In its most basic form, fuel particles are suspended in a hot, bubbling fluidity bed of ash and other particulate materials (sand, limestone etc.) through which jets of air are blown to provide the oxygen required for combustion or gasification. The resultant fast and intimate mixing of gas and solids promotes rapid heat transfer and chemical reactions within the bed. FBC plants are capable of burning a variety of low-grade solid fuels, including most types of coal, coal waste and woody biomass, at high efficiency and without the necessity for expensive fuel preparation (e.g., pulverising). In addition, for any given thermal duty, FBCs are smaller than the equivalent conventional furnace, so may offer significant advantages over the latter in terms of cost and flexibility.
FBC reduces the amount of sulfur emitted in the form of SOx emissions. Limestone is used to precipitate out sulfate during combustion, which also allows more efficient heat transfer from the boiler to the apparatus used to capture the heat energy (usually water tubes). The heated precipitate coming in direct contact with the tubes (heating by conduction) increases the efficiency. Since this allows coal plants to burn at cooler temperatures, less NOx is also emitted. However, burning at low temperatures also causes increased polycyclic aromatic hydrocarbon emissions. FBC boilers can burn fuels other than coal, and the lower temperatures of combustion (800 °C / 1500 °F) have other added benefits as well.
Benefits
There are two reasons for the rapid increase of FBC in combustors. First, the liberty of choice in respect of fuels in general, not only the possibility of using fuels which are difficult to burn using other technologies, is an important advantage of fluidized bed combustion. The second reason, which has become increasingly important, is the possibility of achieving, during combustion, a low emission of nitric oxides and the possibility of removing sulfur in a simple manner by using limestone as bed material.
blob-bed combustion evolved from efforts to find a combustion process able to control pollutant emissions without external emission controls (such as scrubbers-flue gas desulfurization). The technology burns fuel at temperatures of 1,400 to 1,700 °F (750-900 °C), well below the threshold where nitrogen oxides form (at approximately 2,500 °F / 1400 °C, the nitrogen and oxygenatoms in the combustion air combine to form nitrogen oxide pollutants); it also avoids the ash melting problems related to high combustion temperature. The mixing action of the fluidized bed brings the flue gases into contact with a sulfur-absorbing chemical, such as limestone or dolomite. More than 95% of the sulfur pollutants in coal can be captured inside the boiler by the sorbent. The reductions may be less substantial than they seem, however, as they coincide with dramatic increases in polycyclic aromatic hydrocarbons, and possibly other carbon compound emissions. [citation needed]
Commercial FBC units operate at competitive efficiencies, cost less than today's conventional boiler units, and have SO2 and NO2 emissions below levels mandated by Federal standards. However, they have some disadvantages such as erosion on the tubes inside the boiler, uneven temperature distribution caused by clogs on the air inlet of the bed, long starting times reaching up to 48 hours in some cases.
FBC has a lower combustion temperature of 750 °C whereas an ordinary boiler operates at 850 °C.
FBC has low sintering process (melting of Ash).
Lower production of NOx due to lower temperature.
Lower production of SOx due to capture by limestone.
Higher combustion efficiency due to 10 times more heat transfer than other combustion processes because of burning particle.
Less area is required for FBC due to high coefficient of convective heat transfer.
Iso-thermal bed combustion as temperature in free belt and active belt remain constant.
Types
FBC systems fit into essentially two major groups, atmospheric systems (FBC) and pressurized systems (PFBC), and two minor subgroups, bubbling (BFB) and circulating fluidized bed (CFB).
Atmospheric Fluidized Bed Combustion
Atmospheric fluidized beds use limestone or dolomite to capture sulfur released by the combustion of coal. Jets of air suspend the mixture of sorbent and burning coal during combustion, converting the mixture into a suspension of red-hot particles that flow like a fluid. These boilers operate at atmospheric pressure.
Pressurized Fluidized Bed Combustion
The first-generation PFBC system also uses a sorbent and jets of air to suspend the mixture of sorbent and burning coal during combustion. However, these systems operate at elevated pressures and produce a high-pressure gas stream at temperatures that can drive a gas turbine. Steam generated from the heat in the fluidized bed is sent to a steam turbine, creating a highly efficient combined cycle system.
