Yttrialite-(Y) | |
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General | |
Category | Sorosilicates |
Formula (repeating unit) | Y2Si2O7 |
IMA symbol | Ytt-Y [1] |
Strunz classification | 9.BC.05 |
Crystal system | Monoclinic |
Crystal class | Prismatic (2/m) (same H-M symbol) |
Space group | P21/m |
Identification | |
Color | olive-green, brown to black |
Other characteristics | Radioactive |
References | [2] [3] |
Yttrialite or Yttrialite-(Y) is a rare yttrium thorium sorosilicate mineral with formula: (Y,Th)2 Si 2 O 7. It forms green to orange yellow masses with conchoidal fracture. It crystallizes in the monoclinic-prismatic crystal system. It has a Mohs hardness of 5 to 5.5 and a specific gravity of 4.58. It is highly radioactive due to the thorium content.
It is found associated with gadolinite. It was first described in 1889 for an occurrence in the Rode Ranch pegmatite on Baringer Hill, Llano County, Texas. It has also been reported from the Suishouyama pegmatite on Honshū, Japan, and from occurrences in Norway and Sweden.
Amblygonite is a fluorophosphate mineral, (Li,Na)AlPO4(F,OH), composed of lithium, sodium, aluminium, phosphate, fluoride and hydroxide. The mineral occurs in pegmatite deposits and is easily mistaken for albite and other feldspars. Its density, cleavage and flame test for lithium are diagnostic. Amblygonite forms a series with montebrasite, the low fluorine endmember. Geologic occurrence is in granite pegmatites, high-temperature tin veins, and greisens. Amblygonite occurs with spodumene, apatite, lepidolite, tourmaline, and other lithium-bearing minerals in pegmatite veins. It contains about 10% lithium, and has been utilized as a source of lithium. The chief commercial sources have historically been the deposits of California and France.
Titanite, or sphene (from the Greek sphenos (σφηνώ), meaning wedge), is a calcium titanium nesosilicate mineral, CaTiSiO5. Trace impurities of iron and aluminium are typically present. Also commonly present are rare earth metals including cerium and yttrium; calcium may be partly replaced by thorium.
Pyrochlore2Nb2O6(OH,F) is a mineral group of the niobium end member of the pyrochlore supergroup. The general formula, A2B2O7, represent a family of phases isostructural to the mineral pyrochlore. Pyrochlores are an important class of materials in diverse technological applications such as luminescence, ionic conductivity, nuclear waste immobilization, high temperature thermal barrier coatings, automobile exhaust gas control, catalysts, solid oxide fuel cell, ionic/electrical conductors etc.
Euxenite, or euxenite-(Y), is a brownish black mineral with a metallic luster.
Thorite, (Th,U)SiO4, is a rare nesosilicate of thorium that crystallizes in the tetragonal system and is isomorphous with zircon and hafnon. It is the most common mineral of thorium and is nearly always strongly radioactive. It was named in 1829 to reflect its thorium content. Thorite was discovered in 1828 on the island of Løvøya, Norway, by the vicar and mineralogist, Hans Morten Thrane Esmark, who sent the first specimens of this black mineral to his father, Jens Esmark, who was a professor of mineralogy and geology.
Samarskite is a radioactive rare earth mineral series which includes samarskite-(Y), with the chemical formula (YFe3+Fe2+U,Th,Ca)2(Nb,Ta)2O8 and samarskite-(Yb), with the chemical formula (YbFe3+)2(Nb,Ta)2O8. The formula for samarskite-(Y) is also given as (Y,Fe3+,U)(Nb,Ta)O4.
Xenotime is a rare-earth phosphate mineral, the major component of which is yttrium orthophosphate (YPO4). It forms a solid solution series with chernovite-(Y) (YAsO4) and therefore may contain trace impurities of arsenic, as well as silicon dioxide and calcium. The rare-earth elements dysprosium, erbium, terbium and ytterbium, as well as metal elements such as thorium and uranium (all replacing yttrium) are the expressive secondary components of xenotime. Due to uranium and thorium impurities, some xenotime specimens may be weakly to strongly radioactive. Lithiophyllite, monazite and purpurite are sometimes grouped with xenotime in the informal "anhydrous phosphates" group. Xenotime is used chiefly as a source of yttrium and heavy lanthanide metals (dysprosium, ytterbium, erbium and gadolinium). Occasionally, gemstones are also cut from the finest xenotime crystals.
Arfvedsonite is a sodium amphibole mineral with composition: [Na][Na2][(Fe2+)4Fe3+][(OH)2|Si8O22]. It crystallizes in the monoclinic prismatic crystal system and typically occurs as greenish black to bluish grey fibrous to radiating or stellate prisms.
Triplite is a rare phosphate mineral with formula: (Mn, Fe)2PO4(F, OH). It occurs in phosphate-rich granitic pegmatites typically as irregular brown opaque masses. Triplite was first described in 1813 for an occurrence in Chanteloube, Limousin, France. The name is from the Greek triplos for triple, in reference to the three cleavage directions. In color and appearance, it is very similar to rhodocrosite, another manganese bearing mineral. Chemically, it is also quite similar to triploidite the difference being that triplite is fluorine dominant while triploidite is hydroxide dominant.
Thorianite is a rare thorium oxide mineral, ThO2. It was originally described by Ananda Coomaraswamy in 1904 as uraninite, but recognized as a new species by Wyndham R. Dunstan. It was so named by Dunstan on account of its high percentage of thorium; it also contains the oxides of uranium, lanthanum, cerium, praseodymium and neodymium. Helium is present, and the mineral is slightly less radioactive than pitchblende, but is harder to shield due to its high energy gamma rays. It is common in the alluvial gem-gravels of Sri Lanka, where it occurs mostly as water worn, small, heavy, black, cubic crystals. The largest crystals are usually near 1.5 cm. Larger crystals, up to 6 cm (2.4 in), have been reported from Madagascar.
