In chemistry and physics, metastability is an intermediate energetic state within a dynamical system other than the system's state of least energy. A ball resting in a hollow on a slope is a simple example of metastability. If the ball is only slightly pushed, it will settle back into its hollow, but a stronger push may start the ball rolling down the slope. Bowling pins show similar metastability by either merely wobbling for a moment or tipping over completely. A common example of metastability in science is isomerisation. Higher energy isomers are long lived because they are prevented from rearranging to their preferred ground state by barriers in the potential energy.
In physics, a state of matter is one of the distinct forms in which matter can exist. Four states of matter are observable in everyday life: solid, liquid, gas, and plasma. Many intermediate states are known to exist, such as liquid crystal, and some states only exist under extreme conditions, such as Bose–Einstein condensates and Fermionic condensates, neutron-degenerate matter, and quark–gluon plasma. For a list of exotic states of matter, see the article List of states of matter.
Prussian blue is a dark blue pigment produced by oxidation of ferrous ferrocyanide salts. It has the chemical formula FeIII
4[FeII
(CN)
6]
3. Turnbull's blue is chemically identical, but is made from different reagents, and its slightly different color stems from different impurities and particle sizes.
Photochemistry is the branch of chemistry concerned with the chemical effects of light. Generally, this term is used to describe a chemical reaction caused by absorption of ultraviolet, visible (400–750 nm), or infrared radiation (750–2500 nm).
A plastic magnet is a non-metallic magnet made from an organic polymer.
In chemistry, photoisomerization is a form of isomerization induced by photoexcitation. Both reversible and irreversible photoisomerizations are known for photoswitchable compounds. The term "photoisomerization" usually, however, refers to a reversible process.
In chemistry, a nitride is a chemical compound of nitrogen. Nitrides can be inorganic or organic, ionic or covalent. The nitride anion, N3- ion, is very elusive but compounds of nitride are numerous, although rarely naturally occurring. Some nitrides have a found applications, such as wear-resistant coatings (e.g., titanium nitride, TiN), hard ceramic materials (e.g., silicon nitride, Si3N4), and semiconductors (e.g., gallium nitride, GaN). The development of GaN-based light emitting diodes was recognized by the 2014 Nobel Prize in Physics. Metal nitrido complexes are also common.
Magnetic semiconductors are semiconductor materials that exhibit both ferromagnetism and useful semiconductor properties. If implemented in devices, these materials could provide a new type of control of conduction. Whereas traditional electronics are based on control of charge carriers, practical magnetic semiconductors would also allow control of quantum spin state. This would theoretically provide near-total spin polarization, which is an important property for spintronics applications, e.g. spin transistors.
Photochromism is the reversible change of color upon exposure to light. It is a transformation of a chemical species (photoswitch) between two forms by the absorption of electromagnetic radiation (photoisomerization), where the two forms have different absorption spectra.
Solid oxygen forms at normal atmospheric pressure at a temperature below 54.36 K (−218.79 °C, −361.82 °F). Solid oxygen O2, like liquid oxygen, is a clear substance with a light sky-blue color caused by absorption in the red part of the visible light spectrum.
Tris(bipyridine)ruthenium(II) chloride is the chloride salt coordination complex with the formula [Ru(bpy)3]Cl2. This polypyridine complex is a red crystalline salt obtained as the hexahydrate, although all of the properties of interest are in the cation [Ru(bpy)3]2+, which has received much attention because of its distinctive optical properties. The chlorides can be replaced with other anions, such as PF6−.
Molecule-based magnets (MBMs) or molecular magnets are a class of materials capable of displaying ferromagnetism and other more complex magnetic phenomena. This class expands the materials properties typically associated with magnets to include low density, transparency, electrical insulation, and low-temperature fabrication, as well as combine magnetic ordering with other properties such as photoresponsiveness. Essentially all of the common magnetic phenomena associated with conventional transition-metal magnets and rare-earth magnets can be found in molecule-based magnets. Prior to 2011, MBMs were seen to exhibit "magnetic ordering with Curie temperature (Tc) exceeding room temperature".
Discovered only as recently as 2006 by C.D. Stanciu and F. Hansteen and published in Physical Review Letters, this effect is generally called all-optical magnetization reversal. This magnetization reversal technique refers to a method of reversing magnetization in a magnet simply by circularly polarized light and where the magnetization direction is controlled by the light helicity. In particular, the direction of the angular momentum of the photons would set the magnetization direction without the need of an external magnetic field. In fact, this process could be seen as similar to magnetization reversal by spin injection. The only difference is that now, the angular momentum is supplied by the circularly polarized photons instead of the polarized electrons.
Forced Rayleigh scattering (FRS) is an experimental method in physics and chemistry based on light scattering and is usually used to measure diffusion on length scales of roughly 10 μm. Many FRS experiments have been carried out on thermal and mass diffusion in liquids, and thermophoresis (Soret effect) has been measured in polymer solutions.
A hidden state of matter is a state of matter which cannot be reached under ergodic conditions, and is therefore distinct from known thermodynamic phases of the material. Examples exist in condensed matter systems, and are typically reached by the non-ergodic conditions created through laser photo excitation. Short-lived hidden states of matter have also been reported in crystals using lasers. Recently a persistent hidden state was discovered in a crystal of Tantalum(IV) sulfide (TaS2), where the state is stable at low temperatures. A hidden state of matter is not to be confused with hidden order, which exists in equilibrium, but is not immediately apparent or easily observed.
In chemistry, aluminium(I) refers to monovalent aluminium (+1 oxidation state) in both ionic and covalent bonds. Along with aluminium(II), it is an extremely unstable form of aluminium.
Friedrich E. Wagner is a German physicist and emeritus professor who specializes in plasma physics. He was known to have discovered the high-confinement mode of magnetic confinement in fusion plasmas while working at the ASDEX tokamak in 1982. For this discovery and his subsequent contributions to fusion research, was awarded the John Dawson Award in 1987, the Hannes Alfvén Prize in 2007 and the Stern–Gerlach Medal in 2009.
Mixed valence complexes contain an element which is present in more than one oxidation state. Well-known mixed valence compounds include the Creutz–Taube complex, Prussian blue, and molybdenum blue. Many solids are mixed-valency including indium chalcogenides.
Fractional Chern insulators (FCIs) are lattice generalizations of the fractional quantum Hall effect that have been studied theoretically since early 2010. They were first predicted to exist in topological flat bands carrying Chern numbers. They can appear in topologically non-trivial band structures even in the absence of the large magnetic fields needed for the fractional quantum Hall effect. They promise physical realizations at lower magnetic fields, higher temperatures, and with shorter characteristic length scales compared to their continuum counterparts. FCIs were initially studied by adding electron-electron interactions to a fractionally filled Chern insulator, in one-body models where the Chern band is quasi-flat, at zero magnetic field. The FCIs exhibit a fractional quantized Hall conductance.
Corine Mathonière is a French chemist and Professor at the University of Bordeaux. She is part of the Molecular Materials and Magnetism team, who look to use modular molecular materials to assemble into various architectures. She was appointed to the Ordre des Palmes académiques in 2010.
