Names | |
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Preferred IUPAC name 2,4,6-Trinitro-N-(2,4,6-trinitrophenyl)aniline | |
Other names bis(2,4,6-Trinitrophenyl)amine HNDA HNDPA Dipicrylamine Hexamine Hexil Hexyl Hexite Hexamin | |
Identifiers | |
3D model (JSmol) | |
ChemSpider | |
ECHA InfoCard | 100.004.581 |
EC Number |
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PubChem CID | |
UNII | |
CompTox Dashboard (EPA) | |
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Properties | |
C12H5N7O12 | |
Molar mass | 439.209 g·mol−1 |
Appearance | Crystalline solid. Yellow to orange. As ordinarily manufactured, it is yellow brown. |
Density | 1.64 g/cm3 (pressed) |
Melting point | 243 to 245 °C; 469 to 473 °F; 516 to 518 K with decomposition |
Soluble in acetone, warm glacial acetic acid, nitric acid, or aqueous alkalies except potassium hydroxide. | |
Explosive data | |
Detonation velocity | 7100 m/s |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). |
Hexanitrodiphenylamine (abbreviated HND), is an explosive chemical compound with the formula C12H5N7O12. HND was used extensively by the Japanese during World War II but was discontinued due to its toxicity.
Dinitrodiphenylamine is treated with 98% nitric acid. The starting material, dinitrodiphenylamine, is obtained from the reaction of aniline, dinitrochlorobenzene, and soda ash.
HND is a booster-class explosive that was used in World War II by the Germans as a component of Hexanite (60% TNT - 40% HND) and by the Japanese as a component of Kongo (Type 98 H2) (60% Trinitroanisole - 40% HND) for use in bombs, sea mines and depth charges; Seigate (Type 97 H) (60% TNT - 40% HND) for use in torpedo warheads and depth charges; and also in Otsu-B (60% TNT, 24% HND & 16% aluminium powder) for use in torpedo warheads.
Its ammonium salt, also known as Aurantia or Imperial Yellow, was discovered in 1873 by Emil Kopp and used as a yellow colorant for leather, wool and silk in the 19th and early 20th centuries. [1]
A most toxic and poisonous explosive, it attacks the skin, causing blisters which resemble burns. Dust from HND is injurious to the mucous membranes of the mouth, nose, and lungs. Several nitroaromatic explosives, including HND, have been found to be mutagens. [2]
On 12 May 2022, construction of the Bundesautobahn 49 in Germany was halted, after traces of the explosive were found in the excavated material. The road passes over a former explosives factory near Stadtallendorf. The factory had been demolished after World War II, and it was not expected that traces of explosives had remained in the ground. [3]
RDX (abbreviation of "Research Department eXplosive") or hexogen, among other names, is an organic compound with the formula (O2N2CH2)3. It is white, odorless and tasteless, widely used as an explosive. Chemically, it is classified as a nitroamine alongside HMX, which is a more energetic explosive than TNT. It was used widely in World War II and remains common in military applications.
A naval mine is a self-contained explosive device placed in water to damage or destroy surface ships or submarines. Unlike depth charges, mines are deposited and left to wait until they are triggered by the approach of, or contact with, any vessel or a particular vessel type, akin to anti-infantry or anti-vehicle mines. Naval mines can be used offensively, to hamper enemy shipping movements or lock vessels into a harbour; or defensively, to protect friendly vessels and create "safe" zones. Mines allow the minelaying force commander to concentrate warships or defensive assets in mine-free areas giving the adversary three choices: undertake an expensive and time-consuming minesweeping effort, accept the casualties of challenging the minefield, or use the unmined waters where the greatest concentration of enemy firepower will be encountered.
A depth charge is an anti-submarine warfare (ASW) weapon. It is intended to destroy a submarine by being dropped into the water nearby and detonating, subjecting the target to a powerful and destructive hydraulic shock. Most depth charges use high explosive charges and a fuze set to detonate the charge, typically at a specific depth. Depth charges can be dropped by ships, patrol aircraft, and helicopters.
Bomb disposal is an explosives engineering profession using the process by which hazardous explosive devices are disabled or otherwise rendered safe. Bomb disposal is an all-encompassing term to describe the separate, but interrelated functions in the military fields of explosive ordnance disposal (EOD) and improvised explosive device disposal (IEDD), and the public safety roles of public safety bomb disposal (PSBD) and the bomb squad.
Amatol is a highly explosive material made from a mixture of TNT and ammonium nitrate. The British name originates from the words ammonium and toluene. Similar mixtures were known as Schneiderite in France. Amatol was used extensively during World War I and World War II, typically as an explosive in military weapons such as aircraft bombs, shells, depth charges, and naval mines. It was eventually replaced with alternative explosives such as Composition B, Torpex, and Tritonal.
