Chemical metallurgy

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Chemical metallurgy is the science of obtaining metals from their concentrates, semi products, recycled bodies and solutions, and of considering reactions of metals with an approach of disciplines belonging to chemistry. As such, it involves reactivity of metals and it is especially concerned with the reduction and oxidation, and the chemical performance of metals.

Subjects of study in chemical metallurgy include the extraction of metals, thermodynamics, electrochemistry, and chemical degradation (corrosion). [1]

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<span class="mw-page-title-main">Metallurgy</span> Field of science that studies the physical and chemical behavior of metals

Metallurgy is a domain of materials science and engineering that studies the physical and chemical behavior of metallic elements, their inter-metallic compounds, and their mixtures, which are known as alloys. Metallurgy encompasses both the science and the technology of metals; that is, the way in which science is applied to the production of metals, and the engineering of metal components used in products for both consumers and manufacturers. Metallurgy is distinct from the craft of metalworking. Metalworking relies on metallurgy in a similar manner to how medicine relies on medical science for technical advancement. A specialist practitioner of metallurgy is known as a metallurgist.

Extractive metallurgy is a branch of metallurgical engineering wherein process and methods of extraction of metals from their natural mineral deposits are studied. The field is a materials science, covering all aspects of the types of ore, washing, concentration, separation, chemical processes and extraction of pure metal and their alloying to suit various applications, sometimes for direct use as a finished product, but more often in a form that requires further working to achieve the given properties to suit the applications.

<span class="mw-page-title-main">Crucible</span> Container in which substances are heated

A crucible is a ceramic or metal container in which metals or other substances may be melted or subjected to very high temperatures. While crucibles were historically usually made from clay, they can be made from any material that withstands temperatures high enough to melt or otherwise alter its contents.

<span class="mw-page-title-main">Cyril Stanley Smith</span> British metallurgist

Cyril Stanley Smith was a British metallurgist and historian of science. He is most famous for his work on the Manhattan Project where he was responsible for the production of fissionable metals. A graduate of the University of Birmingham and Massachusetts Institute of Technology (MIT), Smith worked for many years as a research metallurgist at the American Brass Company. During World War II he worked in the Chemical-Metallurgical Division of the Los Alamos Laboratory, where he purified, cast and shaped uranium-235 and plutonium, a metal hitherto available only in microgram amounts, and whose properties were largely unknown. After the war he served on the Atomic Energy Commission's influential General Advisory Committee, and the President's Science Advisory Committee.

<span class="mw-page-title-main">Powder metallurgy</span> Process of sintering metal powders

Powder metallurgy (PM) is a term covering a wide range of ways in which materials or components are made from metal powders. PM processes can reduce or eliminate the need for subtractive processes in manufacturing, lowering material losses and reducing the cost of the final product.

Refractory metals are a class of metals that are extraordinarily resistant to heat and wear. The expression is mostly used in the context of materials science, metallurgy and engineering. The definition of which elements belong to this group differs. The most common definition includes five elements: two of the fifth period and three of the sixth period. They all share some properties, including a melting point above 2000 °C and high hardness at room temperature. They are chemically inert and have a relatively high density. Their high melting points make powder metallurgy the method of choice for fabricating components from these metals. Some of their applications include tools to work metals at high temperatures, wire filaments, casting molds, and chemical reaction vessels in corrosive environments. Partly due to the high melting point, refractory metals are stable against creep deformation to very high temperatures.

<span class="mw-page-title-main">Copper extraction</span> Process of extracting copper from the ground

Copper extraction refers to the methods used to obtain copper from its ores. The conversion of copper ores consists of a series of physical, chemical and electrochemical processes. Methods have evolved and vary with country depending on the ore source, local environmental regulations, and other factors.

<span class="mw-page-title-main">Cupellation</span> Refining process in metallurgy

Cupellation is a refining process in metallurgy where ores or alloyed metals are treated under very high temperatures and have controlled operations to separate noble metals, like gold and silver, from base metals, like lead, copper, zinc, arsenic, antimony, or bismuth, present in the ore. The process is based on the principle that precious metals do not oxidise or react chemically, unlike base metals. When they are heated at high temperatures, the precious metals remain apart, and the others react, forming slags or other compounds.

Hydrometallurgy is a technique within the field of extractive metallurgy, the obtaining of metals from their ores. Hydrometallurgy involve the use of aqueous solutions for the recovery of metals from ores, concentrates, and recycled or residual materials. Processing techniques that complement hydrometallurgy are pyrometallurgy, vapour metallurgy, and molten salt electrometallurgy. Hydrometallurgy is typically divided into three general areas:

Pyrometallurgy is a branch of extractive metallurgy. It consists of the thermal treatment of minerals and metallurgical ores and concentrates to bring about physical and chemical transformations in the materials to enable recovery of valuable metals. Pyrometallurgical treatment may produce products able to be sold such as pure metals, or intermediate compounds or alloys, suitable as feed for further processing. Examples of elements extracted by pyrometallurgical processes include the oxides of less reactive elements like iron, copper, zinc, chromium, tin, and manganese.

