Vasilseverginite

Last updated
Vasilseverginite
General
Category Arsenate mineral
Formula
(repeating unit)
Cu9O4(AsO4)2(SO4)2
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/m
Unit cell a = 8.113(4)  Å
b = 9.918(4) Å
c = 11.0225(5) Å; β = 110.86° (approximated)
Identification
References [1] [2]

Vasilseverginite is a very rare arsenate-sulfate mineral [2] with formula Cu9O4(AsO4)2(SO4)2. Its structure is of a new type. [1] It possesses a typical feature of many minerals of its type locality, the Tolbachik volcano, namely being a salt with oxide anions. However, it is the first Tolbachik copper oxysalt that is both arsenate and sulfate. [3] Vasilseverginite is monoclinic, with space group P21/n. [2]

Related Research Articles

Kainite

Kainite ( or ) (KMg(SO4)Cl·3H2O) is an evaporite mineral in the class of "Sulfates (selenates, etc.) with additional anions, with H2O" according to the Nickel–Strunz classification. It is a hydrated potassium-magnesium sulfate-chloride, naturally occurring in irregular granular masses or as crystalline coatings in cavities or fissures. This mineral is dull and soft, and is colored white, yellowish, grey, reddish, or blue to violet. Its name is derived from Greek καινος [kainos] ("(hitherto) unknown"), as it was the first mineral discovered that contained both sulfate and chloride as anions. Kainite forms monoclinic crystals.

Tolbachik

Tolbachik is a volcanic complex on the Kamchatka Peninsula in the far east of Russia. It consists of two volcanoes, Plosky (flat) Tolbachik and Ostry (sharp) Tolbachik, which as the names suggest are respectively a flat-topped shield volcano and a peaked stratovolcano. As Ostry is the mountain's highest point, the entire mountain is often referred to as "Ostry Tolbachik", not to be confused with Ostry, a separate volcano to the north also on the Kamchatka Peninsula.

Alarsite

Alarsite (AlAsO4) is an aluminium arsenate mineral with its name derived from its composition: aluminium and arsenate. Its IMA symbol is Ars. It occurs as brittle subhedral grains which exhibit trigonal symmetry. It has a Mohs hardness of 5-5.5 and a specific gravity of 3.32. It is semitransparent, colorless with pale yellow tints and shows a vitreous luster. It is optically uniaxial (+) with refractive indices of nω = 1.596 and nε = 1.608.

Urusovite is a rare copper aluminium arsenate mineral with formula: CuAlAsO5. It is a monoclinic-prismatic light green mineral.

Piypite

Piypite is a rare potassium, copper sulfate mineral with formula: K2Cu2O(SO4)2. It crystallizes in the tetragonal system and occurs as needlelike crystals and masses. Individual crystals are square in cross-section and often hollow. It is emerald green to black in color with a vitreous to greasy luster.

Feodosiyite is a very rare chloride mineral, just recently approved, with the formula Cu11Mg2Cl18(OH)8•16H2O. Its structure is unique. Feodosiyite comes from the Tolbachik volcano, famous for many rare fumarolic minerals. Chemically similar minerals, chlorides containing both copper and magnesium, include haydeeite, paratacamite-(Mg) and tondiite.

Castellaroite is a rare arsenate mineral with formula Mn3(AsO4)2•4H2O. It is related to the phosphate mineral metaswitzerite. Castellaroite is monoclinic, with space group P21/n. The other natural manganese arsenate hydrate is manganohörnesite, which is an octahydrate.

Juansilvaite

Juansilvaite is a very rare, complex arsenate-sulfate mineral with formula Na5Al3[AsO3(OH)]4[AsO2(OH)2]2(SO4)2·4H2O. It is both hydroxyarsenate and dihydroxyarsenate. It is among few relatively new minerals from the Torrecillas mine in Chile, the other being torrecillasite, canutite, chongite, gajardoite, leverettite, and magnesiokoritnigite. Although having quite common among minerals space group C2/c, juansilvaite has a new type of structure.

Fermiite is a rare uranium mineral with the formula Na4(UO2)(SO4)3·3H2O. Chemically related minerals include oppenheimerite, meisserite (which is also structurally-related to fermiite), belakovskiite, natrozippeite and plášilite. Fermiite comes from the Blue Lizard mine, San Juan County, Utah, USA, which is known for many rare uranium minerals. The name honors Enrico Fermi (1901–1954).

