Organic-rich sedimentary rocks

Last updated

Organic-rich sedimentary rocks are a specific type of sedimentary rock that contains significant amounts (>3%) of organic carbon. [1] [2] The most common types include coal, lignite, oil shale, or black shale. [2] The organic material may be disseminated throughout the rock giving it a uniform dark color, and/or it may be present as discrete occurrences of tar, bitumen, asphalt, petroleum, coal or carbonaceous material. Organic-rich sedimentary rocks may act as source rocks which generate hydrocarbons that accumulate in other sedimentary "reservoir" rocks [2] (see oil sands and petroleum geology). Potential source rocks are any type of sedimentary rock that the ability to dispel available carbon from within it (limestone is a classic example of a source rock). Good reservoir rocks are any sedimentary rock that has high pore-space availability. This allows the hydrocarbons to accumulate within the rock and be stored for long periods of time (a sandstone commonly makes a good source rock). Highly permeable reservoir rocks are also of interest to industry professionals, as they allow for the easy extraction of the hydrocarbons within. The hydrocarbon reservoir system is not complete however without a "cap rock". Cap rocks are rock units which have very low porosity and permeability, which trap the hydrocarbons within the units below as they try to migrate upwards.

Contents

Fossil organic carbon

Organic carbon is derived from ancient biological deposition of matter (kerogen is the name given to this by geologists), and this organic matter is buried with mineral and rock fragments into sedimentary rocks. [2] [3] The temperature and pressure of the burial conditions will affect the material's diagenetic processes, and determine whether or not the material will be transformed into petroleum. Fossiliferous organic carbon can alI BE sported throughout the modern environment, in rivers, soils, and eventually the oceans. This process occurs over a very large time scale, and acts as one of the major mechanisms for fossiliferous organic carbon to be released back into the environment.

Organic sediment production

For decades, it was thought that the majority of the organic-rich sedimentary beds deposited on the ocean floor was a byproduct of three environmental variables: the input of organic material, the rate of sedimentation, and the amount of deep-water oxygenation. These variables are linked on spatial and temporal scales by climate, ocean currents, and sea-level at the time of deposition. [2] [4] Any changes in the variables or the parameters that link them will result in different sedimentary deposits, as seen on the surface today. Knowledge of this information is valued among commercial companies, as its application can deduce which sedimentary deposits could be economically productive to exploit. By using the inverse of the previous methodology, these deposits can be used as proxies to infer information such as paleoclimate, previous ocean circulation cycles, past sea-levels, as well as the proportion of variables with relation to one another that caused the production of the deposit. [2] This information can be very valuable to geoscientists, as it can help them reconstruct past processes that ultimately shaped the Earth to form its present state.

However, based upon more recent research, these outcomes are no longer completely viable. For example: In case studies of the Black Sea, a modern anoxic environment, it has been shown that anoxia within the lower-levels of the water column alone do not produce significant amount of organic-rich sediments, even though sufficient organic material was supplied to the region in the Holocene. Therefore, the new theory is that "primary producers" higher in the water column are responsible for the majority of the deposition of carbon-rich sediment in continental margin environments. [2] Based upon a study conducted involving ocean-circulation models in the Cretaceous, it was found that although conditions were relatively similar to those today, the oceans had much harsher currents that influenced the water column. [5] The new thought is that these ocean currents were slowed by blooms of microscopic marine primary producers, which allowed for the settlement of organic-rich sediments at the seafloor, producing many of the economically productive black shale beds that are present today. To this day it remains an intensely researched subject by scholars and commercial companies alike.

Role of bacteria in organic-rich sedimentary rocks

Bacteria are thought to be an important contributor to the creation of petroleum source rock. However, studies have shown that abundances of bacterial biomarkers do not always reflect relative contributions to sedimentary organic carbon. [6] Bacteria in sedimentary rocks are now thought to only have minor contributions to the production of fossil fuels such as oil. As bacterial reworking of sedimentary debris is extremely important, its significance cannot be ignored. Certain bacteria can assist in the breaking down of organic material early in the sedimentary processes, although bacterial biomass itself may represent only a minor component of the total organic carbon in carbonaceous rocks. Many of the ideas of minimal bacterial contribution can be attributed to isotopic studies of the carbon in some sedimentary rocks.[ citation needed ] Studies of many and varied sedimentary sites are required to come to such conclusions; there are myriad bacterial species, and each organic source rock may have differing interactions with these bacteria. This is why not all bacterial influenced addition of carbon to sedimentary rocks can be excluded: each situation is unique, with varying bacteria, and varying settings. The combination of microscopic and molecular studies should be addressed when interpreting abundances of bacterial biomarkers present in a petroleum source and its influence on the total organic carbon.

