Europium anomaly

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Rare-earth element abundances of basalts, of both terrestrial and lunar origins A graph of basalt REE abundance.png
Rare-earth element abundances of basalts, of both terrestrial and lunar origins

The europium anomaly is the phenomenon whereby the europium (Eu) concentration in a mineral is either enriched or depleted relative to some standard, commonly a chondrite or mid-ocean ridge basalt (MORB). In geochemistry a europium anomaly is said to be "positive" if the Eu concentration in the mineral is enriched relative to the other rare-earth elements (REEs), and is said to be "negative" if Eu is depleted relative to the other REEs.

While all lanthanides form relatively large trivalent (3+) ions, Eu and cerium (Ce) have additional valences, europium forms 2+ ions, and Ce forms 4+ ions, leading to chemical reaction differences in how these ions can partition versus the 3+ REEs. In the case of Eu, its reduced divalent (2+) cations are similar in size and carry the same charge as Ca2+, an ion found in plagioclase and other minerals. While Eu is an incompatible element in its trivalent form (Eu3+) in an oxidizing magma, it is preferentially incorporated into plagioclase in its divalent form (Eu2+) in a reducing magma, where it substitutes for calcium (Ca2+). [2]

Enrichment or depletion is generally attributed to europium's tendency to be incorporated into plagioclase preferentially over other minerals. If a magma crystallizes stable plagioclase, most of the Eu will be incorporated into this mineral, causing a higher than expected concentration of Eu in the mineral versus other REE in that mineral (a positive anomaly). The rest of the magma will then be relatively depleted in Eu with a concentration of Eu lower than expected versus the concentrations of other REEs in that magma. If the Eu-depleted magma is then separated from its plagioclase crystals and subsequently solidifies, its chemical composition will display a negative Eu anomaly (because the Eu is locked up in the plagioclase left in the magma chamber). Conversely, if a magma accumulates plagioclase crystals before solidification, its rock composition will display a relatively positive Eu anomaly. [3] [4]

A well-known example of the Eu anomaly is seen on the Moon. REE analyses of the Moon's light-colored lunar highlands show a large positive Eu anomaly due to the plagioclase-rich anorthosite comprising the highlands. The darker lunar mare, consisting mainly of basalt, shows a large negative Eu anomaly. This has led geologists to speculate as to the genetic relationship between the lunar highlands and mare. It is possible that much of the Moon's Eu was incorporated into the earlier, plagioclase-rich highlands, leaving the later basaltic mare strongly depleted in Eu. [5]

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<span class="mw-page-title-main">Europium</span> Chemical element, symbol Eu and atomic number 63

Europium is a chemical element; it has symbol Eu and atomic number 63. Europium is a silvery-white metal of the lanthanide series that reacts readily with air to form a dark oxide coating. It is the most chemically reactive, least dense, and softest of the lanthanide elements. It is soft enough to be cut with a knife. Europium was isolated in 1901 and named after the continent of Europe. Europium usually assumes the oxidation state +3, like other members of the lanthanide series, but compounds having oxidation state +2 are also common. All europium compounds with oxidation state +2 are slightly reducing. Europium has no significant biological role and is relatively non-toxic compared to other heavy metals. Most applications of europium exploit the phosphorescence of europium compounds. Europium is one of the rarest of the rare-earth elements on Earth.

<span class="mw-page-title-main">Lanthanum</span> Chemical element, symbol La and atomic number 57

Lanthanum is a chemical element; it has symbol La and atomic number 57. It is a soft, ductile, silvery-white metal that tarnishes slowly when exposed to air. It is the eponym of the lanthanide series, a group of 15 similar elements between lanthanum and lutetium in the periodic table, of which lanthanum is the first and the prototype. Lanthanum is traditionally counted among the rare earth elements. Like most other rare earth elements, the usual oxidation state is +3, although some compounds are known with an oxidation state of +2. Lanthanum has no biological role in humans but is essential to some bacteria. It is not particularly toxic to humans but does show some antimicrobial activity.

The lanthanide or lanthanoid series of chemical elements comprises at least the 14 metallic chemical elements with atomic numbers 57–70, from lanthanum through ytterbium. In the periodic table, they fill the 4f orbitals. Lutetium is also sometimes considered a lanthanide, despite being a d-block element and a transition metal.

