Stainless steel, also known as inox, corrosion-resistant steel (CRES) and rustless steel, is an alloy of iron that is resistant to rusting and corrosion. It contains iron with chromium and other elements such as molybdenum, carbon, nickel and nitrogen depending on its specific use and cost. Stainless steel's resistance to corrosion results from the 10.5%, or more, chromium content which forms a passive film that can protect the material and self-heal in the presence of oxygen.
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.
Monel is a group of alloys of nickel and copper, with small amounts of iron, manganese, carbon, and silicon. Monel is not a cupronickel alloy because it has less than 60% copper.
Pitting corrosion, or pitting, is a form of extremely localized corrosion that leads to the random creation of small holes in metal. The driving power for pitting corrosion is the depassivation of a small area, which becomes anodic while an unknown but potentially vast area becomes cathodic, leading to very localized galvanic corrosion. The corrosion penetrates the mass of the metal, with a limited diffusion of ions.
Alloy 20 is an austenitic stainless steel containing less than 50% iron developed for applications involving sulfuric acid. Its corrosion resistance also finds other uses in the chemical, petrochemical, power generation, and plastics industries. Alloy 20 resists pitting and chloride ion corrosion, better than 304 stainless steel and on par with 316L stainless steel. Its copper content protects it from sulfuric acid. Alloy 20 is often chosen to solve stress corrosion cracking problems, which may occur with 316L stainless. Alloy of the same name with the designation "Cb-3" indicates niobium stabilized.
Marine grade stainless alloys typically contain molybdenum to resist the corrosive effects of NaCl or salt in seawater. Concentrations of salt in seawater can vary, and splash zones can cause concentrations to increase dramatically from the spray and evaporation.
Stress corrosion cracking (SCC) is the growth of crack formation in a corrosive environment. It can lead to unexpected and sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. SCC is highly chemically specific in that certain alloys are likely to undergo SCC only when exposed to a small number of chemical environments. The chemical environment that causes SCC for a given alloy is often one which is only mildly corrosive to the metal. Hence, metal parts with severe SCC can appear bright and shiny, while being filled with microscopic cracks. This factor makes it common for SCC to go undetected prior to failure. SCC often progresses rapidly, and is more common among alloys than pure metals. The specific environment is of crucial importance, and only very small concentrations of certain highly active chemicals are needed to produce catastrophic cracking, often leading to devastating and unexpected failure.
The SAE steel grades system is a standard alloy numbering system for steel grades maintained by SAE International.
The salt spray test is a standardized and popular corrosion test method, used to check corrosion resistance of materials and surface coatings. Usually, the materials to be tested are metallic and finished with a surface coating which is intended to provide a degree of corrosion protection to the underlying metal.
Michael A. Streicher was an American metallurgist and engineer who became internationally recognized for his work on the testing and development of corrosion-resistant stainless steel alloys. He published widely in technical journals and textbooks and received numerous patents for his inventions.
Crevice corrosion refers to corrosion occurring in occluded spaces such as interstices in which a stagnant solution is trapped and not renewed. These spaces are generally called crevices. Examples of crevices are gaps and contact areas between parts, under gaskets or seals, inside cracks and seams, spaces filled with deposits and under sludge piles.
Zeron 100 is a super duplex stainless steel developed by Rolled Alloys. The alloy has excellent corrosion resistance combined with high strength. It typically contains 25% chromium and 7% nickel and 3.6% molybdenum along with copper and tungsten additions. Zeron 100 has a 50–50 austenitic–ferritic structure. It also has greater resistance to chloride pitting, crevice corrosion and stress corrosion cracking than exhibited by the standard 300 series stainless steels.
SAF 2205, is a Alleima-owned trademark for a 22Cr duplex (ferritic-austenitic) stainless steel. SAF derives from Sandvik Austenite Ferrite. The nominal chemical composition of SAF 2205 is 22% chromium, 5% nickel, 3.2% molybdenum and other alloying elements such as nitrogen and manganese. The UNS designation for SAF 2205 is S31803/S32205 and the EN steel no. is 1.4462. SAF 2205 or Duplex 2205 is often used as an alternative to expensive 904L stainless steel owing to similar properties but cheaper ingredients. Duplex stainless steel is available in multiple forms like bars, billets, pipes, tubes, sheets, plates and even processed to fittings and flanges.
Duplex stainless steels are a family of stainless steels. These are called duplex grades because their metallurgical structure consists of two phases, austenite and ferrite in roughly equal proportions. They are designed to provide better corrosion resistance, particularly chloride stress corrosion and chloride pitting corrosion, and higher strength than standard austenitic stainless steels such as type A2/304 or A4/316. The main differences in composition, when compared with an austenitic stainless steel is that the duplex steels have a higher chromium content, 20–28%; higher molybdenum, up to 5%; lower nickel, up to 9% and 0.05–0.50% nitrogen. Both the low nickel content and the high strength give significant cost benefits. They are therefore used extensively in the offshore oil and gas industry for pipework systems, manifolds, risers, etc. and in the petrochemical industry in the form of pipelines and pressure vessels. In addition to the improved corrosion resistance compared with the 300 series duplex stainless steels also have higher strength. For example, a Type 304 stainless steel has a 0.2% proof strength in the region of 280 MPa (41 ksi), a 22%Cr duplex stainless steel a minimum 0.2% proof strength of some 450 MPa (65 ksi) and a superduplex grade a minimum of 550 MPa (80 ksi).
SAE 304 stainless steel is the most common stainless steel. It is an alloy of iron, carbon, chromium and nickel. It is an austenitic stainless steel, and is therefore not magnetic. It is less electrically and thermally conductive than carbon steel. It has a higher corrosion resistance than regular steel and is widely used because of the ease in which it is formed into various shapes.
Inconel Alloy 625 is a nickel-based superalloy that possesses high strength properties and resistance to elevated temperatures. It also demonstrates remarkable protection against corrosion and oxidation. Its ability to withstand high stress and a wide range of temperatures, both in and out of water, as well as being able to resist corrosion while being exposed to highly acidic environments makes it a fitting choice for nuclear and marine applications.
904L is an austenitic stainless steel. It is softer than 316L, but its molybdenum addition gives it superior resistance to localized attack by chlorides and greater resistance reducing acids; in particular, its copper addition gives it useful corrosion resistance to all concentrations of sulfuric acid. Its high alloying content also gives it greater resistance to chloride stress corrosion cracking, but it is still susceptible. Its low carbon content makes it resistant to sensitization by welding and which prevents intergranular corrosion.
Havar, or UNS R30004, is an alloy of cobalt, possessing a very high mechanical strength. It can be heat-treated. It is highly resistant to corrosion and is non-magnetic. It is biocompatible. It has high fatigue resistance. It is a precipitation hardening superalloy.
Ferritic stainless steel forms one of the five stainless steel families, the other four being austenitic, martensitic, duplex stainless steels, and precipitation hardened. For example, many of AISI 400-series of stainless steels are ferritic steels. By comparison with austenitic types, these are less hardenable by cold working, less weldable, and should not be used at cryogenic temperatures. Some types, like the 430, have excellent corrosion resistance and are very heat tolerant.