Related Research Articles

<span class="mw-page-title-main">Limestone</span> Sedimentary rocks made of calcium carbonate

Limestone is a type of carbonate sedimentary rock which is the main source of the material lime. It is composed mostly of the minerals calcite and aragonite, which are different crystal forms of CaCO3. Limestone forms when these minerals precipitate out of water containing dissolved calcium. This can take place through both biological and nonbiological processes, though biological processes, such as the accumulation of corals and shells in the sea, have likely been more important for the last 540 million years. Limestone often contains fossils which provide scientists with information on ancient environments and on the evolution of life.

<span class="mw-page-title-main">Shale</span> Fine-grained, clastic sedimentary rock

Shale is a fine-grained, clastic sedimentary rock formed from mud that is a mix of flakes of clay minerals (hydrous aluminium phyllosilicates, e.g. kaolin, Al2Si2O5(OH)4) and tiny fragments (silt-sized particles) of other minerals, especially quartz and calcite. Shale is characterized by its tendency to split into thin layers (laminae) less than one centimeter in thickness. This property is called fissility. Shale is the most common sedimentary rock.

<span class="mw-page-title-main">Sedimentary rock</span> Rock formed by the deposition and subsequent cementation of material

Sedimentary rocks are types of rock that are formed by the accumulation or deposition of mineral or organic particles at Earth's surface, followed by cementation. Sedimentation is the collective name for processes that cause these particles to settle in place. The particles that form a sedimentary rock are called sediment, and may be composed of geological detritus (minerals) or biological detritus. The geological detritus originated from weathering and erosion of existing rocks, or from the solidification of molten lava blobs erupted by volcanoes. The geological detritus is transported to the place of deposition by water, wind, ice or mass movement, which are called agents of denudation. Biological detritus was formed by bodies and parts of dead aquatic organisms, as well as their fecal mass, suspended in water and slowly piling up on the floor of water bodies. Sedimentation may also occur as dissolved minerals precipitate from water solution.

<span class="mw-page-title-main">Chert</span> Hard, fine-grained sedimentary rock composed of cryptocrystalline silica

Chert is a hard, fine-grained sedimentary rock composed of microcrystalline or cryptocrystalline quartz, the mineral form of silicon dioxide (SiO2). Chert is characteristically of biological origin, but may also occur inorganically as a chemical precipitate or a diagenetic replacement, as in petrified wood.

Petroleum geology is the study of origin, occurrence, movement, accumulation, and exploration of hydrocarbon fuels. It refers to the specific set of geological disciplines that are applied to the search for hydrocarbons.

Sedimentology encompasses the study of modern sediments such as sand, silt, and clay, and the processes that result in their formation, transport, deposition and diagenesis. Sedimentologists apply their understanding of modern processes to interpret geologic history through observations of sedimentary rocks and sedimentary structures.

<span class="mw-page-title-main">Kerogen</span> Solid organic matter in sedimentary rocks

Kerogen is solid, insoluble organic matter in sedimentary rocks. Comprising an estimated 1016 tons of carbon, it is the most abundant source of organic compounds on earth, exceeding the total organic content of living matter 10,000-fold. It is insoluble in normal organic solvents and it does not have a specific chemical formula. Upon heating, kerogen converts in part to liquid and gaseous hydrocarbons. Petroleum and natural gas form from kerogen. Kerogen may be classified by its origin: lacustrine (e.g., algal), marine (e.g., planktonic), and terrestrial (e.g., pollen and spores). The name "kerogen" was introduced by the Scottish organic chemist Alexander Crum Brown in 1906, derived from the Greek for "wax birth" (Greek: κηρός "wax" and -gen, γένεση "birth").

The abiogenic petroleum origin proposes that most of earth's petroleum and natural gas deposits were formed inorganically. Mainstream theories about the formation of hydrocarbons on earth point to an origin from the decomposition of long-dead organisms, though the existence of hydrocarbons on extraterrestrial bodies like Saturn's moon Titan indicates that hydrocarbons are sometimes naturally produced by inorganic means. A historical overview of theories of the abiogenic origins of hydrocarbons has been published.

