Author | Robert Brent |
---|---|
Illustrator | Harry Lazarus |
Country | United States |
Language | English |
Series | Golden Books |
Subject | Chemistry |
Genre | Textbook |
Publisher | Western Publishing |
Publication date | 1960 |
Pages | 112 |
The Golden Book of Chemistry Experiments is a children's chemistry book written in 1960 by Robert Brent and illustrated by Harry Lazarus and published by Western Publishing as part of their Golden Books series.
A decade after the book's publication, concerns were raised over the safety of the reactions described, which frequently used or generated toxic or corrosive substances. For example, one experiment generated toxic chlorine gas, and another used carbon tetrachloride, a potent hepatotoxin. [1]
The book was also believed to be a source of inspiration to David Hahn, nicknamed "the Radioactive Boy Scout" by the media, who attempted to construct a nuclear reactor in his mother's shed, [2] although the book does not include any nuclear reactions.
Due to safety concerns, the book was eventually pulled from library shelves. [3] It is now quite rare, and as of November 2023 [update] OCLC lists only 101 copies of this book in libraries worldwide. [4] However, privately-owned copies are routinely put up for sale online.
The first edition was printed in 1960. A second printing was made in 1962 and a revised edition was printed in 1963.
Americium is a synthetic chemical element; it has symbol Am and atomic number 95. It is radioactive and a transuranic member of the actinide series in the periodic table, located under the lanthanide element europium and was thus named after the Americas by analogy.
Heavy water is a form of water whose hydrogen atoms are all deuterium rather than the common hydrogen-1 isotope that makes up most of the hydrogen in normal water. The presence of the heavier hydrogen isotope gives the water different nuclear properties, and the increase in mass gives it slightly different physical and chemical properties when compared to normal water.
Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radioactive decay.
A nuclear reactor is a device used to initiate and control a fission nuclear chain reaction or nuclear fusion reactions. Nuclear reactors are used at nuclear power plants for electricity generation and in nuclear marine propulsion. Heat from nuclear fission is passed to a working fluid, which in turn runs through steam turbines. These either drive a ship's propellers or turn electrical generators' shafts. Nuclear generated steam in principle can be used for industrial process heat or for district heating. Some reactors are used to produce isotopes for medical and industrial use, or for production of weapons-grade plutonium. As of 2022, the International Atomic Energy Agency reports there are 422 nuclear power reactors and 223 nuclear research reactors in operation around the world.
Nuclear power is the use of nuclear reactions to produce electricity. Nuclear power can be obtained from nuclear fission, nuclear decay and nuclear fusion reactions. Presently, the vast majority of electricity from nuclear power is produced by nuclear fission of uranium and plutonium in nuclear power plants. Nuclear decay processes are used in niche applications such as radioisotope thermoelectric generators in some space probes such as Voyager 2. Generating electricity from fusion power remains the focus of international research.
A nuclear meltdown is a severe nuclear reactor accident that results in core damage from overheating. The term nuclear meltdown is not officially defined by the International Atomic Energy Agency or by the United States Nuclear Regulatory Commission. It has been defined to mean the accidental melting of the core of a nuclear reactor, however, and is in common usage a reference to the core's either complete or partial collapse.
The Nuclear Regulatory Commission (NRC) is an independent agency of the United States government tasked with protecting public health and safety related to nuclear energy. Established by the Energy Reorganization Act of 1974, the NRC began operations on January 19, 1975, as one of two successor agencies to the United States Atomic Energy Commission. Its functions include overseeing reactor safety and security, administering reactor licensing and renewal, licensing radioactive materials, radionuclide safety, and managing the storage, security, recycling, and disposal of spent fuel.
A radioisotope thermoelectric generator, sometimes referred to as a radioisotope power system (RPS), is a type of nuclear battery that uses an array of thermocouples to convert the heat released by the decay of a suitable radioactive material into electricity by the Seebeck effect. This type of generator has no moving parts. Because they don't need solar energy, RTGs are ideal for remote and harsh environments for extended periods of time, and because they have no moving parts, there is no risk of parts wearing out or malfunctioning.
Nuclear chemistry is the sub-field of chemistry dealing with radioactivity, nuclear processes, and transformations in the nuclei of atoms, such as nuclear transmutation and nuclear properties.
A nuclear and radiation accident is defined by the International Atomic Energy Agency (IAEA) as "an event that has led to significant consequences to people, the environment or the facility. Examples include lethal effects to individuals, large radioactivity release to the environment, reactor core melt." The prime example of a "major nuclear accident" is one in which a reactor core is damaged and significant amounts of radioactive isotopes are released, such as in the Chernobyl disaster in 1986 and Fukushima nuclear disaster in 2011.
