ni2S5 [17] K Bornemann
Fe2Ni3S4 [17] K Bornemann
Fe3Ni4S5 [17] K Bornemann
Fe2Ni2S3 [17] K Bornemann
FeNi2S4Violaritedark violet greymineral oxidate
Ni3Sn2S2 [18]
Ni3Bi2S2superconducting [18]
Ni3Bi2Se2superconducting [18]
NiSnS3nickel thiostannategreenish blackorthorhombic a=6.88 b=7.89 c=11.95 Z=8 V=644NiCl2 + SnS2 [19]
NiGeS33nickelselenogermanate [20]
Ta2NiS5Orthorhombic [21]
Ta2NiSe5monoclinic β=90.53 [21]
Ta2Ni2Te4 [22]
Ta2Ni3Te5 [22]

References

  1. 1 2 3 4 5 Mellor p443
  2. ↑ Ephraim, Fritz (17 September 1923). "Über Nickelsulfid". Berichte der Deutschen Chemischen Gesellschaft (A and B Series) (in German). 56 (8): 1885–1886. doi:10.1002/cber.19230560825.
  3. ↑ Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle". Zeitschrift für anorganische und allgemeine Chemie (in German). 375 (1): 1–7. doi:10.1002/zaac.19703750102.
  4. ↑ Schneider, R. (1874). "Ueber neue Schwefelsalze". Annalen der Physik und Chemie. 227 (3): 437–450. Bibcode:1874AnP...227..437S. doi:10.1002/andp.18742270306.
  5. 1 2 Hlukhyy, Viktor; Trots, Dmytro; Fässler, Thomas F. (13 January 2017). "First-Order Phase Transition in BaNi2Ge2 and the Influence of the Valence Electron Count on Distortion of the Structure Type". Inorganic Chemistry. 56 (3): 1173–1185. doi:10.1021/acs.inorgchem.6b02190. PMID   28085271.
  6. ↑ Neilson, James R.; McQueen, Tyrel M.; Llobet, Anna; Wen, Jiajia; Suchomel, Matthew R. (24 January 2013). "Charge density wave fluctuations, heavy electrons, and superconductivity in ". Physical Review B. 87 (4) 045124. arXiv: 1212.4744 . Bibcode:2013PhRvB..87d5124N. doi:10.1103/PhysRevB.87.045124. S2CID   119117667.
  7. 1 2 Bronger, W.; Eyck, J.; Rüdorff, W.; Stöussel, A. (July 1970). "Über Thio- und Selenoniccolate und -palladate der schweren Alkalimetalle". Zeitschrift für anorganische und allgemeine Chemie. 375 (1): 1–7. doi:10.1002/zaac.19703750102.
  8. 1 2 3 Bronger, W.; Rennau, R.; Schmitz, D. (May 1991). "Schichtstrukturen ternärer Chalkogenide (A ? K, Rb, Cs; M ? Ni, Pd, Pt; X ? S, Se)". Zeitschrift für anorganische und allgemeine Chemie. 597 (1): 27–32. doi:10.1002/zaac.19915970105.
  9. ↑ Neilson, James R.; McQueen, Tyrel M. (9 May 2012). "Bonding, Ion Mobility, and Rate-Limiting Steps in Deintercalation Reactions with -type ". Journal of the American Chemical Society. 134 (18): 7750–7757. doi:10.1021/ja212012k. PMID   22530571.
  10. ↑ Huimin Chen; Yang, Jinhu; Cao, Chao; Li, Lin; Su, Qiping; Chen, Bin; Wang, Hangdong; Mao, Qianhui; Xu, Binjie; Du, Jianhua; Minghu Fang (1 April 2016). "Superconductivity in a new layered nickel selenide ". Superconductor Science and Technology. 29 (4) 045008. arXiv: 1508.05167 . Bibcode:2016SuScT..29d5008C. doi:10.1088/0953-2048/29/4/045008. S2CID   119179572.
  11. ↑ Wang, Hangdong; Dong, Chiheng; Mao, Qianhui; Khan, Rajwali; Zhou, Xi; Li, Chenxia; Chen, Bin; Yang, Jinhu; Su, Qiping; Fang, Minghu (12 November 2013). "Multiband Superconductivity of Heavy Electrons in a Single Crystal". Physical Review Letters. 111 (20) 207001. arXiv: 1303.4658 . Bibcode:2013PhRvL.111t7001W. doi:10.1103/PhysRevLett.111.207001. PMID   24289702. S2CID   28240997.
  12. ↑ Hasegawa, Takumi; Inui, Mitsutaka; Hondou, Katsuhiro; Fujiwara, Yishihiro; Kato, Tetsuya; Iio, Katsunori (February 2004). "Raman spectroscopy on ternary transition metal chalcogenide ". Journal of Alloys and Compounds. 364 (1–2): 199–207. doi:10.1016/S0925-8388(03)00503-6.
  13. 1 2 Bronger, Welf; Rennau, R. M.; Schmitz, D. (April 1996). "Darstellung und Kristallstruktur von ". Zeitschrift für anorganische und allgemeine Chemie. 622 (4): 627–629. doi:10.1002/zaac.19966220409.
  14. ↑ Sun, Fan; Guo, Zhongnan; Liu, Ning; Wu, Dan; Lin, Jiawei; Cheng, Erjian; Ying, Tianping; Li, Shiyan; Yuan, Wenxia (16 March 2018). ": A Ni-Based Quasi-One-Dimensional Conductor with Spin-Glass Behavior". Inorganic Chemistry. 57 (7): 3798–3804. doi:10.1021/acs.inorgchem.7b03143. PMID   29546755.
  15. 1 2 Mellor p444
  16. ↑ Mellor p445
  17. 1 2 3 4 5 6 Mellor p446
  18. 1 2 3 Rommel, Stefan Michael; Krach, Alexander; Peter, Philipp; Weihrich, Richard (25 April 2016). "Conversion Reactions of Solids: From a Surprising Three-Step Mechanism towards Directed Product Formation". Chemistry. 22 (18): 6333–6339. doi:10.1002/chem.201505209. PMID   26997587.
  19. ↑ Mamedova, N. A.; Ragimov, S. S.; Sadykhov, F. M.; Aliev, I. I. (17 February 2012). "Preparation and physicochemical study of nickel(II) thiostannate in the system". Russian Journal of Inorganic Chemistry. 57 (2): 160–162. doi:10.1134/S0036023612020179. S2CID   94801906.
  20. ↑ Popescu, M. A. (2001-11-30). Non-Crystalline Chalcogenicides. Springer Science & Business Media. p. 73. ISBN   978-1-4020-0359-2.
  21. 1 2 Di Salvo, F.J.; Chen, C.H.; Fleming, R.M.; Waszczak, J.V.; Dunn, R.G.; Sunshine, S.A.; Ibers, James A. (February 1986). "Physical and structural properties of the new layered compounds and ". Journal of the Less Common Metals. 116 (1): 51–61. doi:10.1016/0022-5088(86)90216-X.
  22. 1 2 Tremel, Wolfgang (July 1991). "Isolated and Condensed Ta2Ni2 Clusters in the Layered Tellurides and ". Angewandte Chemie International Edition in English. 30 (7): 840–843. doi:10.1002/anie.199108401.
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