Dielectric absorption

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Dielectric absorption is the name given to the effect by which a capacitor, that has been charged for a long time, discharges only incompletely when briefly discharged. Although an ideal capacitor would remain at zero volts after being discharged, real capacitors will develop a small voltage from time-delayed dipole discharging, [1] a phenomenon that is also called dielectric relaxation, "soakage", or "battery action". For some dielectrics, such as many polymer films, the resulting voltage may be less than 1–2% of the original voltage, but it can be as much as 15% for electrolytic capacitors. The voltage at the terminals generated by the dielectric absorption may possibly cause problems in the function of an electronic circuit or can be a safety risk to personnel. In order to prevent shocks, most very large capacitors are shipped with shorting wires that need to be removed before they are used and/or permanently connected bleeder resistors. When disconnected at one or both ends, DC high-voltage cables can also "recharge themselves" to dangerous voltages.

Contents

Theory

The random orientations of molecular dipoles in a dielectric are aligned under the influence of an electric field by applying a voltage to the electrodes. Diel.png
The random orientations of molecular dipoles in a dielectric are aligned under the influence of an electric field by applying a voltage to the electrodes.
Circuit model for explaining a time-delayed voltage build-up by parallel RC-timers Dielektrische Absorption.svg
Circuit model for explaining a time-delayed voltage build-up by parallel RC-timers

Charging a capacitor (due to a voltage between the capacitor plates) causes an electric field to be applied to the dielectric between the electrodes. This field exerts a torque on the molecular dipoles, causing the directions of the dipole moments to align with the field direction. This change in the molecular dipoles is called oriented polarization and also causes heat to be generated, resulting in dielectric losses (see dissipation factor). The time of the dipoles orientation does not follow the electric field synchronously, but is delayed by a time constant that depends on the material. This delay corresponds to a hysteresis response of the polarization to the external field.

When the capacitor is discharging, the strength of the electric field is decreasing and the common orientation of the molecular dipoles is returning to an undirected state in a process of relaxation. Due to the hysteresis, at the zero point of the electric field, a material-dependent number of molecular dipoles are still polarized along the field direction without a measurable voltage appearing at the terminals of the capacitor. This is like an electrical version of magnetic remanence. The oriented dipoles will be discharged spontaneously over time and the voltage at the electrodes of the capacitor will decay exponentially. [2] The complete discharge time of all dipoles can be days to weeks depending on the material. This "reloaded" voltage can be retained for months, even in electrolytic capacitors, caused by the high insulation resistance in common modern capacitor dielectrics. The discharge of a capacitor and the subsequent reloading can be repeated several times.

Measurement

Dielectric absorption is a property which has been long known. Its value can be measured in accordance with the IEC/EN 60384-1 standard. The capacitor shall be charged at the DC voltage rating for 60 minutes. Then the capacitor shall be disconnected from the power source and shall be discharged for 10 s. The voltage regained on the capacitor terminals (recovery voltage) within 15 minutes is the dielectric absorption voltage. The size of the dielectric absorption voltage is specified in relation to the applied voltage in percent and depends on the dielectric material used. It is specified by many manufacturers in the data sheets. [3] [4] [5] [6] [7]

Type of capacitorDielectric absorption
Air and vacuum capacitorsNot measurable
Class-1 ceramic capacitors, NP00.6%
Class-2 ceramic capacitors, X7R0.6 to 1.0% [7]
Class-2 ceramic capacitors, Z5U2.0 to 2.5% [7]
Polypropylene film capacitors (PP)0.05 to 0.1%
Polyester film capacitors (PET)0.2 to 0.5%
Polyphenylene sulfide film capacitors (PPS)0.05 to 0.1%
Polyethylene naphthalate film capacitors (PEN)1.0 to 1.2%
Tantalum electrolytic capacitors with solid electrolyte2 to 3 %, [8] 10 % [9]
Aluminium electrolytic capacitors with non-solid electrolyte10 to 15% [10]
Double-layer capacitor data not available