Uranium-238 is the most common isotope of uranium found in nature, with a relative abundance of 99%. Unlike uranium-235, it is non-fissile, which means it cannot sustain a chain reaction in a thermal-neutron reactor. However, it is fissionable by fast neutrons, and is fertile, meaning it can be transmuted to fissile plutonium-239. 238U cannot support a chain reaction because inelastic scattering reduces neutron energy below the range where fast fission of one or more next-generation nuclei is probable. Doppler broadening of 238U's neutron absorption resonances, increasing absorption as fuel temperature increases, is also an essential negative feedback mechanism for reactor control.
David Charles Hahn, sometimes called the "Radioactive Boy Scout" or the "Nuclear Boy Scout", was an American nuclear radiation enthusiast who built a homemade neutron source at the age of seventeen.
PLUTO was a materials testing nuclear reactor housed at the Atomic Energy Research Establishment, a former Royal Air Force airfield at Harwell, Oxfordshire in the United Kingdom.
Neutron activation is the process in which neutron radiation induces radioactivity in materials, and occurs when atomic nuclei capture free neutrons, becoming heavier and entering excited states. The excited nucleus decays immediately by emitting gamma rays, or particles such as beta particles, alpha particles, fission products, and neutrons. Thus, the process of neutron capture, even after any intermediate decay, often results in the formation of an unstable activation product. Such radioactive nuclei can exhibit half-lives ranging from small fractions of a second to many years.
Nuclear fuel is material used in nuclear power stations to produce heat to power turbines. Heat is created when nuclear fuel undergoes nuclear fission.
Spent fuel pools (SFP) are storage pools for spent fuel from nuclear reactors. They are typically 40 or more feet (12 m) deep, with the bottom 14 feet equipped with storage racks designed to hold fuel assemblies removed from reactors. A reactor's local pool is specially designed for the reactor in which the fuel was used and is situated at the reactor site. Such pools are used for short-term cooling of the fuel rods. This allows short-lived isotopes to decay and thus reduces the ionizing radiation and decay heat emanating from the rods. The water cools the fuel and provides radiological protection from its radiation.
A liquid metal cooled nuclear reactor, or LMR is a type of nuclear reactor where the primary coolant is a liquid metal. Liquid metal cooled reactors were first adapted for breeder reactor power generation. They have also been used to power nuclear submarines.
The Sodium Reactor Experiment was a pioneering nuclear power plant built by Atomics International at the Santa Susana Field Laboratory near Simi Valley, California. The reactor operated from 1957 to 1964. On July 12, 1957 the Sodium Reactor Experiment became the first nuclear reactor in California to produce electrical power for a commercial power grid by powering the nearby city of Moorpark. In July 1959, the reactor experienced a partial meltdown when 13 of the reactor's 43 fuel elements partially melted, and a controlled release of radioactive gas into the atmosphere occurred. The reactor was repaired and restarted in September 1960. In February 1964, the Sodium Reactor Experiment was in operation for the last time. Removal of the deactivated reactor was completed in 1981. Technical analyses of the 1959 incident have produced contrasting conclusions regarding the types and quantities of radioactive materials released. Members of the neighboring communities have expressed concerns about the possible impacts on their health and environment from the incident. In August 2009, 50 years after the occurrence, the Department of Energy hosted a community workshop to discuss the 1959 incident.
A nuclear reactor coolant is a coolant in a nuclear reactor used to remove heat from the nuclear reactor core and transfer it to electrical generators and the environment. Frequently, a chain of two coolant loops are used because the primary coolant loop takes on short-term radioactivity from the reactor.
Americium-241 is an isotope of americium. Like all isotopes of americium, it is radioactive, with a half-life of 432.2 years. 241
Am
is the most common isotope of americium as well as the most prevalent isotope of americium in nuclear waste. It is commonly found in ionization type smoke detectors and is a potential fuel for long-lifetime radioisotope thermoelectric generators (RTGs). Its common parent nuclides are β− from 241
Pu
, EC from 241
Cm
, and α from 245
Bk
. 241
Am
is fissile and the critical mass of a bare sphere is 57.6–75.6 kilograms (127.0–166.7 lb) and a sphere diameter of 19–21 centimetres (7.5–8.3 in). Americium-241 has a specific activity of 3.43 Ci/g (126.91 GBq/g). It is commonly found in the form of americium-241 dioxide. This isotope also has one meta state, 241m
Am
, with an excitation energy of 2.2 MeV (0.35 pJ) and a half-life of 1.23 μs. The presence of americium-241 in plutonium is determined by the original concentration of plutonium-241 and the sample age. Because of the low penetration of alpha radiation, americium-241 only poses a health risk when ingested or inhaled. Older samples of plutonium containing 241
Pu
contain a buildup of 241
Am
. A chemical removal of americium-241 from reworked plutonium may be required in some cases.