Absolute (perfumery)

Last updated
Jasmine (Jasminum officinale) absolute JasmineAbsolute.png
Jasmine ( Jasminum officinale ) absolute

Used in perfumery and aromatherapy, absolutes are similar to essential oils. They are concentrated, highly aromatic, oily mixtures extracted from plants. Whereas essential oils are produced by distillation, boiling or pressing, absolutes are produced through solvent extraction, or more traditionally, through enfleurage.

Contents

Production

First, plant material is extracted with a hydrocarbon solvent, such as hexane, to yield a concrete. The concrete is then extracted with ethanol. The ethanol extract is cooled (e.g., to −15 °C) to solidify waxes, and cold filtered to yield a liquid extract. When the ethanol evaporates, an oil—the absolute—is left behind. [1]

Traditionally, the absolute was obtained by enfleurage, where the resulting pommade was extracted with ethanol to yield the absolute.

Character and use

Some raw materials are either too delicate or too inert to be steam-distilled and can only yield their aroma through solvent extraction. Examples of these are jasmine and beeswax. Absolutes in demand include rose, jasmine, tuberose, jonquil, ylang-ylang, mimosa, boronia, lavender, lavandin, geranium, clary sage, violet, oakmoss, tonka bean.

Rose oil, [2] jasmine absolute, tuberose absolute, tobacco absolute, [3] orris root oil, ambrette seeds oil, angelica root oil, and orange flower oil are valuable and expensive fragrance and flavor ingredients. [4]

Residual solvents may remain in the absolutes. Therefore, some absolutes are considered undesirable for aromatherapy.[ citation needed ]

See also

Related Research Articles

Perfume is a mixture of fragrant essential oils or aroma compounds (fragrances), fixatives and solvents, usually in liquid form, used to give the human body, animals, food, objects, and living-spaces an agreeable scent. Perfumes can be defined as substances that emit and diffuse a pleasant and fragrant odor. They consist of manmade mixtures of aromatic chemicals and essential oils. The 1939 Nobel Laureate for Chemistry, Leopold Ružička stated in 1945 that "right from the earliest days of scientific chemistry up to the present time, perfumes have substantially contributed to the development of organic chemistry as regards methods, systematic classification, and theory."

<span class="mw-page-title-main">Sandalwood</span> Class of woods from trees in the genus Santalum

Sandalwood is a class of woods from trees in the genus Santalum. The woods are heavy, yellow, and fine-grained, and, unlike many other aromatic woods, they retain their fragrance for decades. Sandalwood oil is extracted from the woods. Sandalwood is often cited as one of the most expensive woods in the world. Both the wood and the oil produce a distinctive fragrance that has been highly valued for centuries. Consequently, some species of these slow-growing trees have suffered over-harvesting in the past.

<span class="mw-page-title-main">Essential oil</span> Hydrophobic liquid containing volatile aroma compounds from plants

An essential oil is a concentrated hydrophobic liquid containing volatile chemical compounds from plants. Essential oils are also known as volatile oils, ethereal oils, aetheroleum, or simply as the oil of the plant from which they were extracted, such as oil of clove. An essential oil is essential in the sense that it contains the essence of the plant's fragrance—the characteristic fragrance of the plant from which it is derived. The term "essential" used here does not mean indispensable or usable by the human body, as with the terms essential amino acid or essential fatty acid, which are so called because they are nutritionally required by a living organism.

<i>Cananga odorata</i> Species of tree

Cananga odorata, known as ylang-ylang or cananga tree, is a tropical tree that is native to and originated in the Philippines and spread to Malaysia, Indonesia, New Guinea, the Solomon Islands, and Queensland, Australia. It is also native to parts of Cambodia, Thailand, India and Vietnam. It is valued for the essential oils extracted from its flowers, which has a strong floral fragrance. Ylang-ylang is one of the most extensively used natural materials in the perfume industry, earning it the name "Queen of Perfumes".

Enfleurage is a process that uses odorless fats that are solid at room temperature to capture the fragrant compounds exuded by plants. The process can be "cold" enfleurage or "hot" enfleurage.

Fragrance oils, also known as aroma oils, aromatic oils, and flavor oils, are blended synthetic aroma compounds or natural essential oils that are diluted with a carrier like propylene glycol, vegetable oil, or mineral oil.

<span class="mw-page-title-main">Rose oil</span> Essential oil extracted from rose petals

Rose oil is the essential oil extracted from the petals of various types of rose. Rose ottos are extracted through steam distillation, while rose absolutes are obtained through solvent extraction, the absolute being used more commonly in perfumery. The production technique originated in Greater Iran. Even with their high price and the advent of organic synthesis, rose oils are still perhaps the most widely used essential oil in perfumery.

<span class="mw-page-title-main">Neroli</span> Essential oil of the bitter orange blossom

Neroli oil is an essential oil produced from the blossom of the bitter orange tree. Its scent is sweet, honeyed and somewhat metallic with green and spicy facets. Orange blossom is also extracted from the same blossom and both extracts are extensively used in perfumery. Orange blossom can be described as smelling sweeter, warmer and more floral than neroli. The difference between how neroli and orange blossom smell and why they are referred to with different names, is a result of the process of extraction that is used to obtain the oil from the blooms. Neroli is extracted by steam distillation and orange blossom is extracted via a process of enfleurage or solvent extraction.