A shell, in a military context, is a projectile whose payload contains an explosive, incendiary, or other chemical filling. Originally it was called a bombshell, but "shell" has come to be unambiguous in a military context. A shell can hold a tracer.
A smoke grenade is a canister-type grenade used as a signaling device, target or landing zone marking device, or as a screening device for unit movements.
The Hedgehog was a forward-throwing anti-submarine weapon that was used primarily during the Second World War. The device, which was developed by the Royal Navy, fired up to 24 spigot mortars ahead of a ship when attacking a U-boat. It was deployed on convoy escort warships such as destroyers and corvettes to supplement the depth charges.
Torpex is a secondary explosive, 50% more powerful than TNT by mass. Torpex comprises 42% RDX, 40% TNT and 18% powdered aluminium. It was used in the Second World War from late 1942, at which time some used the names Torpex and RDX interchangeably, much to the confusion of today's historical researchers. Torpex proved to be particularly useful in underwater munitions because the aluminium component had the effect of making the explosive pulse last longer, which increased the destructive power. Besides torpedoes, naval mines, and depth charges, Torpex was only used in the Upkeep, Tallboy and Grand Slam bombs as well as the drones employed in Operation Aphrodite. Torpex has long been superseded by H6 and Polymer-bonded explosive (PBX) compositions. It is therefore regarded as obsolete and Torpex is unlikely to be encountered except in old munitions or unexploded ordnance, although a notable exception to this is the Sting Ray lightweight torpedo, which as of October 2020 remains in service with the Royal Navy and several foreign militaries. The German equivalent of Torpex was Trialen.
High Blast Explosive, or HBX, is an explosive used as a bursting charge in missile warheads, mines, depth bombs, depth charges, and torpedoes.
There have been many extremely large explosions, accidental and intentional, caused by modern high explosives, boiling liquid expanding vapour explosions (BLEVEs), older explosives such as gunpowder, volatile petroleum-based fuels such as gasoline, and other chemical reactions. This list contains the largest known examples, sorted by date. An unambiguous ranking in order of severity is not possible; a 1994 study by historian Jay White of 130 large explosions suggested that they need to be ranked by an overall effect of power, quantity, radius, loss of life and property destruction, but concluded that such rankings are difficult to assess.
Anti-submarine warfare is a branch of underwater warfare that uses surface warships, aircraft, submarines, or other platforms, to find, track, and deter, damage, or destroy enemy submarines. Such operations are typically carried out to protect friendly shipping and coastal facilities from submarine attacks and to overcome blockades.
According to researcher Chuck Hansen, the W34 Python was a gas-boosted fission primary used in several designs of American thermonuclear weapons.
Minol is a military explosive developed by the Admiralty early in the Second World War to augment supplies of trinitrotoluene (TNT) and RDX, which were in short supply. The aluminium component in Minol significantly prolongs the explosive pulse, making it ideal for use in underwater naval weapons where munitions with a longer explosive pulse are more destructive than those with high brisance. Minol cannot be used in weapons fired from gun barrels because there is a risk of detonation when subjected to over 250 gs of acceleration. Initially, three Minol formulas were used. All percentages shown are by weight:
Hexanite was a castable German military explosive developed early in the 20th century before the First World War for the Kaiserliche Marine, intended to augment supplies of trinitrotoluene (TNT), which were then in short supply. Hexanite is slightly less powerful than TNT on its own. The most common hexanite formula was 60% TNT and 40% hexanitrodiphenylamine.
Ammunition is the material fired, scattered, dropped, or detonated from any weapon or weapon system. Ammunition is both expendable weapons and the component parts of other weapons that create the effect on a target.
In military munitions, a fuze is the part of the device that initiates function. In some applications, such as torpedoes, a fuze may be identified by function as the exploder. The relative complexity of even the earliest fuze designs can be seen in cutaway diagrams.
The SC 1000 or cylindrical explosive bomb was a large air-dropped general-purpose thin-cased high explosive demolition bomb used by Germany during World War II. Weighing more than 1,000 kg (2,200 lb), it was nicknamed the Hermann by the Germans in reference to the Luftwaffe commander, Hermann Göring.
During the Second World War, the Luftwaffe developed a series of unguided rocket-propelled armor-piercing bombs. The three main types were the PC 500 Rs, PC 1000 Rs, and PC 1800 Rs. PC from Panzersprengbombe Cylindrisch the number from the approximate weight of the bomb in kilograms, and Rs meaning rocket propelled. These bombs were intended to be used against armored ships or similar targets. The purpose of the rocket propulsion was to increase the terminal velocity of the bomb and aid penetration.
The AB 250-2(Abwurfbehälter) was a cluster bomb used by the Luftwaffe during World War II.