Coronium was the name of a suggested chemical element, hypothesised in the 19th century. The name, inspired by the solar corona, was given by Gruenwald in 1887. [1] A new atomic thin green line in the solar corona was then considered to be emitted by a new element unlike anything else seen under laboratory conditions. It was later determined to be emitted by iron (Fe13+), so highly ionized that it was at that time impossible to produce in a laboratory.
During the total solar eclipse of 7 August 1869, a green emission line of wavelength 530.3 nm was independently observed by Charles Augustus Young (1834–1908) and William Harkness (1837–1903) in the coronal spectrum. Since this line did not correspond to that of any known material, it was proposed that it was due to an unknown element, provisionally named coronium.
The supposed element was discovered also in the gases given off by Mount Vesuvius in 1898 by a team of Italian chemists led by Raffaello Nasini . [2]
In 1902, over thirty years after his famous predictions of new elements based on his periodic table, and shortly after the discovery of various noble gases, the Russian chemist Dmitri Mendeleev hypothesized that there existed two noble gases of atomic weight less than hydrogen [3] [4] [5] [6] . The first, which he called "element x" or "newtonium", was his attempt a chemical explanation of the luminiferous aether. He argued that it had an atomic weight of 0.14. The second, which he called "element y" or coronium, was his attempt to explain the green emission lines from the Sun. He argued that it had an atomic weight of 0.4.
It was not until the 1930s that Walter Grotrian and Bengt Edlén discovered that the spectral line at 530.3 nm was due to highly ionized iron (Fe13+); other unusual lines in the coronal spectrum were also caused by highly charged ions, such as nickel, the high ionization being due to the extreme temperature of the solar corona. [7] The line at 530.3 nm had previously been misclassified as iron line number 1474. [8]
Atoms are the basic particles of the chemical elements. An atom consists of a nucleus of protons and generally neutrons, surrounded by an electromagnetically bound swarm of electrons. The chemical elements are distinguished from each other by the number of protons that are in their atoms. For example, any atom that contains 11 protons is sodium, and any atom that contains 29 protons is copper. Atoms with the same number of protons but a different number of neutrons are called isotopes of the same element.
Atomic absorption spectroscopy (AAS) and atomic emission spectroscopy (AES) is a spectroanalytical procedure for the quantitative determination of chemical elements by free atoms in the gaseous state. Atomic absorption spectroscopy is based on absorption of light by free metallic ions.
Atomic theory is the scientific theory that matter is composed of particles called atoms. The definition of the word "atom" has changed over the years in response to scientific discoveries. Initially, it referred to a hypothetical concept of there being some fundamental particle of matter, too small to be seen by the naked eye, that could not be divided. Then the definition was refined to being the basic particles of the chemical elements, when chemists observed that elements seemed to combine with each other in ratios of small whole numbers. Then physicists discovered that these particles had an internal structure of their own and therefore perhaps did not deserve to be called "atoms", but renaming atoms would have been impractical by that point.
A corona is the outermost layer of a star's atmosphere. It is a hot but relatively dim region of plasma populated by intermittent coronal structures known as solar prominences or filaments.
In astronomy, the interstellar medium (ISM) is the matter and radiation that exists in the space between the star systems in a galaxy. This matter includes gas in ionic, atomic, and molecular form, as well as dust and cosmic rays. It fills interstellar space and blends smoothly into the surrounding intergalactic space. The energy that occupies the same volume, in the form of electromagnetic radiation, is the interstellar radiation field. Although the density of atoms in the ISM is usually far below that in the best laboratory vacuums, the mean free path between collisions is short compared to typical interstellar lengths, so on these scales the ISM behaves as a gas (more precisely, as a plasma: it is everywhere at least slightly ionized), responding to pressure forces, and not as a collection of non-interacting particles.
Dmitri Mendeleev published a periodic table of the chemical elements in 1869 based on properties that appeared with some regularity as he laid out the elements from lightest to heaviest. When Mendeleev proposed his periodic table, he noted gaps in the table and predicted that then-unknown elements existed with properties appropriate to fill those gaps. He named them eka-boron, eka-aluminium, eka-silicon, and eka-manganese, with respective atomic masses of 44, 68, 72, and 100.
A spectral line is a weaker or stronger region in an otherwise uniform and continuous spectrum. It may result from emission or absorption of light in a narrow frequency range, compared with the nearby frequencies. Spectral lines are often used to identify atoms and molecules. These "fingerprints" can be compared to the previously collected ones of atoms and molecules, and are thus used to identify the atomic and molecular components of stars and planets, which would otherwise be impossible.
Astronomical spectroscopy is the study of astronomy using the techniques of spectroscopy to measure the spectrum of electromagnetic radiation, including visible light, ultraviolet, X-ray, infrared and radio waves that radiate from stars and other celestial objects. A stellar spectrum can reveal many properties of stars, such as their chemical composition, temperature, density, mass, distance and luminosity. Spectroscopy can show the velocity of motion towards or away from the observer by measuring the Doppler shift. Spectroscopy is also used to study the physical properties of many other types of celestial objects such as planets, nebulae, galaxies, and active galactic nuclei.