Aromachology is the study of the influence of odors on human behavior and to examine the relationship between feelings and emotions. Those who practice aromachology are aromachologists. Aromachologists analyze emotions such as relaxation, exhilaration, sensuality, happiness and well-being brought about by odors stimulating the olfactory pathways in the brain and, in particular, the limbic system. Different wearers are thought to have unique physiological and psychological responses to scents, especially those not manufactured synthetically but based on real scents. The word "aromachology" is derived from "aroma" and "physio-psychology", the latter being the study of aroma. This term was coined in 1989 by what is now the Sense of Smell Institute (SSI), a division of The Fragrance Foundation. The SSI defines aromachology as "a concept based on systematic, scientific data collected under controlled conditions". The term is defined as the scientifically observable influence of smell on emotions and moods. Consumers use aromachology to alleviate time pressures, for relaxation or stimulation and as a component of other activities that generate a feeling of well-being.

<span class="mw-page-title-main">Extract</span> Category of substance

An extract (essence) is a substance made by extracting a part of a raw material, often by using a solvent such as ethanol, oil or water. Extracts may be sold as tinctures, absolutes or in powder form.

<span class="mw-page-title-main">Fragrance extraction</span> Separation process of aromatic compounds from raw materials

Fragrance extraction refers to the separation process of aromatic compounds from raw materials, using methods such as distillation, solvent extraction, expression, sieving, or enfleurage. The results of the extracts are either essential oils, absolutes, concretes, or butters, depending on the amount of waxes in the extracted product.

<span class="mw-page-title-main">Types of plant oils</span>

Plant oils or vegetable oils are oils derived from plant sources, as opposed to animal fats or petroleum. There are three primary types of plant oil, differing both the means of extracting the relevant parts of the plant, and in the nature of the resulting oil:

  1. Vegetable fats and oils were historically extracted by putting part of the plant under pressure, squeezing out the oil.
  2. Macerated oils consist of a base oil to which parts of plants are added.
  3. Essential oils are composed of volatile aromatic compounds, extracted from plants by distillation.
<span class="mw-page-title-main">Methyl anthranilate</span> Chemical compound

Methyl anthranilate, also known as MA, methyl 2-aminobenzoate, or carbomethoxyaniline, is an ester of anthranilic acid. Its chemical formula is C8H9NO2. It has a strong and fruity grape smell, and one of its key uses is as a flavoring agent.

<span class="mw-page-title-main">Eau de toilette</span> Lightly scented perfume

Eau de toilette is a lightly scented perfume. It is also referred to as aromatic waters and has a high alcohol content. It is usually applied directly to the skin after bathing or shaving. It is traditionally composed of alcohol and various volatile oils. Traditionally these products were named after a principal ingredient; some being geranium water, lavender water, lilac water, violet water, spirit of myrcia and 'eau de Bretfeld'. Because of this, eau de toilette was sometimes referred to as "toilet water".

<span class="mw-page-title-main">Jasmine in Karnataka</span>

Jasmine is considered the queen of flowers and is called the "Belle of India" or the "Queen of fragrance" as it is exquisitely scented to soothe and refresh. In different parts of India it is called by different names—Mogra, Motia, Chameli, Malli puvvu, Jaati, Mulla, Mallige, Juhi, Mogra or Moonlight in the grove. It is reported that there are 300 varieties of jasmine. It is also stated that jasmine crossed the seas—from Asia to Europe, landing first along the Mediterranean Sea, conquering Greece and Turkey, reaching Western Europe through Spain, then France and Italy and finally landing in England in the latter part of the 17th century..

<i>Salvia stenophylla</i> Species of shrub

Salvia stenophylla is a perennial shrub native to a wide area of Southern Africa: South Africa, Botswana and Namibia. It grows on grassy or stony slopes, and in open countryside or among shrubs. It has been used traditionally as a disinfectant by burning it in huts after sickness, and it is also mixed with tobacco for smoking. Its specific epithet, stenophylla, refers to the narrow leaves.

Concrete, in perfumery, is a waxy mass obtained by solvent extraction of fresh plant material. It is usually used for the production of absolutes.

Resinoids are extracts of resinous plant exudates.

Beard oil is a cosmetic product that is used to nourish both the skin under the beard and the beard itself in order to keep it "soft, shiny, and smooth". Beard oil mimics the natural oils produced by skin, such as sebum, and is composed mainly of carrier oils and essential oils.

References

  1. K. Hüsnü Can Başer; et al. (2013), "Essential Oils", in Arza Seidel; et al. (eds.), Kirk-Othmer Chemical Technology of Cosmetics, ISBN   978-1-118-40692-2
  2. Nedeltcheva-Antonova D, Medarska Y, Stoyanova A, Nenov N, Slavov A, Antonov L (2021). "Chemical profile and sensory evaluation of Bulgarian rose (Rosa damascena Mill.) aroma products, isolated by different techniques". Journal of Essential Oil Research. 33 (2): 171–181. doi:10.1080/10412905.2020.1839583. S2CID   230534578.
  3. Nedeltcheva-Antonova D, Ivanova D, Antonov L, Abe I (2016). "Insight into the aroma profile of Bulgarian tobacco absolute oil". Industrial Crops and Products. 94: 226–232. doi:10.1016/j.indcrop.2016.08.047.
  4. Karl-Georg Fahlbusch; et al. (2007), "Flavors and Fragrances", Ullmann's Encyclopedia of Industrial Chemistry (7th ed.), Wiley, p. 83