<span class="mw-page-title-main">Terbium</span> Chemical element, symbol Tb and atomic number 65

Terbium is a chemical element; it has the symbol Tb and atomic number 65. It is a silvery-white, rare earth metal that is malleable, and ductile. The ninth member of the lanthanide series, terbium is a fairly electropositive metal that reacts with water, evolving hydrogen gas. Terbium is never found in nature as a free element, but it is contained in many minerals, including cerite, gadolinite, monazite, xenotime and euxenite.

<span class="mw-page-title-main">Basalt</span> Magnesium- and iron-rich extrusive igneous rock

Basalt is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron exposed at or very near the surface of a rocky planet or moon. More than 90% of all volcanic rock on Earth is basalt. Rapid-cooling, fine-grained basalt is chemically equivalent to slow-cooling, coarse-grained gabbro. The eruption of basalt lava is observed by geologists at about 20 volcanoes per year. Basalt is also an important rock type on other planetary bodies in the Solar System. For example, the bulk of the plains of Venus, which cover ~80% of the surface, are basaltic; the lunar maria are plains of flood-basaltic lava flows; and basalt is a common rock on the surface of Mars.

<span class="mw-page-title-main">Plagioclase</span> Type of feldspar

Plagioclase ( PLAJ-(ee)-ə-klayss, PLAYJ-, -⁠klayz) is a series of tectosilicate (framework silicate) minerals within the feldspar group. Rather than referring to a particular mineral with a specific chemical composition, plagioclase is a continuous solid solution series, more properly known as the plagioclase feldspar series. This was first shown by the German mineralogist Johann Friedrich Christian Hessel (1796–1872) in 1826. The series ranges from albite to anorthite endmembers (with respective compositions NaAlSi3O8 to CaAl2Si2O8), where sodium and calcium atoms can substitute for each other in the mineral's crystal lattice structure. Plagioclase in hand samples is often identified by its polysynthetic crystal twinning or "record-groove" effect.

<span class="mw-page-title-main">Rare-earth element</span> Any of the fifteen lanthanides plus scandium and yttrium

The rare-earth elements (REE), also called the rare-earth metals or rare earths or, in context, rare-earth oxides, and sometimes the lanthanides, are a set of 17 nearly indistinguishable lustrous silvery-white soft heavy metals. Compounds containing rare earths have diverse applications in electrical and electronic components, lasers, glass, magnetic materials, and industrial processes.

<span class="mw-page-title-main">Anorthite</span> Calcium-rich feldspar mineral

Anorthite (an = not, ortho = straight) is the calcium endmember of the plagioclase feldspar mineral series. The chemical formula of pure anorthite is CaAl2Si2O8. Anorthite is found in mafic igneous rocks. Anorthite is rare on the Earth but abundant on the Moon.

<span class="mw-page-title-main">Bastnäsite</span> Family of minerals

The mineral bastnäsite (or bastnaesite) is one of a family of three carbonate-fluoride minerals, which includes bastnäsite-(Ce) with a formula of (Ce, La)CO3F, bastnäsite-(La) with a formula of (La, Ce)CO3F, and bastnäsite-(Y) with a formula of (Y, Ce)CO3F. Some of the bastnäsites contain OH instead of F and receive the name of hydroxylbastnasite. Most bastnäsite is bastnäsite-(Ce), and cerium is by far the most common of the rare earths in this class of minerals. Bastnäsite and the phosphate mineral monazite are the two largest sources of cerium and other rare-earth elements.

<span class="mw-page-title-main">KREEP</span> Geochemical component of some lunar rocks, potassium, lanthanides, and phosphorus

KREEP, an acronym built from the letters K, REE and P, is a geochemical component of some lunar impact breccia and basaltic rocks. Its most significant feature is somewhat enhanced concentration of a majority of so-called "incompatible" elements and the heat-producing elements, namely radioactive uranium, thorium, and potassium.

<span class="mw-page-title-main">Anorthosite</span> Mafic intrusive igneous rock composed predominantly of plagioclase

Anorthosite is a phaneritic, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic minerals most commonly present.