The emission spectrum of a chemical element or chemical compound is the spectrum of frequencies of electromagnetic radiation emitted due to electrons making a transition from a high energy state to a lower energy state. The photon energy of the emitted photons is equal to the energy difference between the two states. There are many possible electron transitions for each atom, and each transition has a specific energy difference. This collection of different transitions, leading to different radiated wavelengths, make up an emission spectrum. Each element's emission spectrum is unique. Therefore, spectroscopy can be used to identify elements in matter of unknown composition. Similarly, the emission spectra of molecules can be used in chemical analysis of substances.
The Fraunhofer lines are a set of spectral absorption lines. They are dark absorption lines, seen in the optical spectrum of the Sun, and are formed when atoms in the solar atmosphere absorb light being emitted by the solar photosphere. The lines are named after German physicist Joseph von Fraunhofer, who observed them in 1814.
The periodic table is an arrangement of the chemical elements, structured by their atomic number, electron configuration and recurring chemical properties. In the basic form, elements are presented in order of increasing atomic number, in the reading sequence. Then, rows and columns are created by starting new rows and inserting blank cells, so that rows (periods) and columns (groups) show elements with recurring properties. For example, all elements in group (column) 18 are noble gases that are largely—though not completely—unreactive.
Nebulium was a proposed element found in astronomical observation of a nebula by William Huggins in 1864. The strong green emission lines of the Cat's Eye Nebula, discovered using spectroscopy, led to the postulation that an as yet unknown element was responsible for this emission. In 1927, Ira Sprague Bowen showed that the lines are emitted by doubly ionized oxygen (O2+), and no new element was necessary to explain them.
An ion laser is a gas laser that uses an ionized gas as its lasing medium. Like other gas lasers, ion lasers feature a sealed cavity containing the laser medium and mirrors forming a Fabry–Pérot resonator. Unlike helium–neon lasers, the energy level transitions that contribute to laser action come from ions. Because of the large amount of energy required to excite the ionic transitions used in ion lasers, the required current is much greater, and as a result almost all except for the smallest ion lasers are water-cooled. A small air-cooled ion laser might produce, for example, 130 milliwatts of output light with a tube current of about 10 amperes and a voltage of 105 volts. Since one ampere times one volt is one watt, this is an electrical power input of about one kilowatt. Subtracting the (desirable) light output of 130 mW from power input, this leaves the large amount of waste heat of nearly one kW. This has to be dissipated by the cooling system. In other words, the power efficiency is very low.
Extreme ultraviolet radiation or high-energy ultraviolet radiation is electromagnetic radiation in the part of the electromagnetic spectrum spanning wavelengths shorter than the hydrogen Lyman-alpha line from 121 nm down to the X-ray band of 10 nm. By the Planck–Einstein equation the EUV photons have energies from 10.26 eV up to 124.24 eV where we enter the X-ray energies. EUV is naturally generated by the solar corona and artificially by plasma, high harmonic generation sources and synchrotron light sources. Since UVC extends to 100 nm, there is some overlap in the terms.
A deuterium arc lamp is a low-pressure gas-discharge light source often used in spectroscopy when a continuous spectrum in the ultraviolet region is needed.
Walter Robert Wilhelm Grotrian was a German astronomer and astrophysicist.
Static secondary-ion mass spectrometry, or static SIMS is a secondary ion mass spectrometry technique for chemical analysis including elemental composition and chemical structure of the uppermost atomic or molecular layer of a solid which may be a metal, semiconductor or plastic with insignificant disturbance to its composition and structure. It is one of the two principal modes of operation of SIMS, which is the mass spectrometry of ionized particles emitted by a solid surface upon bombardment by energetic primary particles.
Atomic emission spectroscopy (AES) is a method of chemical analysis that uses the intensity of light emitted from a flame, plasma, arc, or spark at a particular wavelength to determine the quantity of an element in a sample. The wavelength of the atomic spectral line in the emission spectrum gives the identity of the element while the intensity of the emitted light is proportional to the number of atoms of the element. The sample may be excited by various methods.
In astronomy and in astrophysics, for radiative losses of the solar corona, it is meant the energy flux radiated from the external atmosphere of the Sun, and, in particular, the processes of production of the radiation coming from the solar corona and transition region, where the plasma is optically-thin. On the contrary, in the chromosphere, where the temperature decreases from the photospheric value of 6000 K to the minimum of 4400 K, the optical depth is about 1, and the radiation is thermal.
Modern spectroscopy in the Western world started in the 17th century. New designs in optics, specifically prisms, enabled systematic observations of the solar spectrum. Isaac Newton first applied the word spectrum to describe the rainbow of colors that combine to form white light. During the early 1800s, Joseph von Fraunhofer conducted experiments with dispersive spectrometers that enabled spectroscopy to become a more precise and quantitative scientific technique. Since then, spectroscopy has played and continues to play a significant role in chemistry, physics and astronomy. Fraunhofer observed and measured dark lines in the Sun's spectrum, which now bear his name although several of them were observed earlier by Wollaston.