Design considerations and safety

The voltage at the terminals generated by the dielectric absorption may possibly cause problems in the function of an electronic circuit. For sensitive analog circuits such as sample and hold circuits, integrators, charge amplifiers or high-quality audio circuits, Class-1 ceramic or polypropylene capacitors instead of Class-2 ceramic capacitors, polyester film capacitors or electrolytic capacitors are used. [11] For most electronic circuits, particularly filtering applications, the small dielectric absorption voltage has no influence on the proper electrical function of the circuit. For aluminum electrolytic capacitors with non-solid electrolyte which are not built into a circuit, the dielectric absorption voltage generated can be a personnel safety risk. [12] The voltage can be quite substantial, for example 50 V for 400 V electrolytic capacitors, and can cause damages to semiconductor devices, or cause sparks during installation in the circuit. Larger aluminum electrolytic capacitors and high-voltage power capacitors are transported and delivered short-circuited to dissipate this unwanted and possibly dangerous energy.

Another effect of dielectric absorption is sometimes described as "soakage". This manifests as a component of leakage current and it contributes to the loss factor of the capacitor. This effect has been known of only recently:[ failed verification ] it is now a proportionately greater part of leakage current due to the significantly improved properties of modern capacitors. [9]

No figures are available from manufacturers for double-layer capacitors.

History

Dielectric absorption was first discovered in Leyden jars and telegraph cables, and it was already a well-known phenomenon in the late 19th century. Once known as "electric absorption", satisfactory explanations of its physical mechanism was lacking at that time. A description appeared in James Clerk Maxwell's 1873 book A Treatise on Electricity and Magnetism , in which he derived its physical model, but it was only applicable to an inhomogeneous dielectric material with multiple layers. [13] [14]

See also

Related Research Articles

<span class="mw-page-title-main">Dielectric</span> Electrically insulating substance able to be polarised by an applied electric field

In electromagnetism, a dielectric is an electrical insulator that can be polarised by an applied electric field. When a dielectric material is placed in an electric field, electric charges do not flow through the material as they do in an electrical conductor, because they have no loosely bound, or free, electrons that may drift through the material, but instead they shift, only slightly, from their average equilibrium positions, causing dielectric polarisation. Because of dielectric polarisation, positive charges are displaced in the direction of the field and negative charges shift in the direction opposite to the field. This creates an internal electric field that reduces the overall field within the dielectric itself. If a dielectric is composed of weakly bonded molecules, those molecules not only become polarised, but also reorient so that their symmetry axes align to the field.

<span class="mw-page-title-main">Permittivity</span> Measure of the electric polarizability of a dielectric

In electromagnetism, the absolute permittivity, often simply called permittivity and denoted by the Greek letter ε (epsilon), is a measure of the electric polarizability of a dielectric. A material with high permittivity polarizes more in response to an applied electric field than a material with low permittivity, thereby storing more energy in the material. In electrostatics, the permittivity plays an important role in determining the capacitance of a capacitor.

<span class="mw-page-title-main">Electrolytic capacitor</span> Type of capacitor

An electrolytic capacitor is a polarized capacitor whose anode or positive plate is made of a metal that forms an insulating oxide layer through anodization. This oxide layer acts as the dielectric of the capacitor. A solid, liquid, or gel electrolyte covers the surface of this oxide layer, serving as the cathode or negative plate of the capacitor. Because of their very thin dielectric oxide layer and enlarged anode surface, electrolytic capacitors have a much higher capacitance-voltage (CV) product per unit volume than ceramic capacitors or film capacitors, and so can have large capacitance values. There are three families of electrolytic capacitor: aluminium electrolytic capacitors, tantalum electrolytic capacitors, and niobium electrolytic capacitors.

An electret is a dielectric material that has a quasi-permanent electric charge or dipole polarisation. An electret generates internal and external electric fields, and is the electrostatic equivalent of a permanent magnet. Although Oliver Heaviside coined this term in 1885, materials with electret properties were already known to science and had been studied since the early 1700s. One particular example is the electrophorus, a device consisting of a slab with electret properties and a separate metal plate. The electrophorus was originally invented by Johan Carl Wilcke in Sweden and again by Alessandro Volta in Italy.

<span class="mw-page-title-main">Electronic component</span> Discrete device in an electronic system

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Dielectric heating, also known as electronic heating, radio frequency heating, and high-frequency heating, is the process in which a radio frequency (RF) alternating electric field, or radio wave or microwave electromagnetic radiation heats a dielectric material. At higher frequencies, this heating is caused by molecular dipole rotation within the dielectric.

