| Senegalite | |
|---|---|
 | |
| General | |
| Category | Mineral |
| Formula (repeating unit) | Al2(PO4)(OH)3⋅3H2 [1] |
| IMA symbol | Sng [2] |
| Identification | |
| Color | Colorless, Light yellow [3] |
Senegalite is a rare aluminum phosphate. It is a hydrated hydroxy phosphate of aluminum. It is named after Senegal, the country in which it was first found to occur. [4] [5]
The molecular structure of the phosphate mineral senegalite is Al
2(PO
4)(OH)
3⋅3H
2O. [6] [5]
In chemistry, a phosphate is an anion, salt, functional group or ester derived from a phosphoric acid. It most commonly means orthophosphate, a derivative of orthophosphoric acid, a.k.a. phosphoric acid H3PO4.
Chrysocolla ( KRIS-ə-KOL-ə) is a hydrous copper phyllosilicate mineral and mineraloid with the formula Cu
2 – xAl
x(H
2Si
2O
5)(OH)
4⋅nH
2O (x < 1) or (Cu, Al)
2H
2Si
2O
5(OH)
4⋅nH
2O).
Brazilianite, whose name derives from its country of origin, Brazil, is a typically yellow-green phosphate mineral, most commonly found in phosphate-rich pegmatites.
Cerite is a complex silicate mineral group containing cerium, formula (Ce,La,Ca)
9(Mg,Fe3+
)(SiO
4)
6(SiO
3OH)(OH)
3. The cerium and lanthanum content varies with the Ce rich species and the La rich species. Analysis of a sample from the Mountain Pass carbonatite gave 35.05% Ce
2O
3 and 30.04% La
2O
3.
Childrenite is a rare hydrated phosphate mineral with elements iron, manganese, aluminium, phosphorus, oxygen and hydrogen. Its chemical formula is (Fe2+
,Mn)2+
AlPO
4(OH)
2•H
2O and it has a molecular weight of 229.83 g/mol. Its specific gravity is 3.2 and it has a Mohs hardness of 4.5 to 5. It is usually translucent and non-fluorescent, with imperfect cleavage. It has a vitreous lustre with a white streak, and is brown or yellow in color. It has a conchoidal, uneven fracture, and an orthorhombic crystal system.
Pumpellyite is a group of closely related sorosilicate minerals:
Phosphophyllite (from Ancient Greek phyllon 'leaf', and phosphate) is a rare mineral with the chemical formula Zn2Fe(PO4)2·4H2O, composed of hydrated zinc phosphate. It is highly prized by collectors for its rarity and for its delicate bluish green colour. Phosphophyllite is rarely cut because it is fragile and brittle, and large crystals are too valuable to be broken up.
Ferrihydrite (Fh) is a widespread hydrous ferric oxyhydroxide mineral at the Earth's surface, and a likely constituent in extraterrestrial materials. It forms in several types of environments, from freshwater to marine systems, aquifers to hydrothermal hot springs and scales, soils, and areas affected by mining. It can be precipitated directly from oxygenated iron-rich aqueous solutions, or by bacteria either as a result of a metabolic activity or passive sorption of dissolved iron followed by nucleation reactions. Ferrihydrite also occurs in the core of the ferritin protein from many living organisms, for the purpose of intra-cellular iron storage.
Chalcophyllite is a rare secondary copper arsenate mineral occurring in the oxidized zones of some arsenic-bearing copper deposits. It was first described from material collected in Germany. At one time chalcophyllite from Wheal Tamar in Cornwall, England, was called tamarite, but this name is now discredited. At Wheal Gorland a specimen exhibiting partial replacement of liriconite, Cu
2Al(AsO
4)(OH)
4·(4H
2O), by chalcophyllite has been found. The mineral is named from the Greek, chalco "copper" and fyllon, "leaf", in allusion to its composition and platy structure. It is a classic Cornish mineral that can be confused with tabular spangolite.
