Stain repellent

Last updated


A stain repellent is a product added to fabric in order to prevent stains. [1]

Contents

Stains

Stains on fabrics are classified into three types: water-based stains and oil-based stains or a mix of both. [2]

Stain repellant fabrics

Fabrics are finished with certain finishes that do not allow unwanted stains or that will wash out in simple laundry.

Chemicals

Mostly larger PFCAs such as perfluorooctanoic acid (PFOA) are used in stain repellancy. It is also known colloquially as C8. PFOA is a product of health concern and subject to regulatory action and voluntary industrial phase-outs. [3]

Alternative chemistry

There are chemicals which are based on C8 free chemistry that may be used as an alternative to PFOA, but those are less durable. [4]

See also

Notes

  1. "Stain Resistance". Textile Information Knowledge Platform. Textile Centre of Excellence. 2020. Retrieved June 19, 2021.
  2. Jackman, Dianne Rose; Dixon, Mary Katherine (1983). water+based+and+oil+based+stains. The Guide to Textiles for Interior Designers. Peguis Publishers Limited. p. 143. ISBN   978-0-919566-95-8.
  3. "Perfluorooctanoic Acid (PFOA), Teflon, and Related Chemicals". www.cancer.org. Retrieved 2021-06-20.
  4. "Huntsman Drives Sustainable Growth in Vietnam's Textile Industry". Huntsman Corporation. Retrieved 2021-06-20.

Related Research Articles

Polytetrafluoroethylene Synthetic polymer

Polytetrafluoroethylene (PTFE) is a synthetic fluoropolymer of tetrafluoroethylene that has numerous applications. The commonly known brand name of PTFE-based compositions is Teflon by Chemours, a spin-off from DuPont, which originally discovered the compound in 1938.

Perfluorooctanoic acid Perfluorinated carboxylic acid

Perfluorooctanoic acid (PFOA) — also known colloquially as C8 — is a perfluorinated carboxylic acid produced and used worldwide as an industrial surfactant in chemical processes and as a material feedstock. PFOA is considered a surfactant, or fluorosurfactant, due to its chemical structure, which consists of a perfluorinated, n-octyl “tail group” and a carboxylate “head group”. The head group can be described as hydrophilic while the fluorocarbon tail is both hydrophobic and lipophobic. The tail group is inert and does not interact strongly with polar or non-polar chemical moieties; the head group is reactive and interacts strongly with polar groups, specifically water. The “tail” is hydrophobic due to being non-polar and lipophobic because fluorocarbons are less susceptible to the London dispersion force than hydrocarbons.

Perfluorooctanesulfonic acid Fluorosurfactant and persistent organic pollutant

Perfluorooctanesulfonic acid (PFOS) is an anthropogenic (human-made) fluorosurfactant, now regarded as a global pollutant. PFOS was the key ingredient in Scotchgard, a fabric protector made by 3M, and numerous stain repellents. It was added to Annex B of the Stockholm Convention on Persistent Organic Pollutants in May 2009. PFOS can be synthesized in industrial production or result from the degradation of precursors. PFOS levels that have been detected in wildlife are considered high enough to affect health parameters, and recently higher serum levels of PFOS were found to be associated with increased risk of chronic kidney disease in the general US population. "This association was independent of confounders such as age, sex, race/ethnicity, body mass index, diabetes, hypertension, and serum cholesterol level."

Huntsman Corporation is an American multinational manufacturer and marketer of chemical products for consumers and industrial customers. Huntsman manufactures assorted polyurethanes, performance products, and adhesives for customers like BMW, GE, Chevron, Procter & Gamble, Unilever and Walkaroo.With global headquarters in The Woodlands, Texas, they operate more than 70 manufacturing, R&D and operations facilities in over 30 countries and employ approximately 9,000 associates across four business divisions. Huntsman Corporation had 2020 revenues of approximately $6 billion.

Durable water repellent A functional finish to make fabrics water-resistant (hydrophobic).

Durable water repellent, or DWR, is a coating added to fabrics at the factory to make them water-resistant (hydrophobic). Most factory-applied treatments are fluoropolymer based; these applications are quite thin and not always effective. Durable water repellents are commonly used in conjunction with waterproof breathable fabrics such as Gore-Tex to prevent the outer layer of fabric from becoming saturated with water. This saturation, called 'wetting out,' can reduce the garment's breathability and let water through. As the DWR wears off over time, re-treatment is recommended when necessary. Many spray-on and wash-in products for treatment of non-waterproof garments and re-treatment of proofed garments losing their water-repellency are available.

Microwave popcorn

Microwave popcorn is a convenience food consisting of unpopped popcorn in an enhanced, sealed paper bag intended to be heated in a microwave oven. In addition to the dried corn, the bags typically contain cooking oil with sufficient saturated fat to solidify at room temperature, one or more seasonings, and natural or artificial flavorings or both. With the many different flavors, there are many different providers.

Scotchgard is a 3M brand of products, a stain and durable water repellent applied to fabric, furniture, and carpets to protect them from stains. Scotchgard products typically rely on organofluorine chemicals as the main active ingredient along with petroleum distillate solvents.

Non-stick surface

A non-stick surface is a surface engineered to reduce the ability of other materials to stick to it. Non-stick cookware is a common application, where the non-stick coating allows food to brown without sticking to the pan. Non-stick is often used to refer to surfaces coated with polytetrafluoroethylene (PTFE), a well-known brand of which is Teflon. In the twenty-first century, other coatings have been marketed as non-stick, such as anodized aluminium, silica, enameled cast iron, and seasoned cookware.

