Renewable polyethylene

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Biopolyethylene (also known as renewable polyethylene) is polyethylene made out of ethanol, which becomes ethylene after a dehydration process. It can be made from various feedstocks including sugar cane, sugar beet, and wheat grain. [1]

Contents

The final product is indistinguishable from conventional polyethylene (except that it is radioactive due to the presence of carbon 14), and thus is recyclable in the same chain established for conventional PE.

The first plant

In 2007 an ethanol-based manufacturing plant, totally integrated from sugarcane to polyethylene, was announced by the Dow Chemical Company, in conjunction with Crystalsev, a large sugar and ethanol producer in Brazil. [2] The plant was projected to produce 350 000 metric tonnes per year of renewable LLDPE (linear low-density polyethylene), would begin construction in 2008, and was slated to start production in 2011.

Benefits

One of the main environmental benefits of Green PE is the sequestration of roughly 2.15 tonnes of CO2 per tonne of Green Polyethylene produced, which comes from the CO2 absorbed by the sugar cane while growing, minus the CO2 emitted through the production process. Renewable polyethylene is non-biodegradable and can be recycled in the same waste streams as traditional polyethylenes (HDPE, LDPE, LLDPE) as it is chemically identical. [3]

Disadvantages

Producing feedstock for biobased plastics relies upon intensive agriculture, potentially contributing to deforestation in order to clear land for agricultural use. Large-scale production of feedstock also requires inputs such as fossil fuels, fertilizers, and pesticides.

Production

Braskem is the world leader in the production of biopolymer, with the Green Polyethylene "I'm green™", a thermoplastic resin produced from ethylene made from sugarcane ethanol, a 100% renewable raw material which helps reduce greenhouse gas emissions. The production started in 2010 and is located in Triunfo, South of Brazil.

Today the Braskem industrial unit has an annual production capacity of 200 000 tonne of Green Polyethylene. Green PE has the same properties, performance, and application versatility as fossil-based polyethylene, which makes it a drop-in replacement in the plastic production chain. For these same reasons, it is also recyclable in the same recycling chain used by traditional polyethylene. Because it is part of the portfolio of high-density polyethylene (HDPE) and linear low-density polyethylene (LLDPE) products, Green PE rapidly became an option for applications in rigid and flexible packaging, closures, bags, and other products. In January 2014, the family of low-density polyethylene (LDPE) was added to the product portfolio, effectively covering additional applications in packaging and films. [4] [5]

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<span class="mw-page-title-main">Ethylene</span> Hydrocarbon compound (H₂C=CH₂)

Ethylene is a hydrocarbon which has the formula C2H4 or H2C=CH2. It is a colourless, flammable gas with a faint "sweet and musky" odour when pure. It is the simplest alkene.

<span class="mw-page-title-main">Petrochemical</span> Chemical product derived from petroleum

Petrochemicals are the chemical products obtained from petroleum by refining. Some chemical compounds made from petroleum are also obtained from other fossil fuels, such as coal or natural gas, or renewable sources such as maize, palm fruit or sugar cane.

<span class="mw-page-title-main">Polyethylene</span> Most common thermoplastic polymer

Polyethylene or polythene (abbreviated PE; IUPAC name polyethene or poly(methylene)) is the most commonly produced plastic. It is a polymer, primarily used for packaging (plastic bags, plastic films, geomembranes and containers including bottles, etc.). As of 2017, over 100 million tonnes of polyethylene resins are being produced annually, accounting for 34% of the total plastics market.

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<span class="mw-page-title-main">Bagasse</span> Residue of sugar cane after juice extraction

Bagasse is the dry pulpy fibrous material that remains after crushing sugarcane or sorghum stalks to extract their juice. It is used as a biofuel for the production of heat, energy, and electricity, and in the manufacture of pulp and building materials. Agave bagasse is similar, but is the material remnants after extracting blue agave sap.

<span class="mw-page-title-main">Ethanol fermentation</span> Biological process that produces ethanol and carbon dioxide as by-products

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<span class="mw-page-title-main">Methanol economy</span>

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Low-density polyethylene (LDPE) is a thermoplastic made from the monomer ethylene. It was the first grade of polyethylene, produced in 1933 by Dr John C. Swallow and M.W Perrin who were working for Imperial Chemical Industries (ICI) using a high pressure process via free radical polymerization. Its manufacture employs the same method today. The EPA estimates 5.7% of LDPE is recycled in the United States. Despite competition from more modern polymers, LDPE continues to be an important plastic grade. In 2013 the worldwide LDPE market reached a volume of about US$33 billion.

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A polyolefin is a type of polymer with the general formula (CH2CHR)n where R is an alkyl group. They are usually derived from a small set of simple olefins (alkenes). Dominant in a commercial sense are polyethylene and polypropylene. More specialized polyolefins include polyisobutylene and polymethylpentene. They are all colorless or white oils or solids. Many copolymers are known, such as polybutene, which derives from a mixture of different butene isomers. The name of each polyolefin indicates the olefin from which it is prepared; for example, polyethylene is derived from ethylene, and polymethylpentene is derived from 4-methyl-1-pentene. Polyolefins are not olefins themselves because the double bond of each olefin monomer is opened in order to form the polymer. Monomers having more than one double bond such as butadiene and isoprene yield polymers that contain double bonds (polybutadiene and polyisoprene) and are usually not considered polyolefins. Polyolefins are the foundations of many chemical industries.

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References

  1. Life Cycle Assessment Workbooks for a Selection of Major Renewable Chemicals
  2. "Dow and Crystalsev Announce Plans to Make Polyethylene from Sugar Cane in Brazil". Dow Chemical Company. 2007.
  3. "I'm green". Braskem.
  4. "Braskem & Toyota Tsusho start joint marketing activities for green polyethylene from sugar cane". bioplastics24.com.
  5. "Braskem Profile and history". Braskem.