Archaeometallurgy is the study of the past use and production of metals by humans. It is a sub-discipline of archaeology and archaeological science.

In metallurgy, refining consists of purifying an impure metal. It is to be distinguished from other processes such as smelting and calcining in that those two involve a chemical change to the raw material, whereas in refining, the final material is usually identical chemically to the original one, only it is purer. The processes used are of many types, including pyrometallurgical and hydrometallurgical techniques.

<span class="mw-page-title-main">Metals of antiquity</span> Metals known in antiquity

The metals of antiquity are the seven metals which humans had identified and found use for in prehistoric times in Europe and the Middle East: gold, silver, copper, tin, lead, iron, and mercury. These seven are the metals from which the modern world was forged; until the discovery of antimony in the 9th century, and arsenic in the 13th, these were the only known elemental metals, compared to approximately 90 known today.

Leaching is a process widely used in extractive metallurgy where ore is treated with chemicals to convert the valuable metals within into soluble salts while the impurity remains insoluble. These can then be washed out and processed to give the pure metal; the materials left over are commonly known as tailings. Compared to pyrometallurgy, leaching is easier to perform, requires less energy and is potentially less harmful as no gaseous pollution occurs. Drawbacks of leaching include its lower efficiency and the often significant quantities of waste effluent and tailings produced, which are usually either highly acidic or alkali as well as toxic.

Anatoly Ivanovich Belyaev (1906–1967) founded the school of metallurgy of light non-ferrous metals and semi-conducting materials. He was Professor of Moscow Institute of Steel and Alloys. He was head of the department of metallurgy of light metals in the Moscow Institute of Non-ferrous Metals and Gold from 1943 to 1963. From 1962 to 1967 he was organizer and head of the chair for producing pure metals and semi-conducting materials in MISIS.

Ore concentrate, dressed ore or simply concentrate is the product generally produced by metal ore mines. The raw ore is usually ground finely in various comminution operations and gangue (waste) is removed, thus concentrating the metal component. The concentrate is then transported to various physical or chemical processes called hydrometallurgy, pyrometallurgy smelters, and electrometallurgy where it is used to produce useful metals.

Physical metallurgy is one of the two main branches of the scientific approach to metallurgy, which considers in a systematic way the physical properties of metals and alloys. It is basically the fundamentals and applications of the theory of phase transformations in metal and alloys, as the title of classic, challenging monograph on the subject with this title. While chemical metallurgy involves the domain of reduction/oxidation of metals, physical metallurgy deals mainly with mechanical and magnetic/electric/thermal properties of metals – treated by the discipline of solid state physics. Calphad methodology, able to produce Phase diagrams which is the basis for evaluating or estimating physical properties of metals, relies on Computational thermodynamics i.e. on Chemical thermodynamics and could be considered a common and useful field for both the two sub-disciplines.

Sieverts' law, in physical metallurgy and in chemistry, is a rule to predict the solubility of gases in metals. It is named after German chemist Adolf Sieverts (1874–1947). The law states that the solubility of a diatomic gas in metal is proportional to the square root of the partial pressure of the gas in thermodynamic equilibrium. Hydrogen, oxygen and nitrogen are examples of dissolved diatomic gases of frequent interest in metallurgy.

<span class="mw-page-title-main">University of the Witwatersrand School of Chemical and Metallurgical Engineering</span>

The School of Chemical and Metallurgical Engineering is one of seven schools in the University of the Witwatersrand's Faculty of Engineering and the Built Environment. The School offers 4-year undergraduate degrees and post-graduate degrees in chemical and metallurgical engineering.

The Ames Project was a research and development project that was part of the larger Manhattan Project to build the first atomic bombs during World War II. It was founded by Frank Spedding from Iowa State College in Ames, Iowa as an offshoot of the Metallurgical Laboratory at the University of Chicago devoted to chemistry and metallurgy, but became a separate project in its own right. The Ames Project developed the Ames Process, a method for preparing pure uranium metal that the Manhattan Project needed for its atomic bombs and nuclear reactors. Between 1942 and 1945, it produced over 1,000 short tons (910 t) of uranium metal. It also developed methods of preparing and casting thorium, cerium and beryllium. In October 1945 Iowa State College received the Army-Navy "E" Award for Excellence in Production, an award usually only given to industrial organizations. In 1947 it became the Ames Laboratory, a national laboratory under the Atomic Energy Commission.

References

  1. Moore, John Jeremy; Boyce, E. A. (1990). Chemical Metallurgy. doi:10.1016/c2013-0-00969-3. ISBN   9780408053693.

See also