Cyrilovite (NaFe33+(PO4)2(OH)4·2(H2O)) is a hydrous sodium iron phosphate mineral. It is isomorphous and isostructural with wardite, the sodium aluminium counterpart.
Penikisite was discovered by Alan Kulan and Gunar Penikis near Rapid Creek, Yukon Territory. The mineral is a member of the bjarebyite group along with kulanite, ideally BaFe2+2Al2(PO4)3(OH)3, and bjarebyite, ideally BaMn2+2Al2(PO4)3(OH)3. It is among several new minerals that have been discovered in the Rapid Creek and Big Fish areas of Yukon Territory. Kulanite is similar in many ways to penikisite in appearance and properties. The chemical formula for penikisite is Ba(Mg,Fe,Ca)Al2(PO4)2(OH)3. It has a hardness of about 4 and a density of 3.79 g/cm3. Penikisite is unique among the bjarebyite group in being monoclinic and has a biaxial optical class. It comes in shades of blue and green and, when rubbed on a streak plate, is pale green to white in color. Although penikisite and kulanite both range from blue to green, penikisite zones are easily distinguishable from kulanite zones in kulanite-penikisite crystals because they are lighter than the darker kulanite in color. Penikisite is a phosphate and is different from kulanite in that it is a magnesium-rich phosphate whereas kulanite is an iron-rich phosphate.
Mundite is a uranium phosphate mineral with chemical formula: Al(UO2)3(PO4)2(OH)3·5(H2O). It contains aluminium and has a yellow tinge to it. It usually appears on sandstones or limestones.
Collinsite is a mineral with chemical formula Ca
2(Mg,Fe2+
)(PO
4)
2•2H
2O. It was discovered in British Columbia, Canada, and formally described in 1927. It was named in honor of William Henry Collins (1878–1937), director of the Geological Survey of Canada. There are three varieties of the mineral: magnesian collinsite, zincian collinsite, and strontian collinsite. The crystal structure consists of polyhedral chains linked by weak hydrogen bonds.
Sinkankasite, mineral formula: H
2MnAl(PO
4)
2(OH)·6H
2O, was named after John Sinkankas (1915–2002), noted author and mineral collector, Scripps Institute of Oceanography. It is triclinic; as colorless, bladed to prismatic crystals up to 4 mm in length, often as divergent, radial aggregates and as pseudomorphs after triphlyte crystals; occurs in the Barker pegmatite, east of Keystone, South Dakota, and in the Palermo pegmatite, North Groton, New Hampshire.
Greifensteinite is beryllium phosphate mineral with formula: Ca2Fe2+5Be4(PO4)6(OH)4·6H2O. It is the Fe2+ dominant member of the roscherite group. It crystallizes in the monoclinic crystal system and typically forms prismatic dark olive green crystals.
Chanabayaite is the first recognized triazolate mineral, having the formula Cu
2(N
3C
2H
2Cl
4.
Metavivianite is a hydrated iron phosphate mineral found in a number of geological environments. As a secondary mineral it is typically formed from oxidizing vivianite. Metavivianite is typically found as dark blue or dark green prismatic to flattened crystals.
Crandallite is a calcium aluminium basic phosphate mineral. It has ideal formula CaAl
3(PO
4)
2(OH)
5·H
2O. Crandallite was named after Milan L. Crandall, Jr, who worked for Knight Syndicate. This mineral is found in laterite and in alteration products of phosphate rich pegmatites.
The oxalate phosphates are chemical compounds containing oxalate and phosphate anions. They are also called oxalatophosphates or phosphate oxalates. Some oxalate-phosphate minerals found in bat guano deposits are known. Oxalate phosphates can form metal organic framework compounds.
The phosphate sulfates are mixed anion compounds containing both phosphate and sulfate ions. Related compounds include the arsenate sulfates, phosphate selenates, and arsenate selenates.
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