<span class="mw-page-title-main">Capacitor types</span> Manufacturing styles of an electronic device

Capacitors are manufactured in many styles, forms, dimensions, and from a large variety of materials. They all contain at least two electrical conductors, called plates, separated by an insulating layer (dielectric). Capacitors are widely used as parts of electrical circuits in many common electrical devices.

In electronics, a bleeder resistor, bleeder load, leakage resistor, capacitor discharge resistor or safety discharge resistor is a resistor connected in parallel with the output of a high-voltage power supply circuit for the purpose of discharging the electric charge stored in the power supply's filter capacitors when the equipment is turned off, for safety reasons. It eliminates the possibility of a leftover charge causing electric shock if people handle or service the equipment in the off state, believing it is safe. A bleeder resistor is usually a standard resistor rather than a specialized component.

<span class="mw-page-title-main">Capacitor</span> Passive two-terminal electronic component that stores electrical energy in an electric field

A capacitor is an electronic device that stores electrical energy in an electric field by accumulating electric charges on two closely spaced surfaces that are insulated from each other. It is a passive electronic component with two terminals.

<span class="mw-page-title-main">Ceramic capacitor</span> Fixed-value capacitor using ceramic

A ceramic capacitor is a fixed-value capacitor where the ceramic material acts as the dielectric. It is constructed of two or more alternating layers of ceramic and a metal layer acting as the electrodes. The composition of the ceramic material defines the electrical behavior and therefore applications. Ceramic capacitors are divided into two application classes:

<span class="mw-page-title-main">Applications of capacitors</span> Uses of capacitors in daily life

Capacitors have many uses in electronic and electrical systems. They are so ubiquitous that it is rare that an electrical product does not include at least one for some purpose. Capacitors allow only AC signals to pass when they are charged blocking DC signals. The main components of filters are capacitors. Capacitors have the ability to connect one circuit segment to another. Capacitors are used by Dynamic Random Access Memory (DRAM) devices to represent binary information as bits.

<span class="mw-page-title-main">Tantalum capacitor</span> Type of electrolytic capacitor

A tantalum electrolytic capacitor is an electrolytic capacitor, a passive component of electronic circuits. It consists of a pellet of porous tantalum metal as an anode, covered by an insulating oxide layer that forms the dielectric, surrounded by liquid or solid electrolyte as a cathode. Because of its very thin and relatively high permittivity dielectric layer, the tantalum capacitor distinguishes itself from other conventional and electrolytic capacitors in having high capacitance per volume and lower weight.

<span class="mw-page-title-main">Failure of electronic components</span> Ways electronic components fail and prevention measures

Electronic components have a wide range of failure modes. These can be classified in various ways, such as by time or cause. Failures can be caused by excess temperature, excess current or voltage, ionizing radiation, mechanical shock, stress or impact, and many other causes. In semiconductor devices, problems in the device package may cause failures due to contamination, mechanical stress of the device, or open or short circuits.

<span class="mw-page-title-main">Polymer capacitor</span> Solid conductive electrolyte

A polymer capacitor, or more accurately a polymer electrolytic capacitor, is an electrolytic capacitor (e-cap) with a solid conductive polymer electrolyte. There are four different types:

<span class="mw-page-title-main">Supercapacitor</span> Electrochemical capacitor

A supercapacitor (SC), also called an ultracapacitor, is a high-capacity capacitor, with a capacitance value much higher than solid-state capacitors but with lower voltage limits. It bridges the gap between electrolytic capacitors and rechargeable batteries. It typically stores 10 to 100 times more energy per unit volume or mass than electrolytic capacitors, can accept and deliver charge much faster than batteries, and tolerates many more charge and discharge cycles than rechargeable batteries.

<span class="mw-page-title-main">Film capacitor</span> Electrical capacitor with an insulating plastic film as the dielectric

Film capacitors, plastic film capacitors, film dielectric capacitors, or polymer film capacitors, generically called film caps as well as power film capacitors, are electrical capacitors with an insulating plastic film as the dielectric, sometimes combined with paper as carrier of the electrodes.

