Clinozoisite

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Clinozoisite
Clinozoisite, Amphibole Group - Mount Belvidere Quarries, Vermont, USA.jpg
Clinozoisite
General
Category Sorosilicates
Epidote group
Formula
(repeating unit)
Ca2Al3(Si2O7)(SiO4)O(OH)
IMA symbol Czo [1]
Strunz classification 9.BG.05a
Dana classification58.2.1a.4
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P21/m
Unit cell a = 8.879, b = 5.583
c = 10.155 [Å]; β = 115.50°; Z = 2
Identification
ColorColorless, green, gray, light green, yellow green, pink
Crystal habit Elongated primatic crystals, striated; granular to fibrous
Twinning Lamellar on {100} uncommon
Cleavage Perfect on {001}
Fracture Irregular/uneven
Tenacity Brittle
Mohs scale hardness6–7
Luster Vitreous
Streak Grayish white
Diaphaneity Transparent to translucent
Specific gravity 3.3–3.4
Optical propertiesBiaxial (+)
Refractive index nα = 1.706 – 1.724 nβ = 1.708 – 1.729 nγ = 1.712 – 1.735
Birefringence δ = 0.006 – 0.011
2V angle 14 to 90° measured
References [2] [3] [4]

Clinozoisite is a complex calcium aluminium sorosilicate mineral with formula: Ca2Al3(Si2O7)(SiO4)O(OH). It forms a continuous solid solution series with epidote by substitution of iron(III) in the aluminium (m3 site) and is also called aluminium epidote. [2]

Clinothulite is a manganese bearing variety with a pinkish hue due to substitution of Mn(III) in the aluminium site. [5]

It was originally discovered in 1896 in East Tyrol, Austria, and is so-named because of its resemblance to zoisite and its monoclinic crystal structure. [2]

It occurs in rocks which have undergone low to medium grade regional metamorphism and in contact metamorphism of high calcium sedimentary rocks. It also occurs in saussurite alteration of plagioclase. [3]

Jadeite bearing pyroxene minerals have suggested clinozoisite and paragonite are associated and derived from lawsonite releasing quartz and water via the following reaction: [6]

Related Research Articles

<span class="mw-page-title-main">Hornblende</span> Complex inosilicate series of minerals

Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.

<span class="mw-page-title-main">Amphibole</span> Group of inosilicate minerals

Amphibole is a group of inosilicate minerals, forming prism or needlelike crystals, composed of double chain SiO
4
tetrahedra, linked at the vertices and generally containing ions of iron and/or magnesium in their structures. Its IMA symbol is Amp. Amphiboles can be green, black, colorless, white, yellow, blue, or brown. The International Mineralogical Association currently classifies amphiboles as a mineral supergroup, within which are two groups and several subgroups.

<span class="mw-page-title-main">Pyroxene</span> Group of inosilicate minerals with single chains of silica tetrahedra

The pyroxenes are a group of important rock-forming inosilicate minerals found in many igneous and metamorphic rocks. Pyroxenes have the general formula XY(Si,Al)2O6, where X represents calcium (Ca), sodium (Na), iron or magnesium (Mg) and more rarely zinc, manganese or lithium, and Y represents ions of smaller size, such as chromium (Cr), aluminium (Al), magnesium (Mg), cobalt (Co), manganese (Mn), scandium (Sc), titanium (Ti), vanadium (V) or even iron. Although aluminium substitutes extensively for silicon in silicates such as feldspars and amphiboles, the substitution occurs only to a limited extent in most pyroxenes. They share a common structure consisting of single chains of silica tetrahedra. Pyroxenes that crystallize in the monoclinic system are known as clinopyroxenes and those that crystallize in the orthorhombic system are known as orthopyroxenes.

<span class="mw-page-title-main">Lepidolite</span> Light micas with substantial lithium

Lepidolite is a lilac-gray or rose-colored member of the mica group of minerals with chemical formula K(Li,Al)3(Al,Si,Rb)4O10(F,OH)2. It is the most abundant lithium-bearing mineral and is a secondary source of this metal. It is the major source of the alkali metal rubidium.

