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Syngas, or synthesis gas, is a mixture of hydrogen and carbon monoxide, in various ratios. The gas often contains some carbon dioxide and methane. It is principally used for producing ammonia or methanol. Syngas is combustible and can be used as a fuel. Historically, it has been used as a replacement for gasoline, when gasoline supply has been limited; for example, wood gas was used to power cars in Europe during WWII.
Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.
Coal gas is a flammable gaseous fuel made from coal and supplied to the user via a piped distribution system. It is produced when coal is heated strongly in the absence of air. Town gas is a more general term referring to manufactured gaseous fuels produced for sale to consumers and municipalities.
The Fischer–Tropsch process is a collection of chemical reactions that converts a mixture of carbon monoxide and hydrogen, known as syngas, into liquid hydrocarbons. These reactions occur in the presence of metal catalysts, typically at temperatures of 150–300 °C (302–572 °F) and pressures of one to several tens of atmospheres. The Fischer–Tropsch process is an important reaction in both coal liquefaction and gas to liquids technology for producing liquid hydrocarbons.
In industrial chemistry, coal gasification is the process of producing syngas—a mixture consisting primarily of carbon monoxide (CO), hydrogen, carbon dioxide, methane, and water vapour —from coal and water, air and/or oxygen.
The Sabatier reaction or Sabatier process produces methane and water from a reaction of hydrogen with carbon dioxide at elevated temperatures and pressures in the presence of a nickel catalyst. It was discovered by the French chemists Paul Sabatier and Jean-Baptiste Senderens in 1897. Optionally, ruthenium on alumina makes a more efficient catalyst. It is described by the following exothermic reaction.
Substitute natural gas (SNG), or synthetic natural gas, is a fuel gas (predominantly methane, CH4) that can be produced from fossil fuels such as lignite coal, oil shale, or from biofuels (when it is named bio-SNG) or using electricity with power-to-gas systems.
Coal liquefaction is a process of converting coal into liquid hydrocarbons: liquid fuels and petrochemicals. This process is often known as "Coal to X" or "Carbon to X", where X can be many different hydrocarbon-based products. However, the most common process chain is "Coal to Liquid Fuels" (CTL).
Synthetic fuel or synfuel is a liquid fuel, or sometimes gaseous fuel, obtained from syngas, a mixture of carbon monoxide and hydrogen, in which the syngas was derived from gasification of solid feedstocks such as coal or biomass or by reforming of natural gas.
Underground coal gasification (UCG) is an industrial process which converts coal into product gas. UCG is an in-situ gasification process, carried out in non-mined coal seams using injection of oxidants and steam. The product gas is brought to the surface through production wells drilled from the surface.
Basin Electric Power Cooperative is a wholesale electric generation and transmission cooperative based in North Dakota that provides electricity to 2.8 million customers in nine U.S. states. The roots of the cooperative go back to 1960 when Leland Olds and ten power suppliers created Giant Power Cooperative. Giant Power was first going to be a generation and transmission cooperative, but to keep electricity cheaper for rural customers, Basin Electric Power Cooperative was started in 1961. Today, Basin Electric's power sources include coal, natural gas, hydroelectric, wind, waste heat, and nuclear. The current CEO and General Manager is Paul Sukut. A subsidiary of Basin Electric, Dakota Gasification Company, operates the Great Plains Synfuels Plant, which captures and sequesters nearly 50% of its carbon dioxide emissions in a system developed during the Carter administration. In 2005, the membership of Basin Electric passed a resolution requiring 10 percent of electricity demand to be provided by renewable forms of energy. At the end of 2009, Basin Electric finished construction on a 77 turbine wind energy project.
The Dakota Coal Company, subsidiary of Basin Electric Power Cooperative, is based in Bismarck, North Dakota. It controls the rights to lignite reserves in North Dakota and provides financing for the Freedom Mine north of Beulah, ND. Dakota Coal Company is also responsible for marketing Freedom Mine lignite production. Dakota Coal and The Coteau Properties Co. work closely with their customers to ensure lignite quality doesn't hamper daily plant operations.
An integrated gasification combined cycle (IGCC) is a technology using a high pressure gasifier to turn coal and other carbon based fuels into pressurized gas—synthesis gas (syngas). It can then remove impurities from the syngas prior to the electricity generation cycle. Some of these pollutants, such as sulfur, can be turned into re-usable byproducts through the Claus process. This results in lower emissions of sulfur dioxide, particulates, mercury, and in some cases carbon dioxide. With additional process equipment, a water-gas shift reaction can increase gasification efficiency and reduce carbon monoxide emissions by converting it to carbon dioxide. The resulting carbon dioxide from the shift reaction can be separated, compressed, and stored through sequestration. Excess heat from the primary combustion and syngas fired generation is then passed to a steam cycle, similar to a combined cycle gas turbine. This process results in improved thermodynamic efficiency, compared to conventional pulverized coal combustion.
