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In geology and sedimentology, connate fluids are liquids that were trapped in the pores of sedimentary rocks as they were deposited. These liquids are largely composed of water, but also contain many mineral components as ions in solution.
As rocks are buried, they undergo lithification and the connate fluids are usually expelled. If the escape route for these fluids is blocked, the pore fluid pressure can build up, leading to overpressure.
An understanding of the geochemistry of connate fluids is important if the diagenesis of the rock is to be quantified. The solutes in the connate fluids often precipitate and reduce the porosity and permeability of the host rock, which can have important implications for its hydrocarbon prospectivity. The chemical components of the connate fluid can also yield information on the provenance of aquifers and of the thermal history of the host rock. Minute bubbles of fluid are often trapped within the crystals of the cementing material. These fluid inclusions provide direct information about the composition of the fluid and the pressure-temperature conditions that existed during diagenesis of the sediments.
Some analyses of connate water samples from Louisiana (USA) compared to seawater
| Average of samples from Tertiary formations | Average of samples from Cretaceous formations | ||||
|---|---|---|---|---|---|
| Constituent | Seawater mg/l | Connate water mg/l | Ratio Connate/Sea Water | Connate water mg/l | Ratio Connate/Sea Water |
| Lithium | 0.2 | 3 | 15 | 4 | 20 |
| Sodium | 10,600 | 37,539 | 3.5 | 28,462 | 2.7 |
| Potassium | 380 | 226 | 0.59 | 193 | 0.51 |
| Calcium | 400 | 2,077 | 5.2 | 4,999 | 12 |
| Magnesium | 1,300 | 686 | 0.53 | 606 | 0.47 |
| Strontium | 8 | 148 | 19 | 346 | 43 |
| Barium | 0.03 | 73 | 2,430 | 48.3 | 1,608 |
| Boron | 4.8 | 20 | 4.1 | 27.5 | 5.7 |
| Chloride | 19,000 | 63,992 | 3.4 | 54,910 | 2.9 |
| Bromide | 65 | 79 | 1.2 | 287 | 4.4 |
| Iodide | 0.05 | 21 | 420 | 37 | 740 |
| Sulphate | 2,690 | 104 | 0.039 | 206 | 0.077 |
| Source: A. Gene Collins, "Geochemistry of some petroleum-associated waters from Louisiana," US Bureau of Mines, Rept. of Investigations 7326, January 1970. | |||||
Similar, but different in origin, is the concept of fossil water, which is used to describe very old groundwater found in deep aquifers or bedrock. Typically it was recharged during a different climatic period (e.g., the last ice age) so is also very old, but possibly not of the same genesis as the rock.
Filtration is a physical separation process that separates solid matter and fluid from a mixture using a filter medium that has a complex structure through which only the fluid can pass. Solid particles that cannot pass through the filter medium are described as oversize and the fluid that passes through is called the filtrate. Oversize particles may form a filter cake on top of the filter and may also block the filter lattice, preventing the fluid phase from crossing the filter, known as blinding. The size of the largest particles that can successfully pass through a filter is called the effective pore size of that filter. The separation of solid and fluid is imperfect; solids will be contaminated with some fluid and filtrate will contain fine particles. Filtration occurs both in nature and in engineered systems; there are biological, geological, and industrial forms.
Sandstone is a clastic sedimentary rock composed mainly of sand-sized silicate grains. Sandstones comprise about 20–25% of all sedimentary rocks.
Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of geological detritus (minerals) or biological detritus. The geological detritus originated from weathering and erosion of existing rocks, or from the solidification of molten lava blobs erupted by volcanoes. The geological detritus is transported to the place of deposition by water, wind, ice or mass movement, which are called agents of denudation. Biological detritus was formed by bodies and parts of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on the floor of water bodies. Sedimentation may also occur as dissolved minerals precipitate from water solution.
An aquifer is an underground layer of water-bearing, permeable rock, rock fractures, or unconsolidated materials. Groundwater from aquifers can be extracted using a water well. Water from aquifers can be sustainably harvested through the use of qanats. Aquifers vary greatly in their characteristics. The study of water flow in aquifers and the characterization of aquifers is called hydrogeology. Related terms include aquitard, which is a bed of low permeability along an aquifer, and aquiclude, which is a solid, impermeable area underlying or overlying an aquifer, the pressure of which could lead to the formation of a confined aquifer. The classification of aquifers is as follows: Saturated versus unsaturated; aquifers versus aquitards; confined versus unconfined; isotropic versus anisotropic; porous, karst, or fractured; transboundary aquifer.
Sedimentology encompasses the study of modern sediments such as sand, silt, and clay, and the processes that result in their formation, transport, deposition and diagenesis. Sedimentologists apply their understanding of modern processes to interpret geologic history through observations of sedimentary rocks and sedimentary structures.