<span class="mw-page-title-main">Anoxic event</span> Historic oxygen depletion events in Earths oceans

Oceanic anoxic events or anoxic events (anoxia conditions) describe periods wherein large expanses of Earth's oceans were depleted of dissolved oxygen (O2), creating toxic, euxinic (anoxic and sulfidic) waters. Although anoxic events have not happened for millions of years, the geologic record shows that they happened many times in the past. Anoxic events coincided with several mass extinctions and may have contributed to them. These mass extinctions include some that geobiologists use as time markers in biostratigraphic dating. On the other hand, there are widespread, various black-shale beds from the mid-Cretaceous which indicate anoxic events but are not associated with mass extinctions. Many geologists believe oceanic anoxic events are strongly linked to the slowing of ocean circulation, climatic warming, and elevated levels of greenhouse gases. Researchers have proposed enhanced volcanism (the release of CO2) as the "central external trigger for euxinia."

<span class="mw-page-title-main">Sulfur cycle</span> Biogeochemical cycle of sulfur

The sulfur cycle is a biogeochemical cycle in which the sulfur moves between rocks, waterways and living systems. It is important in geology as it affects many minerals and in life because sulfur is an essential element (CHNOPS), being a constituent of many proteins and cofactors, and sulfur compounds can be used as oxidants or reductants in microbial respiration. The global sulfur cycle involves the transformations of sulfur species through different oxidation states, which play an important role in both geological and biological processes. Steps of the sulfur cycle are:

<span class="mw-page-title-main">Mudrock</span> Class of fine grained siliciclastic sedimentary rocks

Mudrocks are a class of fine-grained siliciclastic sedimentary rocks. The varying types of mudrocks include siltstone, claystone, mudstone, slate, and shale. Most of the particles of which the stone is composed are less than 116 mm and are too small to study readily in the field. At first sight, the rock types appear quite similar; however, there are important differences in composition and nomenclature.

In petroleum geology, source rock is rock which has generated hydrocarbons or which could generate hydrocarbons. Source rocks are one of the necessary elements of a working petroleum system. They are organic-rich sediments that may have been deposited in a variety of environments including deep water marine, lacustrine and deltaic. Oil shale can be regarded as an organic-rich but immature source rock from which little or no oil has been generated and expelled. Subsurface source rock mapping methodologies make it possible to identify likely zones of petroleum occurrence in sedimentary basins as well as shale gas plays.

<span class="mw-page-title-main">Shallow water marine environment</span>

Shallow water marine environment refers to the area between the shore and deeper water, such as a reef wall or a shelf break. This environment is characterized by oceanic, geological and biological conditions, as described below. The water in this environment is shallow and clear, allowing the formation of different sedimentary structures, carbonate rocks, coral reefs, and allowing certain organisms to survive and become fossils.

<span class="mw-page-title-main">Pyrobitumen</span> Type of solid, amorphous organic matter

Pyrobitumen is a type of solid, amorphous organic matter. Pyrobitumen is mostly insoluble in carbon disulfide and other organic solvents as a result of molecular cross-linking, which renders previously soluble organic matter insoluble. Not all solid bitumens are pyrobitumens, in that some solid bitumens are soluble in common organic solvents, including CS
2
, dichloromethane, and benzene-methanol mixtures.

<span class="mw-page-title-main">Persian Gulf Basin</span>

The Persian Gulf Basin is found between the Eurasian and the Arabian Plate. The Persian Gulf is described as a shallow marginal sea of the Indian Ocean that is located between the south western side of Iran and the Arabian Peninsula and south and southeastern side of Oman and the United Arab Emirates. Other countries that border the Persian Gulf basin include; Saudi Arabia, Qatar, Kuwait, Bahrain and Iraq. The Persian Gulf extends a distance of 1,000 km (620 mi) with an area of 240,000 km2 (93,000 sq mi). The Persian Gulf basin is a wedge-shaped foreland basin which lies beneath the western Zagros thrust and was created as a result of the collision between the Arabian and Eurasian plates.

<span class="mw-page-title-main">Tarfaya Basin</span>

The Tarfaya Basin is a structural basin located in southern Morocco that extends westward into the Moroccan territorial waters in the Atlantic Ocean. The basin is named for the city of Tarfaya located near the border of Western Sahara, a region governed by the Kingdom of Morocco. The Canary Islands form the western edge of the basin and lie approximately 100 km to the west.