<span class="mw-page-title-main">Zoisite</span> Sorosilicate mineral

Zoisite, first known as saualpite, after its type locality, is a calcium aluminum hydroxy sorosilicate belonging to the epidote group of minerals. Its chemical formula is Ca2Al3(SiO4)(Si2O7)O(OH).

<span class="mw-page-title-main">Epidote</span> Sorosilicate mineral

Epidote is a calcium aluminium iron sorosilicate mineral.

<span class="mw-page-title-main">Silicate mineral</span> Rock-forming minerals with predominantly silicate anions

Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.

<span class="mw-page-title-main">Chlorite group</span> Type of mineral

The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

<span class="mw-page-title-main">Cummingtonite</span> Silicate mineral

Cummingtonite is a metamorphic amphibole with the chemical composition (Mg,Fe2+
)
2
(Mg,Fe2+
)
5
Si
8
O
22
(OH)
2
, magnesium iron silicate hydroxide.

<span class="mw-page-title-main">Illite</span> Group of related non-expanding clay minerals

Illite, also called hydromica or hydromuscovite, is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina octahedron (O) – silica tetrahedron (T) layers. The space between this T-O-T sequence of layers is occupied by poorly hydrated potassium cations which are responsible for the absence of swelling. Structurally, illite is quite similar to muscovite with slightly more silicon, magnesium, iron, and water and slightly less tetrahedral aluminium and interlayer potassium. The chemical formula is given as (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2·(H2O)], but there is considerable ion (isomorphic) substitution. It occurs as aggregates of small monoclinic grey to white crystals. Due to the small size, positive identification usually requires x-ray diffraction or SEM-EDS analysis. Illite occurs as an altered product of muscovite and feldspar in weathering and hydrothermal environments; it may be a component of sericite. It is common in sediments, soils, and argillaceous sedimentary rocks as well as in some low grade metamorphic rocks. The iron-rich member of the illite group, glauconite, in sediments can be differentiated by x-ray analysis.

<span class="mw-page-title-main">Paragonite</span>

Paragonite is a mineral, related to muscovite. Its empirical formula is NaAl2(AlSi3O10)(OH)2. A wide solvus separates muscovite from paragonite, such that there is little solid solution along the vector Na+K+ and apparent micas of intermediate composition is most commonly a microscopic (or even sub-microscopic) intergrowth of two distinct micas, one rich in K, and the other in Na. Paragonite is a common mineral in rocks metamorphosed under blueschist facies conditions along with other sodic minerals such as albite, jadeite and glaucophane. During the transition from blueschist to greenschist facies, paragonite and glaucophane are transformed into chlorite and albite. Jadeite bearing pyroxene minerals have suggested clinozoisite and paragonite are associated and derived from lawsonite releasing quartz and water via the following reaction:

<span class="mw-page-title-main">Afwillite</span> Nesosilicate alteration mineral also sometimes found in hydrated cement paste

Afwillite is a calcium hydroxide nesosilicate mineral with formula Ca3(SiO3OH)2·2H2O. It occurs as glassy, colorless to white prismatic monoclinic crystals. Its Mohs scale hardness is between 3 and 4. It occurs as an alteration mineral in contact metamorphism of limestone. It occurs in association with apophyllite, natrolite, thaumasite, merwinite, spurrite, gehlenite, ettringite, portlandite, hillebrandite, foshagite, brucite and calcite.

<span class="mw-page-title-main">Melilite</span> Sorosilicate mineral

Melilite refers to a mineral of the melilite group. Minerals of the group are solid solutions of several endmembers, the most important of which are gehlenite and åkermanite. A generalized formula for common melilite is (Ca,Na)2(Al,Mg,Fe2+)[(Al,Si)SiO7]. Discovered in 1793 near Rome, it has a yellowish, greenish-brown color. The name derives from the Greek words meli (μέλι) "honey" and lithos (λίθους) "stone".The name refers to a group of minerals (melilite group) with chemically similar composition, nearly always minerals in åkermanite-gehlenite series.