Catagenesis is a term used in petroleum geology to describe the cracking process which results in the conversion of organic kerogens into hydrocarbons.
Metamorphism is the transformation of existing rock to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface.
Volcanic rock is a rock formed from lava erupted from a volcano. Like all rock types, the concept of volcanic rock is artificial, and in nature volcanic rocks grade into hypabyssal and metamorphic rocks and constitute an important element of some sediments and sedimentary rocks. For these reasons, in geology, volcanics and shallow hypabyssal rocks are not always treated as distinct. In the context of Precambrian shield geology, the term "volcanic" is often applied to what are strictly metavolcanic rocks. Volcanic rocks and sediment that form from magma erupted into the air are called "pyroclastics," and these are also technically sedimentary rocks.
Hydrogeology is the area of geology that deals with the distribution and movement of groundwater in the soil and rocks of the Earth's crust. The terms groundwater hydrology, geohydrology, and hydrogeology are often used interchangeably.
Permeability in fluid mechanics and the Earth sciences is a measure of the ability of a porous material to allow fluids to pass through it.
Soil mechanics is a branch of soil physics and applied mechanics that describes the behavior of soils. It differs from fluid mechanics and solid mechanics in the sense that soils consist of a heterogeneous mixture of fluids and particles but soil may also contain organic solids and other matter. Along with rock mechanics, soil mechanics provides the theoretical basis for analysis in geotechnical engineering, a subdiscipline of civil engineering, and engineering geology, a subdiscipline of geology. Soil mechanics is used to analyze the deformations of and flow of fluids within natural and man-made structures that are supported on or made of soil, or structures that are buried in soils. Example applications are building and bridge foundations, retaining walls, dams, and buried pipeline systems. Principles of soil mechanics are also used in related disciplines such as geophysical engineering, coastal engineering, agricultural engineering, hydrology and soil physics.
A petroleum reservoir or oil and gas reservoir is a subsurface accumulation of hydrocarbons contained in porous or fractured rock formations.
Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined.
Clastic rocks are composed of fragments, or clasts, of pre-existing minerals and rock. A clast is a fragment of geological detritus, chunks, and smaller grains of rock broken off other rocks by physical weathering. Geologists use the term clastic to refer to sedimentary rocks and particles in sediment transport, whether in suspension or as bed load, and in sediment deposits.
In geology, texture or rock microstructure refers to the relationship between the materials of which a rock is composed. The broadest textural classes are crystalline, fragmental, aphanitic, and glassy. The geometric aspects and relations amongst the component particles or crystals are referred to as the crystallographic texture or preferred orientation. Textures can be quantified in many ways. The most common parameter is the crystal size distribution. This creates the physical appearance or character of a rock, such as grain size, shape, arrangement, and other properties, at both the visible and microscopic scale.
Petrophysics is the study of physical and chemical rock properties and their interactions with fluids.
A fracture is any separation in a geologic formation, such as a joint or a fault that divides the rock into two or more pieces. A fracture will sometimes form a deep fissure or crevice in the rock. Fractures are commonly caused by stress exceeding the rock strength, causing the rock to lose cohesion along its weakest plane. Fractures can provide permeability for fluid movement, such as water or hydrocarbons. Highly fractured rocks can make good aquifers or hydrocarbon reservoirs, since they may possess both significant permeability and fracture porosity.
Stylolites are serrated surfaces within a rock mass at which mineral material has been removed by pressure dissolution, in a deformation process that decreases the total volume of rock. Minerals which are insoluble in water, such as clays, pyrite and oxides, as well as insoluble organic matter, remain within the stylolites and make them visible. Sometimes host rocks contain no insoluble minerals, in which case stylolites can be recognized by change in texture of the rock. They occur most commonly in homogeneous rocks, carbonates, cherts, sandstones, but they can be found in certain igneous rocks and ice. Their size vary from microscopic contacts between two grains (microstylolites) to large structures up to 20 m in length and up to 10 m in amplitude in ice. Stylolites usually form parallel to bedding, because of overburden pressure, but they can be oblique or even perpendicular to bedding, as a result of tectonic activity.
Porosity or void fraction is a measure of the void spaces in a material, and is a fraction of the volume of voids over the total volume, between 0 and 1, or as a percentage between 0% and 100%. Strictly speaking, some tests measure the "accessible void", the total amount of void space accessible from the surface.
Fault zone hydrogeology is the study of how brittlely deformed rocks alter fluid flows in different lithological settings, such as clastic, igneous and carbonate rocks. Fluid movements, that can be quantified as permeability, can be facilitated or impeded due to the existence of a fault zone. This is because different mechanisms that deform rocks can alter porosity and permeability within a fault zone. Fluids involved in a fault system generally are groundwater and hydrocarbons.