An ultrafast monochromator is a monochromator that preserves the duration of an ultrashort pulse (in the femtosecond, or lower, time-scale). [1] [2] Monochromators are devices that select for a particular wavelength, typically using a diffraction grating to disperse the light and a slit to select the desired wavelength; however, a diffraction grating introduces path delays that measurably lengthen the duration of an ultrashort pulse. An ultrafast monochromator uses a second diffraction grating to compensate time delays introduced to the pulse by the first grating and other dispersive optical elements.
Diffraction gratings are constructed such that the angle of the incident ray, θi, is related to the angle of the mth outgoing ray, θm, by the expression
Two rays diffracted by adjacent grooves will differ in path length by a distance mλ. The total difference between the longest and shortest path within a beam is computed by multiplying mλ by the total number of grooves illuminated.
For instance, a beam of width 10 mm illuminating a grating with 1200 grooves/mm uses 12,000 grooves. At a wavelength of 10 nm, the first order diffracted beam, m = 1, will have a path length variation across the beam of 120 μm. This corresponds to a time difference in the arrival of 400 femtoseconds. This is often negligible for picosecond pulses but not for those of femtosecond duration.
A major application is the extraction, without time-broadening, of a single high-order harmonic pulse out of the many generated by an ultrafast laser pulse interacting with a gas target.[ citation needed ]
Diffraction refers to various phenomena that occur when a wave encounters an obstacle or opening. It is defined as the interference or bending of waves around the corners of an obstacle or through an aperture into the region of geometrical shadow of the obstacle/aperture. The diffracting object or aperture effectively becomes a secondary source of the propagating wave. Italian scientist Francesco Maria Grimaldi coined the word diffraction and was the first to record accurate observations of the phenomenon in 1660.
In optics, a diffraction grating is an optical component with a periodic structure that diffracts light into several beams travelling in different directions. The emerging coloration is a form of structural coloration. The directions or diffraction angles of these beams depend on the wave (light) incident angle to the diffraction grating, the spacing or distance between adjacent diffracting elements on the grating, and the wavelength of the incident light. The grating acts as a dispersive element. Because of this, diffraction gratings are commonly used in monochromators and spectrometers, but other applications are also possible such as optical encoders for high precision motion control and wavefront measurement.
X-ray fluorescence (XRF) is the emission of characteristic "secondary" X-rays from a material that has been excited by being bombarded with high-energy X-rays or gamma rays. The phenomenon is widely used for elemental analysis and chemical analysis, particularly in the investigation of metals, glass, ceramics and building materials, and for research in geochemistry, forensic science, archaeology and art objects such as paintings.
In physics and chemistry, Bragg's law, Wulff–Bragg's condition or Laue-Bragg interference, a special case of Laue diffraction, gives the angles for coherent scattering of waves from a crystal lattice. It encompasses the superposition of wave fronts scattered by lattice planes, leading to a strict relation between wavelength and scattering angle, or else to the wavevector transfer with respect to the crystal lattice. Such law had initially been formulated for X-rays upon crystals. However, It applies to all sorts of quantum beams, including neutron and electron waves at atomic distances, as well as visible light at artificial periodic microscale lattices.
A monochromator is an optical device that transmits a mechanically selectable narrow band of wavelengths of light or other radiation chosen from a wider range of wavelengths available at the input. The name is from the Greek roots mono-, "single", and chroma, "colour", and the Latin suffix -ator, denoting an agent.
In optics, the Fraunhofer diffraction equation is used to model the diffraction of waves when the diffraction pattern is viewed at a long distance from the diffracting object, and also when it is viewed at the focal plane of an imaging lens. In contrast, the diffraction pattern created near the object is given by the Fresnel diffraction equation.
In optics, an ultrashort pulse, also known as an ultrafast event, is an electromagnetic pulse whose time duration is of the order of a picosecond or less. Such pulses have a broadband optical spectrum, and can be created by mode-locked oscillators. Amplification of ultrashort pulses almost always requires the technique of chirped pulse amplification, in order to avoid damage to the gain medium of the amplifier.
In physics, terahertz time-domain spectroscopy (THz-TDS) is a spectroscopic technique in which the properties of matter are probed with short pulses of terahertz radiation. The generation and detection scheme is sensitive to the sample's effect on both the amplitude and the phase of the terahertz radiation. By measuring in the time-domain, the technique can provide more information than conventional Fourier-transform spectroscopy, which is only sensitive to the amplitude.
An acousto-optic modulator (AOM), also called a Bragg cell or an acousto-optic deflector (AOD), uses the acousto-optic effect to diffract and shift the frequency of light using sound waves. They are used in lasers for Q-switching, telecommunications for signal modulation, and in spectroscopy for frequency control. A piezoelectric transducer is attached to a material such as glass. An oscillating electric signal drives the transducer to vibrate, which creates sound waves in the material. These can be thought of as moving periodic planes of expansion and compression that change the index of refraction. Incoming light scatters off the resulting periodic index modulation and interference occurs similar to Bragg diffraction. The interaction can be thought of as a three-wave mixing process resulting in Sum-frequency generation or Difference-frequency generation between phonons and photons.
