Cobalt oleate

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Cobalt oleate
Cobalt oleate.svg
Names
IUPAC name
Cobalt (Z)-octadec-9-enoate
Other names
Cobaltous oleate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.038.953 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 242-865-9
UNII
  • CCCCCCCC/C=C\CCCCCCCC(=O)[O-].CCCCCCCC/C=C\CCCCCCCC(=O)[O-].[Co+2]
Properties
C36H66CoO4
Molar mass 621.853 g·mol−1
AppearancePurple powder
Solubility Soluble in benzene, carbon tetrachloride, pyridine, chloroform, quinoline [1]
Hazards
GHS labelling:
GHS-pictogram-exclam.svg GHS-pictogram-pollu.svg
Warning
H317, H411, H412
P261, P272, P273, P280, P302+P352, P321, P333+P313, P362+P364, P391, P501
Related compounds
Other cations
Sodium oleate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Cobalt oleate is an organometallic compound with the formula Co(C 18 H 33 O 2)2. When cobalt oleate is added to non-polar solvents, the viscosity rapidly increases, and then continues increasing over time. This unusual viscosity effect is caused by the formation of a weak coordination complex with the solvent molecules. [1]

Contents

Preparation

Cobalt oleate can be synthesized by heating a solution of sodium oleate and cobalt(II) chloride to 70 °C. [2]

See also

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References

  1. 1 2 Funakoshi, Hideo; Matuura, Ryohei (October 1964). "Peptizing Action of Some Polar Substances on the Benzene Solution of Cobalt Oleate". Nature. 204 (4954): 186. Bibcode:1964Natur.204..186F. doi: 10.1038/204186a0 . ISSN   0028-0836. S2CID   4198459.
  2. An, Kwangjin; Lee, Nohyun; Park, Jongnam; Kim, Sung Chul; Hwang, Yosun; Park, Je-Geun; Kim, Jae-Young; Park, Jae-Hoon; Han, Myung Joon; Yu, Jaejun; Hyeon, Taeghwan (2006-08-01). "Synthesis, Characterization, and Self-Assembly of Pencil-Shaped CoO Nanorods" . Journal of the American Chemical Society. 128 (30): 9753–9760. doi:10.1021/ja0608702. ISSN   0002-7863. PMID   16866531.