Tribofilm

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Tribofilms (boundary lubricant films, [1] boundary lubricating films, [2] tribo-boundary films [3] or boundary films [4] ) are films that form on tribologically stressed surfaces. Tribofilms are mostly solid surface films that result from a chemical reaction of lubricant components or tribological surfaces.

Tribofilms play an important role in reducing friction and wear in lubricated systems. They form as a result of complex mechanochemical interactions between surface materials and lubricants, [5] and the study of tribofilm formation processes is a major field of tribology.

Generally, a tribofilm is any film that forms in a tribosystem "as a result of interaction between chemical components of the [lubricant] with the lubricated surface". [6] The term is mostly used to describe strongly bound films that are formed on tribologically stressed surfaces, such as tribochemical reaction films [1] (for example produced by ZDDP-containing lubricants [7] [8] ) or polymeric and non-sacrificial reaction films (for example formed by complex esters). [1]

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Friction is the force resisting the relative motion of solid surfaces, fluid layers, and material elements sliding against each other. There are several types of friction:

A lubricant is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity.

<span class="mw-page-title-main">Lubrication</span> The presence of a material to reduce friction between two surfaces.

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<span class="mw-page-title-main">Wear</span> Damaging, gradual removal or deformation of material at solid surfaces

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Tribology is the science and engineering of interacting surfaces in relative motion. It includes the study and application of the principles of friction, lubrication and wear. Tribology is highly interdisciplinary, drawing on many academic fields, including physics, chemistry, materials science, mathematics, biology and engineering. People who work in the field of tribology are referred to as tribologists.

<span class="mw-page-title-main">Zinc dithiophosphate</span> Lubricant additive

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<span class="mw-page-title-main">Robert Carpick</span>

Robert William Carpick is a Canadian mechanical engineer. He is currently director of diversity, equity, and inclusion and John Henry Towne Professor in the Department of Mechanical Engineering and Applied Mechanics at the University of Pennsylvania. He is best known for his work in tribology, particularly nanotribology.

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<span class="mw-page-title-main">Q. Jane Wang</span> Chinese-American tribologist

Qian Jane Wang is an American professor of mechanical engineering and the Executive Director for the Center for Surface Engineering and Tribology at Northwestern University. She is a tribologist whose research includes work on contact mechanics, lubrication, micromechanics, and solid-state batteries.

References

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  2. Hsu, S.M.; Gates, R.S. (2005). "Boundary lubricating films: formation and lubrication mechanism". Tribology International. 38 (3): 305–312. doi:10.1016/j.triboint.2004.08.021.
  3. Qu, Jun; Chi, Miaofang; Meyer, Harry M.; Blau, Peter J.; Dai, Sheng; Luo, Huimin (2011-08-01). "Nanostructure and Composition of Tribo-Boundary Films Formed in Ionic Liquid Lubrication". Tribology Letters. 43 (2): 205–211. doi:10.1007/s11249-011-9800-z. ISSN   1023-8883. S2CID   137805525.
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