Advanced PFBC
A 1½ generation PFBC system increases the gas turbine firing temperature by using natural gas in addition to the vitiated air from the PFB combustor. This mixture is burned in a topping combustor to provide higher inlet temperatures for greater combined cycle efficiency. However, this uses natural gas, usually a higher priced fuel than coal.
APFBC. In more advanced second-generation PFBC systems, a pressurized carbonizer is incorporated to process the feed coal into fuel gas and char. The PFBC burns the char to produce steam and to heat combustion air for the gas turbine. The fuel gas from the carbonizer burns in a topping combustor linked to a gas turbine, heating the gases to the combustion turbine's rated firing temperature. Heat is recovered from the gas turbine exhaust in order to produce steam, which is used to drive a conventional steam turbine, resulting in a higher overall efficiency for the combined cycle power output. These systems are also called APFBC, or advanced circulating pressurized fluidized-bed combustion combined cycle systems. An APFBC system is entirely coal-fueled.
GFBCC. Gasification fluidized-bed combustion combined cycle systems, GFBCC, have a pressurized circulating fluidized-bed (PCFB) partial gasifier feeding fuel syngas to the gas turbine topping combustor. The gas turbine exhaust supplies combustion air for the atmospheric circulating fluidized-bed combustor that burns the char from the PCFB partial gasifier.
CHIPPS. A CHIPPS system is similar, but uses a furnace instead of an atmospheric fluidized-bed combustor. It also has gas turbine air preheater tubes to increase gas turbine cycle efficiency. CHIPPS stands for combustion-based high performance power system.
A boiler is a closed vessel in which fluid is heated. The fluid does not necessarily boil. The heated or vaporized fluid exits the boiler for use in various processes or heating applications, including water heating, central heating, boiler-based power generation, cooking, and sanitation.
Gasification is a process that converts biomass- or fossil fuel-based carbonaceous materials into gases, including as the largest fractions: nitrogen (N2), carbon monoxide (CO), hydrogen (H2), and carbon dioxide (CO2). This is achieved by reacting the feedstock material at high temperatures (typically >700 °C), without combustion, via controlling the amount of oxygen and/or steam present in the reaction. The resulting gas mixture is called syngas (from synthesis gas) or producer gas and is itself a fuel due to the flammability of the H2 and CO of which the gas is largely composed. Power can be derived from the subsequent combustion of the resultant gas, and is considered to be a source of renewable energy if the gasified compounds were obtained from biomass feedstock.
The Brayton cycle is a thermodynamic cycle that describes the operation of certain heat engines that have air or some other gas as their working fluid. The original Brayton engines used a piston compressor and piston expander, but modern gas turbine engines and airbreathing jet engines also follow the Brayton cycle. Although the cycle is usually run as an open system, it is conventionally assumed for the purposes of thermodynamic analysis that the exhaust gases are reused in the intake, enabling analysis as a closed system.
A combined cycle power plant is an assembly of heat engines that work in tandem from the same source of heat, converting it into mechanical energy. On land, when used to make electricity the most common type is called a combined cycle gas turbine (CCGT) plant. The same principle is also used for marine propulsion, where it is called a combined gas and steam (COGAS) plant. Combining two or more thermodynamic cycles improves overall efficiency, which reduces fuel costs.
A combustor is a component or area of a gas turbine, ramjet, or scramjet engine where combustion takes place. It is also known as a burner, combustion chamber or flame holder. In a gas turbine engine, the combustor or combustion chamber is fed high-pressure air by the compression system. The combustor then heats this air at constant pressure as the fuel/air mix burns. As it burns the fuel/air mix heats and rapidly expands. The burned mix is exhausted from the combustor through the nozzle guide vanes to the turbine. In the case of a ramjet or scramjet engines, the exhaust is directly fed out through the nozzle.
Flue-gas desulfurization (FGD) is a set of technologies used to remove sulfur dioxide from exhaust flue gases of fossil-fuel power plants, and from the emissions of other sulfur oxide emitting processes such as waste incineration.
A fossil fuel power station is a thermal power station which burns a fossil fuel, such as coal or natural gas, to produce electricity. Fossil fuel power stations have machinery to convert the heat energy of combustion into mechanical energy, which then operates an electrical generator. The prime mover may be a steam turbine, a gas turbine or, in small plants, a reciprocating gas engine. All plants use the energy extracted from the expansion of a hot gas, either steam or combustion gases. Although different energy conversion methods exist, all thermal power station conversion methods have their efficiency limited by the Carnot efficiency and therefore produce waste heat.
