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Manganese is a chemical element; it has symbol Mn and atomic number 25. It is a hard, brittle, silvery metal, often found in minerals in combination with iron. Manganese was first isolated in the 1770s. Manganese is a transition metal with a multifaceted array of industrial alloy uses, particularly in stainless steels. It improves strength, workability, and resistance to wear. Manganese oxide is used as an oxidising agent; as a rubber additive; and in glass making, fertilisers, and ceramics. Manganese sulfate can be used as a fungicide.
Polymetallic nodules, also called manganese nodules, are mineral concretions on the sea bottom formed of concentric layers of iron and manganese hydroxides around a core. As nodules can be found in vast quantities, and contain valuable metals, deposits have been identified as a potential economic interest. Depending on their composition and autorial choice, they may also be called ferromanganese or polymetallic nodules. Ferromanganese nodules are mineral concretions composed of silicates and insoluble iron and manganese oxides that form on the ocean seafloor and terrestrial soils. The formation mechanism involves a series of redox oscillations driven by both abiotic and biotic processes. As a byproduct of pedogenesis, the specific composition of a ferromanganese nodule depends on the composition of the surrounding soil. The formation mechanisms and composition of the nodules allow for couplings with biogeochemical cycles beyond iron and manganese. The high relative abundance of nickel, copper, manganese, and other rare metals in nodules has increased interest in their use as a mining resource.
Psilomelane is a group name for hard black manganese oxides including hollandite and romanechite. Psilomelane consists of hydrous manganese oxide with variable amounts of barium and potassium. Psilomelane is erroneously, and uncommonly, known as black hematite, despite not being related to true hematite, which is an iron oxide.
Manganese oxide is any of a variety of manganese oxides and hydroxides. These include
Pyrolusite is a mineral consisting essentially of manganese dioxide (MnO2) and is important as an ore of manganese. It is a black, amorphous appearing mineral, often with a granular, fibrous, or columnar structure, sometimes forming reniform crusts. It has a metallic luster, a black or bluish-black streak, and readily soils the fingers. The specific gravity is about 4.8. Its name is from the Greek for fire and to wash, in reference to its use as a way to remove tints from glass.
Manganite is a mineral composed of manganese oxide-hydroxide, MnO(OH), crystallizing in the monoclinic system (pseudo-orthorhombic). Crystals of manganite are prismatic and deeply striated parallel to their length; they are often grouped together in bundles. The color is dark steel-grey to iron-black, and the luster brilliant and submetallic. The streak is dark reddish brown. The hardness is 4, and the specific gravity is 4.3. There is a perfect cleavage parallel to the brachypinacoid, and less-perfect cleavage parallel to the prism faces. Twinned crystals are not infrequent.
Rhodonite is a manganese inosilicate, with the formula (Mn, Fe, Mg, Ca)SiO3, and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (its name comes from Ancient Greek ῥόδον (rhódon) 'rose'), often tending to brown due to surface oxidation. The rose-red hue is caused by the manganese cation (Mn2+).
WAD, Wad, or wad may refer to:
Gossan is intensely oxidized, weathered or decomposed rock, usually the upper and exposed part of an ore deposit or mineral vein. In the classic gossan or iron cap all that remains is iron oxides and quartz, often in the form of boxworks. In other cases, quartz and iron oxides, limonite, goethite, and jarosite, exist as pseudomorphs, replacing the pyrite and primary ore minerals. Frequently, gossan appears as a red "stain" against the background rock and soil, due to the abundance of oxidized iron; the gossan may be a topographic positive area due to the abundance of erosion-resistant quartz and iron oxides. Although most gossans are red, orange, or yellow, black gossans from manganese oxides such as pyrolusite, manganite, and especially psilomelane form at the oxidized portion of manganese-rich mineral deposits.
Hausmannite is a complex oxide, or a mixed oxide, of manganese containing both di- and tri-valent manganese. Its chemical formula can be represented as MnIIMnIII2O4, or more simply noted as MnO·Mn2O3, or Mn3O4, as commonly done for magnetite, the corresponding iron oxide. It belongs to the spinel group and forms tetragonal crystals. Hausmannite is a brown to black metallic mineral with Mohs hardness of 5.5 and a specific gravity of 4.8.
Lithiophilite is a mineral containing the element lithium. It is lithium manganese(II) phosphate with chemical formula LiMnPO4. It occurs in pegmatites often associated with triphylite, the iron end member in a solid solution series. The mineral with intermediate composition is known as sicklerite and has the chemical formula Li(Mn,Fe)PO4). The name lithiophilite is derived from the Greek philos (φιλός) "friend", as lithiophilite is usually found with lithium.
Bixbyite is a manganese iron oxide mineral with chemical formula: (Mn,Fe)2O3. The iron/manganese ratio is quite variable and many specimens have almost no iron. It is a metallic dark black with a Mohs hardness of 6.0 – 6.5. It is a somewhat rare mineral sought after by collectors as it typically forms euhedral isometric crystals exhibiting various cubes, octahedra, and dodecahedra.
Todorokite is a complex hydrous manganese oxide mineral with generic chemical formula (Na,Ca,K,Ba,Sr)
1-x(Mn,Mg,Al)
6O
12·3-4H
2O. It was named in 1934 for the type locality, the Todoroki mine, Hokkaido, Japan. It belongs to the prismatic class 2/m of the monoclinic crystal system, but the angle β between the a and c axes is close to 90°, making it seem orthorhombic. It is a brown to black mineral which occurs in massive or tuberose forms. It is quite soft with a Mohs hardness of 1.5, and a specific gravity of 3.49 – 3.82. It is a component of deep ocean basin manganese nodules.
Moss agate is a semi-precious gemstone formed from silicon dioxide. It is a form of chalcedony which includes minerals of a green color embedded in the stone, forming filaments and other patterns suggestive of moss. The field is a clear or milky-white quartz, and the included minerals are mainly oxides of manganese or iron. It is not a true form of agate, because it does not have concentric banding.
Bromellite, whose name derives from the Swedish chemist Magnus von Bromell (1670–1731), is a white oxide mineral. The mineral form of beryllium oxide, it is found in complex pegmatitic manganese-iron deposits, but is more frequently made synthetically. This is a rare mineral to encounter in its natural state, but it has been made synthetically for over 40 years.
Jacobsite is a manganese iron oxide mineral. It is in the spinel group and forms a solid solution series with magnetite. The chemical formula is (Mn,Mg)Fe2O4 or with oxidation states and substitutions: (Mn2+,Fe2+,Mg)(Fe3+,Mn3+)2O4.
Chlorargyrite is the mineral form of silver chloride (AgCl). Chlorargyrite occurs as a secondary mineral phase in the oxidation of silver mineral deposits. It crystallizes in the isometric–hexoctahedral crystal class. Typically massive to columnar in occurrence it also has been found as colorless to variably yellow cubic crystals. The color changes to brown or purple on exposure to light. It is quite soft with a Mohs hardness of 1 to 2 and dense with a specific gravity of 5.55. It is also known as cerargyrite and, when weathered by desert air, as horn silver. Bromian chlorargyrite is also common. Chlorargyrite is water-insoluble.
Ramsdellite (Mn4+O2) is an orthorhombic manganese dioxide mineral. It is relatively uncommon, and is usually found in deposits containing other manganese oxide crystals.
References
- Palache, Charles; Berman, Harry; Frondel, Clifford (1944), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Volume I: Elements, Sulfides, Sulfosalts, Oxides (7th, revised and enlarged ed.), New York: John Wiley and Sons, Inc., pp. 566–567