<span class="mw-page-title-main">Lawsonite</span>

Lawsonite is a hydrous calcium aluminium sorosilicate mineral with formula CaAl2Si2O7(OH)2·H2O. Lawsonite crystallizes in the orthorhombic system in prismatic, often tabular crystals. Crystal twinning is common. It forms transparent to translucent colorless, white, pink, and bluish to pinkish grey glassy to greasy crystals. Refractive indices are nα = 1.665, nβ = 1.672 – 1.676, and nγ = 1.684 – 1.686. It is typically almost colorless in thin section, but some lawsonite is pleochroic from colorless to pale yellow to pale blue, depending on orientation. The mineral has a Mohs hardness of 7.5 and a specific gravity of 3.09. It has perfect cleavage in two directions and a brittle fracture.

In inorganic chemistry, mineral hydration is a reaction which adds water to the crystal structure of a mineral, usually creating a new mineral, commonly called a hydrate.

<span class="mw-page-title-main">Portlandite</span> Calcium hydroxide mineral

Portlandite is a hydroxide-bearing mineral typically included in the oxide mineral class. It is the naturally occurring form of calcium hydroxide (Ca(OH)2) and the calcium analogue of brucite (Mg(OH)2).

<span class="mw-page-title-main">Dollaseite-(Ce)</span> Epidote supergroup, sorosilicate mineral

Dollaseite-(Ce) is a sorosilicate end-member epidote rare-earth mineral which was discovered by Per Geijer (1927) in the Ostanmossa mine, Norberg district, Sweden. Dollaseite-(Ce), although not very well known, is part of a broad epidote group of minerals which are primarily silicates, the most abundant type of minerals on earth. Dollaseite-(Ce) forms as dark-brown subhedral crystals primarily in Swedish mines. With the ideal chemical formula, CaREE3+
Mg
2
AlSi
3
O
11
,(OH)F
, dollaseite-(Ce) can be partially identified by its content of the rare earth element cerium.

<span class="mw-page-title-main">Amesite</span>

Amesite is a mineral with general formula of Mg2Al2SiO5(OH)4.

<span class="mw-page-title-main">Ferrogedrite</span> Amphibole, double chain inosilicate mineral

Ferrogedrite is an amphibole mineral with the complex chemical formula of ☐Fe2+2(Fe2+3Al2)(Si6Al2)O22(OH)2. It is sodium and calcium poor, making it part of the magnesium-iron-manganese-lithium amphibole subgroup. Defined as less than 1.00 apfu (atoms per formula unit) of Na + Ca and consisting of greater than 1.00 apfu of (Mg, Fe2+, Mn2+, Li) separating it from the calcic-sodic amphiboles. It is related to anthophyllite amphibole and gedrite through coupled substitution of (Al, Fe3+) for (Mg, Fe2+, Mn) and Al for Si. and determined by the content of silicon in the standard cell.

<span class="mw-page-title-main">Bavenite</span>

Bavenite is a calcium beryllium aluminosilicate, and it is a part of the Bavenite-Bohseite series. Its name originates from its type locality, which is Baveno, Italy. This mineral is approved by the IMA, and got grandfathered, meaning it is still believed to refer to a valid mineral species. It was discovered in 1901 in a pink granite mined in Lago Maggiore. When bavenite was discovered, it was considered as a member of the zeolite series. Later it was removed from the series as unlike zeolites, bavenite loses the water stored in its crystal lattice in a way higher temperature, between 210 and 320 °C. It is a cheap mineral considering its rarity.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Clinozoisite on Mindat.org
  3. 1 2 "Clinozoisite in the Handbook of Mineralogy" (PDF). Archived from the original (PDF) on 2015-09-24. Retrieved 2014-03-24.
  4. Clinozoisite data on Webmineral
  5. Clinothulite on Mindat
  6. Deer, William A. (1997). Single-chain Silicates, Volume 2A. Geological Society of London. p. 477.