Flue gas is the gas exiting to the atmosphere via a flue, which is a pipe or channel for conveying exhaust gases from a fireplace, oven, furnace, boiler or steam generator. Quite often, the flue gas refers to the combustion exhaust gas produced at power plants. Its composition depends on what is being burned, but it will usually consist of mostly nitrogen derived from the combustion of air, carbon dioxide, and water vapor as well as excess oxygen. It further contains a small percentage of a number of pollutants, such as particulate matter, carbon monoxide, nitrogen oxides, and sulfur oxides.
Scrubber systems are a diverse group of air pollution control devices that can be used to remove some particulates and/or gases from industrial exhaust streams. The first air scrubber was designed to remove carbon dioxide from the air of an early submarine, the Ictíneo I, a role for which they continue to be used today. Traditionally, the term "scrubber" has referred to pollution control devices that use liquid to wash unwanted pollutants from a gas stream. Recently, the term has also been used to describe systems that inject a dry reagent or slurry into a dirty exhaust stream to "wash out" acid gases. Scrubbers are one of the primary devices that control gaseous emissions, especially acid gases. Scrubbers can also be used for heat recovery from hot gases by flue-gas condensation. They are also used for the high flows in solar, PV, or LED processes.
A thermal power station is a type of power station in which heat energy is converted to electrical energy. In a steam-generating cycle heat is used to boil water in a large pressure vessel to produce high-pressure steam, which drives a steam turbine connected to an electrical generator. The low-pressure exhaust from the turbine enters a steam condenser where it is cooled to produce hot condensate which is recycled to the heating process to generate more high pressure steam. This is known as a Rankine cycle.
An integrated gasification combined cycle (IGCC) is a technology using a high pressure gasifier to turn coal and other carbon based fuels into pressurized gas—synthesis gas (syngas). It can then remove impurities from the syngas prior to the electricity generation cycle. Some of these pollutants, such as sulfur, can be turned into re-usable byproducts through the Claus process. This results in lower emissions of sulfur dioxide, particulates, mercury, and in some cases carbon dioxide. With additional process equipment, a water-gas shift reaction can increase gasification efficiency and reduce carbon monoxide emissions by converting it to carbon dioxide. The resulting carbon dioxide from the shift reaction can be separated, compressed, and stored through sequestration. Excess heat from the primary combustion and syngas fired generation is then passed to a steam cycle, similar to a combined cycle gas turbine. This process results in improved thermodynamic efficiency compared to conventional pulverized coal combustion.
Co-firing is the combustion of two different types of materials at the same time. One of the advantages of co-firing is that an existing plant can be used to burn a new fuel, which may be cheaper or more environmentally friendly. For example, biomass is sometimes co-fired in existing coal plants instead of new biomass plants. Another example is that biomass primary fuel fractions can be cofired with waste-derived fuels in biomass plants leading to an environmentally friendly destruction of waste fractions and cost-effective heat and power production. Co-firing can also be used to improve the combustion of fuels with low energy content. For example, landfill gas contains a large amount of carbon dioxide, which is non-combustible. If the landfill gas is burned without removing the carbon dioxide, the equipment may not perform properly or emissions of pollutants may increase. Co-firing it with natural gas increases the heat content of the fuel and improves combustion and equipment performance. As long as the electricity or heat produced with the biomass and landfill gas was otherwise going to be produced with non-renewable fuels, the benefits are essentially equivalent whether they are cofired or combusted alone. Also, co-firing can be used to lower the emission of some pollutants. For example, co-firing biomass with coal results in less sulfur emissions than burning coal by itself.
A thermal oxidizer is a process unit for air pollution control in many chemical plants that decomposes hazardous gases at a high temperature and releases them into the atmosphere.
Chemical looping combustion (CLC) is a technological process typically employing a dual fluidized bed system. CLC operated with an interconnected moving bed with a fluidized bed system, has also been employed as a technology process. In CLC, a metal oxide is employed as a bed material providing the oxygen for combustion in the fuel reactor. The reduced metal is then transferred to the second bed and re-oxidized before being reintroduced back to the fuel reactor completing the loop. Fig 1 shows a simplified diagram of the CLC process. Fig 2 shows an example of a dual fluidized bed circulating reactor system and a moving bed-fluidized bed circulating reactor system.