Hydrogen production is the family of industrial methods for generating hydrogen gas. As of 2020, the majority of hydrogen (∼95%) is produced from fossil fuels by steam reforming of natural gas and other light hydrocarbons, partial oxidation of heavier hydrocarbons, and coal gasification. Other methods of hydrogen production include biomass gasification, zero-CO2-emission methane pyrolysis, and electrolysis of water. The latter processes, methane pyrolysis as well as water electrolysis can be done directly with any source of electricity, such as solar power.
Methanation is the conversion of carbon monoxide and carbon dioxide (COx) to methane (CH4) through hydrogenation. The methanation reactions of COx were first discovered by Sabatier and Senderens in 1902.
The milestones for carbon capture and storage show the lack of commercial scale development and implementation of CCS over the years since the first carbon tax was imposed.
Linc Energy was an Australian energy company that specialised in coal-based synthetic fuel production, as well as conventional oil and gas production. It was engaged in development and commercialisation of proprietary underground coal gasification technology. Produced gas was used for production of synthetic fuel through gas-to-liquid technology, and was also used for power generation. The company had its headquarters in Brisbane, Queensland.
The Weyburn-Midale Carbon Dioxide Project is, as of 2008, the world's largest carbon capture and storage project. It is located in Midale, Saskatchewan, Canada.
Coal gasification is a process whereby a hydrocarbon feedstock (coal) is converted into gaseous components by applying heat under pressure in the presence of steam. Rather than burning, most of the carbon-containing feedstock is broken apart by chemical reactions that produce "syngas." Syngas is primarily hydrogen and carbon monoxide, but the exact composition can vary. In Integrated Gasification Combined Cycle (IGCC) systems, the syngas is cleaned and burned as fuel in a combustion turbine which then drives an electric generator. Exhaust heat from the combustion turbine is recovered and used to create steam for a steam turbine-generator. The use of these two types of turbines in combination is one reason why gasification-based power systems can achieve high power generation efficiencies. Currently, commercially available gasification-based systems can operate at around 40% efficiencies. Syngas, however, emits more greenhouse gases than natural gas, and almost twice as much carbon as a coal plant. Coal gasification is also water-intensive.
Lower-temperature fuel cell types such as the proton exchange membrane fuel cell, phosphoric acid fuel cell, and alkaline fuel cell require pure hydrogen as fuel, typically produced from external reforming of natural gas. However, fuels cells operating at high temperature such as the solid oxide fuel cell (SOFC) are not poisoned by carbon monoxide and carbon dioxide, and in fact can accept hydrogen, carbon monoxide, carbon dioxide, steam, and methane mixtures as fuel directly, because of their internal shift and reforming capabilities. This opens up the possibility of efficient fuel cell-based power cycles consuming solid fuels such as coal and biomass, the gasification of which results in syngas containing mostly hydrogen, carbon monoxide and methane which can be cleaned and fed directly to the SOFCs without the added cost and complexity of methane reforming, water gas shifting and hydrogen separation operations which would otherwise be needed to isolate pure hydrogen as fuel. A power cycle based on gasification of solid fuel and SOFCs is called an Integrated Gasification Fuel Cell (IGFC) cycle; the IGFC power plant is analogous to an integrated gasification combined cycle power plant, but with the gas turbine power generation unit replaced with a fuel cell power generation unit. By taking advantage of intrinsically high energy efficiency of SOFCs and process integration, exceptionally high power plant efficiencies are possible. Furthermore, SOFCs in the IGFC cycle can be operated so as to isolate a carbon dioxide-rich anodic exhaust stream, allowing efficient carbon capture to address greenhouse gas emissions concerns of coal-based power generation.
References
- ↑ Beulah, North Dakota 58523. "beulah". Google Maps. Retrieved 2012-01-23.
- ↑ MacPherson, James (2008-06-18). "Portsmouth company chosen to lead $300 million CO2 project". Associated Press. Retrieved 2012-01-24.
- ↑ Gomez, Nathalie (16 August 2021). "Bakken Energy reaches agreement to purchase Dakota Gasification Company assets". KX News. Nexstar Media Inc. Retrieved 31 August 2021.
- ↑ Alvarado, Vladimir; Manrique, Eduardo (2010). Enhanced Oil Recovery: Field Planning and Development Strategies. Gulf Professional Publishing. p. 86. ISBN 978-1-85617-855-6.
- ↑ "Boards of Directors". Basin Electric Power Cooperative. Archived from the original on 2014-08-09. Retrieved 2014-08-13.
- ↑ Kathi Risch (2013-02-05). "New faces in 2012: Basin Electric and Dakota Gas boards welcome new members". Basin Electric Power Cooperative. Archived from the original on 2014-08-14. Retrieved 2014-08-13.
- ↑ "Governance". DakotaGas.com. Archived from the original on 2021-08-11. Retrieved 11 August 2021.