In petrology and geochemistry, an incompatible element is one that is unsuitable in size and/or charge to the cation sites of the minerals in which it is included. It is defined by a partition coefficient between rock-forming minerals and melt being much smaller than 1.

<span class="mw-page-title-main">Geology of the Moon</span> Structure and composition of the Moon

The geology of the Moon is quite different from that of Earth. The Moon lacks a true atmosphere, and the absence of free oxygen and water eliminates erosion due to weather. Instead, the surface is eroded much more slowly through the bombardment of the lunar surface by micrometeorites. It does not have any known form of plate tectonics, it has a lower gravity, and because of its small size, it cooled faster. In addition to impacts, the geomorphology of the lunar surface has been shaped by volcanism, which is now thought to have ended less than 50 million years ago. The Moon is a differentiated body, with a crust, mantle, and core.

<span class="mw-page-title-main">Moon rock</span> Rocks on or from the Moon

Moon rock or lunar rock is rock originating from Earth's Moon. This includes lunar material collected during the course of human exploration of the Moon, and rock that has been ejected naturally from the Moon's surface and landed on Earth as meteorites.

<span class="mw-page-title-main">Barberton Greenstone Belt</span> Ancient granite-greenstone terrane in South Africa

The Barberton Greenstone Belt is situated on the eastern edge of the Kaapvaal Craton in South Africa. It is known for its gold mineralisation and for its komatiites, an unusual type of ultramafic volcanic rock named after the Komati River that flows through the belt. Some of the oldest exposed rocks on Earth are located in the Barberton Greenstone Belt of the Eswatini–Barberton areas and these contain some of the oldest traces of life on Earth, second only to the Isua Greenstone Belt of Western Greenland. The Makhonjwa Mountains make up 40% of the Baberton belt. It is named after the town Barberton, Mpumalanga.

<span class="mw-page-title-main">Lunar magma ocean</span> Theorized historical geological layer on the Moon

The Lunar Magma Ocean (LMO) is the layer of molten rock that is theorized to have been present on the surface of the Moon. The Lunar Magma Ocean was likely present on the Moon from the time of the Moon's formation to tens or hundreds of millions of years after that time. It is a thermodynamic consequence of the Moon's relatively rapid formation in the aftermath of a giant impact between the proto-Earth and another planetary body. As the Moon accreted from the debris from the giant impact, gravitational potential energy was converted to thermal energy. Due to the rapid accretion of the Moon, thermal energy was trapped since it did not have sufficient time to thermally radiate away energy through the lunar surface. The subsequent thermochemical evolution of the Lunar Magma Ocean explains the Moon's largely anorthositic crust, europium anomaly, and KREEP material.

<span class="mw-page-title-main">Yttrium</span> Chemical element, symbol Y and atomic number 39

Yttrium is a chemical element; it has symbol Y and atomic number 39. It is a silvery-metallic transition metal chemically similar to the lanthanides and has often been classified as a "rare-earth element". Yttrium is almost always found in combination with lanthanide elements in rare-earth minerals and is never found in nature as a free element. 89Y is the only stable isotope and the only isotope found in the Earth's crust.

The cerium anomaly, in geochemistry, is the phenomenon whereby cerium (Ce) concentration is either depleted or enriched in a rock relative to the other rare-earth elements (REEs). A Ce anomaly is said to be "negative" if Ce is depleted relative to the other REEs and is said to be "positive" if Ce is enriched relative to the other REEs.

The Mountain Pass Rare Earth Mine and Processing Facility, owned by MP Materials, is an open-pit mine of rare-earth elements on the south flank of the Clark Mountain Range in California, 53 miles (85 km) southwest of Las Vegas, Nevada. In 2020 the mine supplied 15.8% of the world's rare-earth production. It is the only rare-earth mining and processing facility in the United States.

Appinite is an amphibole-rich plutonic rock of high geochemical variability. Appinites are therefore regarded as a rock series comprising hornblendites, meladiorites, diorites, but also granodiorites and granites. Appinites have formed from magmas very rich in water. They occur in very different geological environments. The ultimate source region of these peculiar rocks is the upper mantle, which was altered metasomatically and geochemically before melting.

References

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