Oppenheimerite is a very rare uranium mineral with the formula Na2(UO2)(SO4)2•3H2O. Chemically related minerals include fermiite, natrozippeite, plášilite, belakovskiite and meisserite. Most of these uranyl sulfate minerals were originally found in the Blue Lizard mine, San Juan County, Utah, US. The mineral is named after American Theoretical physicist J. Robert Oppenheimer.

Plášilite is a very rare uranium mineral with the formula Na2(UO2)(SO4)2•3H2O. Chemically related minerals include natrozippeite, belakovskiite, meisserite, fermiite and oppenheimerite. Most of these uranyl sulfate minerals were originally found in the Blue Lizard mine, San Juan County, Utah, US. The mineral is named after Czech crystallographer Jakub Plášil.

Chrysothallite is a rare thallium-bearing chloride mineral with the formula K6Cu6Tl3+Cl17(OH)4•H2O. Chrysothallite is unique in being only the second mineral with essential trivalent thallium, a feature shared with natural thallium(III) oxide, avicennite. Another examples of natural thallium chlorides are steropesite, Tl3BiCl6, and lafossaite, TlCl. Chrysothallite is one of numerous fumarolic minerals discovered among fumarolic sites of the Tolbachik volcano, Kamchatka, Russia The mineral is named in allusion to its colour and thallium content.

Itelmenite is a rare sulfate mineral with the formula Na4Mg3Cu3(SO4)8. It is one of many fumarolic minerals discovered on the Tolbachik volcano.

Hermannjahnite is a rare sulfate mineral with the relatively simple formula CuZn(SO4)2. It is one of many fumarolic minerals discovered on the Tolbachik volcano.

Kainotropite is a rare vanadate mineral with the formula Cu4FeO2(V2O7)(VO4). It contains trivalent iron. It is one of many fumarolic minerals discovered on the Tolbachik volcano. The name of its parental fumarole is "Yadovitaya", which means poisonous.

Bieberite

Bieberite (CoSO4 · 7H2O) is a pinkish red colored sulfate mineral high in cobalt content. The name is derived from the type locality at the copper deposit in Bieber, Hesse, Germany. It has been described and reported as far back as the 1700s. Bieberite primarily occurs as a secondary mineral, forming in cobalt-bearing arsenide and sulfide deposits through oxidation.

Euchlorine (KNaCu3(SO4)3O) is a rare emerald-green colored sulfate mineral found naturally occurring as a sublimate in fumaroles around volcanic eruptions. It was first discovered in fumaroles of the 1868 eruption at Mount Vesuvius in Campania, Italy by Arcangelo Scacchi. The name 'euchlorine' comes from the Greek word εΰχλωρος meaning "pale green" in reference to the mineral's color, other reported spellings include euclorina, euchlorin, and euchlorite.

The sulfate chlorides are double salts containing both sulfate (SO42–) and chloride (Cl) anions. They are distinct from the chlorosulfates, which have a chlorine atom attached to the sulfur as the ClSO3 anion.

The sulfate fluorides are double salts that contain both sulfate and fluoride anions. They are in the class of mixed anion compounds. Some of these minerals are deposited in fumaroles.

Fumarole mineral Minerals deposited by gases

Fumarole minerals are minerals which are deposited by fumarole exhalations. They form when gases and compounds desublimate or precipitate out of condensates, forming mineral deposits. They are mostly associated with volcanoes, but have been encountered on burning coal deposits as well. They can be black or multicoloured and are often unstable upon exposure to the atmosphere.

References

  1. 1 2 Pekov, I.V., Britvin, S.N., Yapaskurt, V.O., Krivovichev, S.V., Vigasina, M.F., and Sidorov, E.G., 2015. Vasilseverginite, IMA 2015-083. CNMNC Newsletter No. 28, December 2015, 1864; Mineralogical Magazine 79, 1859–1864
  2. 1 2 3 "Vasilseverginite: Vasilseverginite mineral information and data". Mindat.org. Retrieved 2016-03-10.
  3. "Tolbachik volcano, Kamchatka Oblast', Far-Eastern Region, Russia - Mindat.org". Mindat.org. Retrieved 2016-03-04.