Double-layer capacitance is the important characteristic of the electrical double layer which appears at the interface between a surface and a fluid. At this boundary two layers of electric charge with opposing polarity form, one at the surface of the electrode, and one in the electrolyte. These two layers, electrons on the electrode and ions in the electrolyte, are typically separated by a single layer of solvent molecules that adhere to the surface of the electrode and act like a dielectric in a conventional capacitor. The amount of charge stored in double-layer capacitor depends on the applied voltage.

<span class="mw-page-title-main">SAL electrolytic capacitor</span> Capacitor with high capacitance in a small package

SAL electrolytic capacitors are a form of capacitor developed for high capacitance in a small package, with a long and robust service life. They are aluminum electrolytic capacitors with anodic oxidized aluminum oxide as dielectric and with the semiconducting solid manganese dioxide as electrolyte. They are made of etched and formed aluminum anodes, which are folded for the dipped pearl types or wound into a roll for the axial style. The solid manganese dioxide electrolyte is formed onto this roll in a pyrolytic process, similar to that for solid tantalum capacitors.

<span class="mw-page-title-main">Aluminum electrolytic capacitor</span> Type of capacitor

Aluminum electrolytic capacitors are polarized electrolytic capacitors whose anode electrode (+) is made of a pure aluminum foil with an etched surface. The aluminum forms a very thin insulating layer of aluminum oxide by anodization that acts as the dielectric of the capacitor. A non-solid electrolyte covers the rough surface of the oxide layer, serving in principle as the second electrode (cathode) (-) of the capacitor. A second aluminum foil called “cathode foil” contacts the electrolyte and serves as the electrical connection to the negative terminal of the capacitor.

<span class="mw-page-title-main">Niobium capacitor</span> Electrolytic capacitor

A niobium electrolytic capacitor is an electrolytic capacitor whose anode (+) is made of passivated niobium metal or niobium monoxide, on which an insulating niobium pentoxide layer acts as a dielectric. A solid electrolyte on the surface of the oxide layer serves as the capacitor's cathode (−).

References

  1. "Modeling Dielectric Absorption in Capacitors, by Ken Kundert" (PDF).
  2. "Elliot sound products, 2.1 - Dielectric Absorption".
  3. WIMA, Characteristics of Metallized film capacitors in Comparison with Other Dielectrics "WIMA". Archived from the original on 2012-11-05. Retrieved 2012-12-14.
  4. "Film Capacitors, TDK Epcos, General technical information" (PDF). Archived from the original (PDF) on 2012-02-01. Retrieved 2012-01-23.
  5. AVX, Dielectric Comparison Chart
  6. "Holystone, Capacitor Dielectric Comparison, Technical Note 3" (PDF). Archived from the original (PDF) on 2012-02-01. Retrieved 2012-01-23.
  7. 1 2 3 https://www.wima.de/de/service/knowledge-base/grundlagen-der-kondensatorentechnologie/ knowledge base of the capacitor manufacturer WIMA (german), Retrieved 2020-11-21.
  8. "Kemet, Polymer Tantalum Chip Capacitors" (PDF). Archived from the original (PDF) on 2014-11-23. Retrieved 2012-01-23.
  9. 1 2 R. W. Franklin, AVX, Analysis of Solid Tantalum Capacitor Leakage Current, PDF, PDF
  10. CDE, Aluminum Electrolytic Capacitor Application Guide, PDF
  11. National Semiconductors, Understand Capacitor Soakage to Optimize Analog Systems Archived 2010-01-23 at the Wayback Machine
  12. What's all this Trapped Charge and Dielectric Compression stuff anyhow?
  13. Maxwell, James (1873). "Chapter X. Conduction in Dielectrics". A Treatise on Electricity and Magnetism. Clarendon Press. p. 376. In a condenser of this kind, first charged in any way, next discharged through a wire of small resistance, and then insulated, no new electrification will appear. In most actual condensers, however, we find that after discharge and insulation a new charge is gradually developed, of the same kind as the original charge, but inferior in intensity. This is called the residual charge. To account for it we must admit that the constitution of the dielectric medium is different from that which we have just described. We shall find, however, that a medium formed of a conglomeration of small pieces of different simple media would possess this property.
  14. H. A. Rowland (1878). "Note on the Theory of Electric Absorption". American Journal of Mathematics . 1 (1): 53–58. doi:10.2307/2369434. JSTOR   2369434.

Further reading