Stain removal is the process of removing a mark or spot left by one substance on a specific surface like a fabric. A solvent or detergent is generally used to conduct stain removal and many of these are available over the counter.

Finishing (textiles) Any process performed after dyeing the yarn or fabric to improve the look, performance, or "hand" (feel) of the finished textile or clothing

In textile manufacturing, finishing refers to the processes that convert the woven or knitted cloth into a usable material and more specifically to any process performed after dyeing the yarn or fabric to improve the look, performance, or "hand" (feel) of the finish textile or clothing. The precise meaning depends on context.

Perfluorononanoic acid, or PFNA, is a synthetic perfluorinated carboxylic acid and fluorosurfactant that is also an environmental contaminant found in people and wildlife along with PFOS and PFOA.

Per- and polyfluoroalkyl substances Class of perfluorinated chemical compounds

Per- and polyfluoroalkyl substances (PFASs) are synthetic organofluorine chemical compounds that have multiple fluorine atoms attached to an alkyl chain. As such, they contain at least one perfluoroalkyl moiety, –CnF2n–. According to the Organisation for Economic Co-operation and Development (OECD):

PFASs are defined as fluorinated substances that contain at least one fully fluorinated methyl or methylene carbon atom (without any H/Cl/Br/I atom attached to it), i.e. with a few noted exceptions, any chemical with at least a perfluorinated methyl group (–CF3) or a perfluorinated methylene group (–CF2–) is a PFAS.

Fluorotelomers are fluorocarbon-based oligomers, or telomers, synthesized by telomerization. Some fluorotelomers and fluorotelomer-based compounds are a source of environmentally persistent perfluorinated carboxylic acids such as PFOA and PFNA, while others are under extended investigation.

Perfluorinated compound

A perfluorinated compound (PFC) is an organofluorine compound containing only carbon-fluorines and C-C bonds but also other heteroatoms. PFCs have properties that result from the presence of fluorocarbons (containing only C–F and C–C bonds) and the functional group. Common functional groups in PFCs are OH, CO2H, chlorine, O, and SO3H.

<i>The Devil We Know</i> 2018 documentary by Stephanie Soechtig

The Devil We Know is a 2018 investigative documentary film by director Stephanie Soechtig regarding allegations of health hazards from perfluorooctanoic acid, a key ingredient used in manufacturing Teflon, and DuPont's potential responsibility. PFAS are commonly found in every household, and in products as diverse as non-stick cookware, stain resistant furniture and carpets, wrinkle free and water repellant clothing, cosmetics, lubricants, paint, pizza boxes, popcorn bags, and many other everyday products.

Water contamination in Lawrence and Morgan Counties, Alabama

Water contamination in Lawrence and Morgan Counties, Alabama, revolves around the presence of perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS) in the water supply. After the US Environmental Protection Agency (EPA) released new health advisories in March 2016, there was concern over health risks of the levels of PFOA and PFOS present. The responses of different government officials, agencies, and companies raise questions as to whether or not there was any environmental injustice involved.

GenX is a Chemours trademark name for a synthetic, short-chain organofluorine chemical compound, the ammonium salt of hexafluoropropylene oxide dimer acid (HFPO-DA) fluoride. It can also be used more informally to refer to the group of related fluorochemicals that are used to produce GenX. DuPont began the commercial development of GenX in 2009 as a replacement for perfluorooctanoic acid.

This timeline of events related to per- and polyfluoroalkyl substances (PFASs) includes events related to the discovery, development, manufacture, marketing, uses, concerns, litigation, regulation, and legislation, involving the human-made PFASs, particularly perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS). and about the companies, mainly DuPont and 3M that manufactured and marketed them. Perfluorinated compounds are a group of hundreds of human-made compounds collectively known" as PFAS. Fluorosurfactants (PFAS) have been produced and marketed by DuPont under its trademark Teflon—a fluorinated polymer. PFAS compounds and their derivatives are widely used in many products from water resistant textiles to fire-fighting foam. A replacement for PFOAs and PFOS—GenX chemicals and PFBS—are "human-made, fluorinated organic chemicals that are part of the larger group —per- and polyfluoroalkyl substances (PFAS).

Textile performance Fitness for purpose of textiles

Textile performance, also known as fitness for purpose, is a textile's capacity to withstand various conditions, environments, and hazards, qualifying it for particular uses. The performance of textile products influences their appearance, comfort, durability, and protection. Different textile applications require a different set of performance parameters. As a result, the specifications determine the level of performance of a textile product. Textile testing certifies the product's conformity to buying specification. It describes product manufactured for non-aesthetic purposes, where fitness for purpose is the primary criterion. Engineering of high performance fabrics presents a unique set of challenges.

Chemical finishing of textiles Chemical finishing methods that may alter the chemical properties of the treated fabrics

Chemical finishing of textiles refers to the process of applying and treating textiles with a variety of chemicals in order to achieve desired functional properties. Chemical finishing of textiles is a part of the textile finishing process where the emphasis is on chemical substances instead of mechanical finishing. Chemical finishing in textiles also known as wet finishing. Chemical finishing adds properties to the treated textiles. These properties may vary from Normal to Advanced or High Tech. Softening of textiles, durable water repellancy and wrinkle free fabric finishes are examples of chemical finishing.