Zinc-aluminium (ZA) alloys are alloys whose main constituents are zinc and aluminium. Other alloying elements include magnesium and copper. This type of alloy was originally developed for gravity casting. Noranda, New Jersey Zinc Co. Ltd., St. Joe Mineral Co. and the International Lead Zinc Research Organization (ILZRO) were the main companies that pioneered the ZA alloys between the 1950s and the 1970s. They were designed to compete with bronze, cast iron and aluminium using sand and permanent mold casting methods. Distinguishing features of ZA alloys include high as-cast strength, excellent bearing properties, as well as low energy requirements (for melting). [1]
ZA alloys make good bearings because their final composition includes hard eutectic zinc-aluminium-copper particles embedded in a softer zinc-aluminium matrix. The hard particles provide a low-friction bearing surface, while the softer material wears back to provide space for lubricant to flow, similar to Babbitt metal.[ citation needed ]
The numbers associated with the name represent the amount of aluminium in the alloy (i.e. ZA8 has 8% aluminium). [1]
ZA8 | ZA12 | ZA27 | ||||
---|---|---|---|---|---|---|
Mechanical properties | Sand cast | Permanent mold | Sand cast | Permanent mold | Sand cast | Permanent mold |
Ultimate tensile strength [ksi (MPa)] | 38 (263) | 32-37 (221-255) | 40-46 (276-317) | 45-50 (310-345) | 58-64 (400-441) | 45-47 (310-324) |
Yield strength - 0.2% offset [ksi (MPa)] | 29 (200) | 30 (206) | 31 (214) | 39 (269) | 54 (372) | 37 (255) |
Elongation [% in 2"] | 1-2 | 1-2 | 1-3 | 1-3 | 3-6 | 8-11 |
Shear strength [ksi (MPa)] | - | 35 (241) | 37 (255) | - | 42 (290) | 33 (228) |
Hardness [Brinell] | 85 | 85-90 | 89-105 | 89-105 | 110-120 | 90-110 |
Impact strength [ft·lbf (J)] | 156 (20) | - | 193 (25) | - | 353 (47) | 433 (58) |
Fatigue strength rotary bend in 5x108 cycles [ksi (MPa)] | - | 7.5 (52) | 15 (103) | - | 25 (172) | 15 (103) |
Compressive yield strength 0.1% offset [ksi (MPa)] | 29 (199) | 31 (214) | 33 (227) | 34 (234) | 48 (331) | 37 (255) |
Modulus of elasticity [psi x 106 (GPa)] | 12.4 (85.5) | 12.47 (85.5) | 12.07 (82.7) | 12.07 (82.7) | 11.37 (77.9) | 11.37 (77.9) |
Poisson's ratio | 0.29 | 0.29 | 0.30 | 0.30 | 0.32 | 0.32 |
Physical properties | Sand cast | Permanent mold | Sand cast | Permanent mold | Sand cast | Permanent mold |
Density [lb/in3 (g/cm3)] | .227 (6.3) | 0.227 (6.3) | 0.218 (6.0) | 0.218 (6.0) | 0.181 (5.0) | 0.181 (5.0) |
Melting Range | 375-404°C (707-759°F) | 375-404°C (707-759°F) | 377-432°C (710-810°F) | 377-432°C (710-810°F) | 376-484°C (708-903°F) | 376-484°C (708-903°F) |
Electrical Conductivity [S/m (%IACS)] | 1.61 (27.7) | 1.61 (27.7) | 1.64 (28.3) | 1.64 (28.3) | 1.72 (29.7) | 1.72 (29.7) |
Thermal Conductivity [BTU/hr/ft2/°R (W/m/K)] | 66.3 (114.7) | 66.3 (114.7) | 67.1 (116.1) | 67.1 (116.1) | 72.5 (125.5) | 72.5 (125.5) |
CTE [68-212°F μin/in/°R (100-200°C μm/m/K)] | 12.9 (23.3) | 12.9 (23.3) | 13.4 (24.2) | 13.4 (24.2) | 14.4 (26.0) | 14.4 (26.0) |
Specific Heat [BTU/lb/°R (J/kg/K)] | .104 (435) | .104 (435) | .107 (448) | .107 (448) | .125 (523) | .125 (523) |
Pattern of Die Shrinkage [in/ft (mm/m)] | 1/8 (10.4) | 1/8 (10.4) | 5/32 (13.0) | 5/32 (13.0) | 5/32 (13.0) | 5/32 (13.0) |
ZA8 | ZA12 | ZA27 | ||||
---|---|---|---|---|---|---|
Composition | Ingot | Casting | Ingot | Casting | Ingot | Casting |
Al | 8.2-8.8 | 8.0-8.8 | 10.8-11.5 | 10.5-11.5 | 25.5-28.0 | 25.0-28.0 |
Mg | .020-.030 | .015-.030 | .020-.030 | .015-.030 | .012-.020 | .010-.020 |
Cu | 0.8-1.3 | 0.8-1.3 | 0.5-1.2 | 0.5-1.2 | 2.0-2.5 | 2.0-2.5 |
Fe (max) | .065 | .075 | .065 | .075 | .072 | .075 |
Pb (max) | .005 | .006 | .005 | .006 | .005 | .006 |
Cd | .005 | .006 | .005 | .006 | .005 | .006 |
Sn (max) | .002 | .003 | .002 | .003 | .002 | .003 |
Ni (other)x10 | - | - | - | - | - | - |
Zn | Bal | Bal | Bal | Bal | Bal | Bal |
Color Code ASTM B908 | Blue | Blue | Orange | Orange | Purple | Purple |
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Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the science and the technology of metals; that is, the way in which science is applied to the production of metals, and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy is distinct from the craft of metalworking. Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist.
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Die casting is a metal casting process that is characterized by forcing molten metal under high pressure into a mold cavity. The mold cavity is created using two hardened tool steel dies which have been machined into shape and work similarly to an injection mold during the process. Most die castings are made from non-ferrous metals, specifically zinc, copper, aluminium, magnesium, lead, pewter, and tin-based alloys. Depending on the type of metal being cast, a hot- or cold-chamber machine is used.
ZAMAK is a family of alloys with a base metal of zinc and alloying elements of aluminium, magnesium, and copper.
Spin casting, also known as centrifugal rubber mold casting (CRMC), is a method of utilizing inertia to produce castings from a rubber mold. Typically, a disc-shaped mold is spun along its central axis at a set speed. The casting material, usually molten metal or liquid thermoset plastic, is then poured in through an opening at the top-center of the mold. The filled mold then continues to spin as the metal solidifies.
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Continuous casting, also called strand casting, is the process whereby molten metal is solidified into a "semifinished" billet, bloom, or slab for subsequent rolling in the finishing mills. Prior to the introduction of continuous casting in the 1950s, steel was poured into stationary molds to form ingots. Since then, "continuous casting" has evolved to achieve improved yield, quality, productivity and cost efficiency. It allows lower-cost production of metal sections with better quality, due to the inherently lower costs of continuous, standardised production of a product, as well as providing increased control over the process through automation. This process is used most frequently to cast steel. Aluminium and copper are also continuously cast.
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Metals used for architectural purposes include lead, for water pipes, roofing, and windows; tin, formed into tinplate; zinc, copper and aluminium, in a range of applications including roofing and decoration; and iron, which has structural and other uses in the form of cast iron or wrought iron, or made into steel. Metal alloys used in building include bronze ; brass ; monel metal and nickel silver, mainly consisting of nickel and copper; and stainless steel, with important components of nickel and chromium.
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