Chirped pulse amplification (CPA) is a technique for amplifying an ultrashort laser pulse up to the petawatt level, with the laser pulse being stretched out temporally and spectrally, then amplified, and then compressed again. The stretching and compression uses devices that ensure that the different color components of the pulse travel different distances.
Ultrafast laser spectroscopy is a spectroscopic technique that uses ultrashort pulse lasers for the study of dynamics on extremely short time scales. Different methods are used to examine the dynamics of charge carriers, atoms, and molecules. Many different procedures have been developed spanning different time scales and photon energy ranges; some common methods are listed below.
A prism compressor is an optical device used to shorten the duration of a positively chirped ultrashort laser pulse by giving different wavelength components a different time delay. It typically consists of two prisms and a mirror. Figure 1 shows the construction of such a compressor. Although the dispersion of the prism material causes different wavelength components to travel along different paths, the compressor is built such that all wavelength components leave the compressor at different times, but in the same direction. If the different wavelength components of a laser pulse were already separated in time, the prism compressor can make them overlap with each other, thus causing a shorter pulse.
In optics, a dispersive prism is an optical prism that is used to disperse light, that is, to separate light into its spectral components. Different wavelengths (colors) of light will be deflected by the prism at different angles. This is a result of the prism material's index of refraction varying with wavelength (dispersion). Generally, longer wavelengths (red) undergo a smaller deviation than shorter wavelengths (blue). The dispersion of white light into colors by a prism led Sir Isaac Newton to conclude that white light consisted of a mixture of different colors.
Volume holograms are holograms where the thickness of the recording material is much larger than the light wavelength used for recording. In this case diffraction of light from the hologram is possible only as Bragg diffraction, i.e., the light has to have the right wavelength (color) and the wave must have the right shape. Volume holograms are also called thick holograms or Bragg holograms.
The European X-Ray Free-Electron Laser Facility is an X-ray research laser facility commissioned during 2017. The first laser pulses were produced in May 2017 and the facility started user operation in September 2017. The international project with twelve participating countries; nine shareholders at the time of commissioning, later joined by three other partners, is located in the German federal states of Hamburg and Schleswig-Holstein. A free-electron laser generates high-intensity electromagnetic radiation by accelerating electrons to relativistic speeds and directing them through special magnetic structures. The European XFEL is constructed such that the electrons produce X-ray light in synchronisation, resulting in high-intensity X-ray pulses with the properties of laser light and at intensities much brighter than those produced by conventional synchrotron light sources.
The first description of multiple-prism arrays, and multiple-prism dispersion, was given by Newton in his book Opticks. Prism pair expanders were introduced by Brewster in 1813. A modern mathematical description of the single-prism dispersion was given by Born and Wolf in 1959. The generalized multiple-prism dispersion theory was introduced by Duarte and Piper in 1982.
Multiple-prism grating laser oscillators, or MPG laser oscillators, use multiple-prism beam expansion to illuminate a diffraction grating mounted either in Littrow configuration or grazing-incidence configuration. Originally, these narrow-linewidth tunable dispersive oscillators were introduced as multiple-prism Littrow (MPL) grating oscillators, or hybrid multiple-prism near-grazing-incidence (HMPGI) grating cavities, in organic dye lasers. However, these designs were quickly adopted for other types of lasers such as gas lasers, diode lasers, and more recently fiber lasers.
Ultrafast X-rays or ultrashort X-ray pulses are femtosecond x-ray pulses with wavelengths occurring at interatomic distances. This beam uses the X-ray's inherent abilities to interact at the level of atomic nuclei and core electrons. This ability combined with the shorter pulses at 30 femtosecond could capture the change in position of atoms, or molecules during phase transitions, chemical reactions, and other transient processes in physics, chemistry, and biology.
Polarization ripples are parallel oscillations which have been observed since the 1960s on the bottom of pulsed laser irradiation of semiconductors. They have the property to be very dependent to the orientation of the laser electric field.
Ultrafast electron diffraction (UED), also known as femtosecond electron diffraction (FED), is a pump-probe experimental method based on the combination of optical pump-probe spectroscopy and electron diffraction. UED provides information on the dynamical changes of the structure of materials. It is very similar to time resolved crystallography, but instead of using X-rays as the probe, it uses electrons. In the UED technique, a femtosecond (fs) laser optical pulse excites (pumps) a sample into an excited, usually non-equilibrium, state. The pump pulse may induce chemical, electronic or structural transitions. After a finite time interval, a fs electron pulse is incident upon the sample. The electron pulse undergoes diffraction as a result of interacting with the sample. The diffraction signal is, subsequently, detected by an electron counting instrument such as a CCD camera. Specifically, after the electron pulse diffracts from the sample, the scattered electrons will form a diffraction pattern (image) on a CCD camera. This pattern contains structural information about the sample. By adjusting the time difference between the arrival of the pump and probe beams, one can obtain a series of diffraction patterns as a function of the various time differences. The diffraction data series can be concatenated in order to produce a motion picture of the changes that occurred in the data. UED can provide a wealth of dynamics on charge carriers, atoms, and molecules.
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(help)Palmer, Christopher (2020). Diffraction Grating Handbook (8th ed.). MKS Newport.