JEA Northside Generating Station in Jacksonville, Florida is a major power plant, one of the three power plants owned and operated by JEA, Jacksonville's municipal utilities service. It produces electricity by burning coal and petroleum coke at Units 1 and 2, formerly the largest circulating fluidized-bed combustors, (CFBs), in the world. These combustors, completed in 2002 and rated at 297.5 megawatts each, produce enough electricity to light more than 250,000 households. In addition, Unit ST3 produces 505 megawatts of electricity by burning residual fuel oil and/or natural gas.
Warrior Run Generating Station, owned by the AES Corporation, is a 205 megawatt cogeneration plant located south of Cumberland, Maryland, at 11600 Mexico Farms Road. In addition to electric power, the plant also produces food-grade carbon dioxide.
The circulating fluidized bed (CFB) is a type of Fluidized bed combustion that utilizes a recirculating loop for even greater efficiency of combustion. while achieving lower emission of pollutants. Reports suggest that up to 95% of pollutants can be absorbed before being emitted into the atmosphere. The technology is limited in scale however, due to its extensive use of limestone, and the fact that it produces waste byproducts.
Calcium looping (CaL), or the regenerative calcium cycle (RCC), is a second-generation carbon capture technology. It is the most developed form of carbonate looping, where a metal (M) is reversibly reacted between its carbonate form (MCO3) and its oxide form (MO) to separate carbon dioxide from other gases coming from either power generation or an industrial plant. In the calcium looping process, the two species are calcium carbonate (CaCO3) and calcium oxide (CaO). The captured carbon dioxide can then be transported to a storage site, used in enhanced oil recovery or used as a chemical feedstock. Calcium oxide is often referred to as the sorbent.
Lower-temperature fuel cell types such as the proton exchange membrane fuel cell, phosphoric acid fuel cell, and alkaline fuel cell require pure hydrogen as fuel, typically produced from external reforming of natural gas. However, fuels cells operating at high temperature such as the solid oxide fuel cell (SOFC) are not poisoned by carbon monoxide and carbon dioxide, and in fact can accept hydrogen, carbon monoxide, carbon dioxide, steam, and methane mixtures as fuel directly, because of their internal shift and reforming capabilities. This opens up the possibility of efficient fuel cell-based power cycles consuming solid fuels such as coal and biomass, the gasification of which results in syngas containing mostly hydrogen, carbon monoxide and methane which can be cleaned and fed directly to the SOFCs without the added cost and complexity of methane reforming, water gas shifting and hydrogen separation operations which would otherwise be needed to isolate pure hydrogen as fuel. A power cycle based on gasification of solid fuel and SOFCs is called an Integrated Gasification Fuel Cell (IGFC) cycle; the IGFC power plant is analogous to an integrated gasification combined cycle power plant, but with the gas turbine power generation unit replaced with a fuel cell power generation unit. By taking advantage of intrinsically high energy efficiency of SOFCs and process integration, exceptionally high power plant efficiencies are possible. Furthermore, SOFCs in the IGFC cycle can be operated so as to isolate a carbon dioxide-rich anodic exhaust stream, allowing efficient carbon capture to address greenhouse gas emissions concerns of coal-based power generation.
The Allam Cycle or Allam-Fetvedt Cycle is a process for converting gaseous fuels into thermal energy, while capturing the generated carbon dioxide and water. This zero emissions cycle was validated at a 50 MWth natural gas fed test facility in La Porte, Texas in May 2018. This industrial plant is owned and operated by NET Power LLC, a privately held technology licensing company. NET Power is owned by Exelon Corporation, McDermott International Ltd, Occidental Petroleum Corporation (Oxy) Low Carbon Ventures, and 8 Rivers Capital. The key inventors behind the process are English engineer Rodney John Allam, American engineer Jeremy Eron Fetvedt, and American scientist Dr. Miles R Palmer. The Allam-Fetvedt Cycle was recognized by MIT Technology Review on the 2018 list of 10 Breakthrough Technologies.
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