Fergusonite is a mineral comprising a complex oxide of various rare-earth elements. The general chemical formula of fergusonite is (Y,REE)NbO4, where REE = rare-earth elements in solid solution with Y. Yttrium is usually dominant (the mineral in this case being referred to as fergusonite-(Y)), but sometimes Ce or Nd may be the major rare-earth component (in fergusonite-(Ce) and fergusonite-(Nd), respectively). The other rare-earth elements are present in smaller amounts, and tantalum sometimes substitutes for some of the niobium. There are Fergusonite-beta-(Nd), Fergusonite-beta-(Y), Fergusonite-beta-(Ce) forms too, but they are classified as 4.DG.10 in the Nickel–Strunz system. The mineral has tetragonal crystal symmetry and the same structure as scheelite (calcium tungstate, CaWO4), but can be metamict (amorphous) due to radiation damage from its small content of thorium. It is found as needle-like or prismatic crystals in pegmatite. It was named after British politician and mineral collector Robert Ferguson of Raith (1767–1840).
Microlite was once known as a pale-yellow, reddish-brown, or black isometric mineral composed of sodium calcium tantalum oxide with a small amount of fluorine. Its chemical formula is(Na,Ca)2Ta2O6(O,OH,F). Today it is a name of a group of oxide minerals of a similar stoichiometry having tantalum prevailing over titanium and niobium. The microlite group belongs to a large pyrochlore supergroup that occurs in pegmatites and constitutes an ore of tantalum. It has a Mohs hardness of 5.5 and a variable specific gravity of 4.2 to 6.4. It occurs as disseminated microscopic subtranslucent to opaque octahedral crystals with a refractive index of 2.0 to 2.2. Microlite is also called djalmaite, but both names are now obsolete.
Eucryptite is a lithium bearing aluminium silicate mineral with formula LiAlSiO4. It crystallizes in the trigonal - rhombohedral crystal system. It typically occurs as granular to massive in form and may pseudomorphically replace spodumene. It has a brittle to conchoidal fracture and indistinct cleavage. It is transparent to translucent and varies from colorless to white to brown. It has a Mohs hardness of 6.5 and a specific gravity of 2.67. Optically it is uniaxial positive with refractive index values of nω = 1.570 - 1.573 and nε = 1.583 - 1.587.
Thomasclarkite-(Y) is a rare mineral which was known as UK-93 until 1997, when it was renamed in honour of Thomas H. Clark (1893–1996), McGill University professor. The mineral is one of many rare-earth element minerals from Mont Saint-Hilaire. The only reported occurrence is in an alkalic pegmatite dike in an intrusive gabbro-nepheline syenite.
Scorzalite ((Fe2+,Mg)Al2(OH,PO4)2) is a dark blue phosphate mineral containing iron, magnesium, and aluminium phosphate. Scorzalite forms one endmember of a solid solution series with the lighter, more magnesium-rich lazulite.
Betafite is a mineral group in the pyrochlore supergroup, with the chemical formula (Ca,U)2(Ti,Nb,Ta)2O6(OH). Betafite typically occurs as a primary mineral in granite pegmatites, rarely in carbonatites. Originally defined by the B-site atom Ti, the development of new nomenclature for mineral names led to modernization of the system for nomenclature of pyrochlore and betafite in order to further rationalize the naming process of this grouping of minerals. Only two of the mineral species that were formerly recognized as betafite are presently retained. They are oxyuranobetafite and oxycalciobetafite. The term betafite is now a synonym or varietal group name under the pyrochlore super group.
Huttonite is a thorium nesosilicate mineral with the chemical formula ThSiO4 and which crystallizes in the monoclinic system. It is dimorphous with tetragonal thorite, and isostructual with monazite. An uncommon mineral, huttonite forms transparent or translucent cream–colored crystals. It was first identified in samples of beach sands from the West Coast region of New Zealand by the mineralogist Colin Osborne Hutton (1910–1971). Owing to its rarity, huttonite is not an industrially useful mineral.
Althupite (IMA symbol: Ahp) is a rare aluminium thorium uranyl phosphate mineral with complex formula written as AlTh(UO2)7(PO4)4O2(OH)5·15H2O, from a granitic pegmatite. It is named after its composition (ALuminium, THorium, Uranium, and Phosphorus).
Brockite is a rare earth phosphate mineral with formula: (Ca,Th,Ce)PO4·H2O. It crystallizes in the hexagonal system in the chiral space group 180 or its enantiomorph 181. It is typically granular to massive with only rare occurrence of stubby crystals. It is radioactive due to the thorium content.
Grayite, ThPO4·(H2O), is a thorium phosphate mineral of the Rabdophane group first discovered in 1957 by S.H.U. Bowie in Rhodesia. It is of moderate hardness occurring occasionally in aggregates of hexagonal crystals occasionally but more commonly in microgranular/cryptocrystalline masses. Due to its thorium content, grayite displays some radioactivity although it is only moderate and the mineral displays powder XRD peaks without any metamict-like effects. The color of grayite is most commonly observed as a light to dark reddish brown but has also been observed as lighter yellows with grayish tints. It has a low to moderate hardness with a Mohs hardness of 3–4 and has a specific gravity of 3.7–4.3. It has been found in both intrusive igneous and sedimentary environments.