<span class="mw-page-title-main">Delta Field (Niger Delta)</span>

The Delta Field is located offshore from Nigeria on Oil Mining Leases (OML) 49 and 95. This is located within the Niger Delta Basin and sits in 12 feet of water. In 1965, the Delta 1 well was completed and the Delta Field opened in 1968 for production.

Bituminite is an autochthonous maceral that is a part of the liptinite group in lignite, that occurs in petroleum source rocks originating from organic matter such as algae which has undergone alteration or degradation from natural processes such as burial. It occurs as fine-grained groundmass, laminae or elongated structures that appear as veinlets within horizontal sections of lignite and bituminous coals, and also occurs in sedimentary rocks. Its occurrence in sedimentary rocks is typically found surrounding alginite, and parallel along bedding planes. Bituminite is not considered to be bitumen because its properties are different from most bitumens. It is described to have no definite shape or form when present in bedding and can be identified using different kinds of visible and fluorescent lights. There are three types of bituminite: type I, type II and type III, of which type I is the most common. The presence of bituminite in oil shales, other oil source rocks and some coals plays an important factor when determining potential petroleum-source rocks.

<span class="mw-page-title-main">Greater Green River Basin</span> River basin in southwestern Wyoming, United States

The Greater Green River Basin (GGRB) is a 21,000 square mile basin located in Southwestern Wyoming. The Basin was formed during the Cretaceous period sourced by underlying Permian and Cretaceous deposits. The GGRB is host to many anticlines created during the Laramide Orogeny trapping many of its hydrocarbon resources. It is bounded by the Rawlins Uplift, Uinta Mountains, Sevier overthrust belt, Sierra Madre Mountains, and the Wind River Mountain Range. The Greater Green River Basin is subdivided into four smaller basins, the Green River Basin, Great Divide Basin, Washakie Basin, and Sand Wash Basin. Each of these possesses hydrocarbons that have been economically exploited. There are 303 named fields throughout the basin, the majority of which produce natural gas; the largest of these gas fields is the Jonah Field.

The Officer Basin is an intracratonic sedimentary basin that covers roughly 320,000 km2 along the border between southern and western Australia. Exploration for hydrocarbons in this basin has been sparse, but the geology has been examined for its potential as a hydrocarbon reservoir. This basin's extensive depositional history, with sedimentary thicknesses exceeding 6 km and spanning roughly 350 Ma during the Neoproterozoic, make it an ideal candidate for hydrocarbon production.

References

[7] [8] [9] [10] [11]

  1. Boggs, S., 2006, Principles of Sedimentology and Stratigraphy (4th), Pearson Prentice Hall, Upper Saddle River, N.J., p. 662
  2. 1 2 3 4 5 6 7 Ferriday, Tim; Montenari, Michael (2016). "Chemostratigraphy and Chemofacies of Source Rock Analogues: A High-Resolution Analysis of Black Shale Successions from the Lower Silurian Formigoso Formation (Cantabrian Mountains, NW Spain)". Stratigraphy & Timescales. 1: 123–255. doi:10.1016/bs.sats.2016.10.004 via Elsevier Science Direct.
  3. Copard, Y., Amiotte-Suchet, P., Di-Giovanni, C.., (2007) Storage and release of fossil organic carbon related to weathering of sedimentary rocks. Earth and Planetary Science. Vol. 258. pp. 345–357.
  4. Arthur, M.A., Dean, W.E., Stow, D.A.V., 1984, Models for the deposition of Mesozoic-Cenozoic fine-grained organic-carbon-rich sediment in the deep sea, The Geological Society, 15, pp. 527–560
  5. Pederson T.F., Calvert, S.E., 1990, Anoxia vs. Productivity: What Controls the Formation of Organic-Carbon-Rich Sediments and Sedimentary Rocks?, The American Association of Petroleum Geologists Bulletin, 74(4), pp. 454–466
  6. Hartgers, W.A., Damste, J. S. S., Requejo, A.G., Allan, J., Hayes, J.M., de Leeuw, J.W. (1994). Evidence for only minor contributions from bacteria to sedimentary organic carbon. Nature. Vol. 369. p. 224.
  7. Bushnev, D.A., Shchepetova, E.V., Lyyurov, S.V.., (2005) Organic Geochemistry of Oxfordian Carbon-rich Sedimentary Rocks of the Russian Plate. Lithology and Mineral Resources. Vol. 41. pp. 423–434.
  8. Akinlua, A. Torto, N. (2010) Geochemical evaluation of Niger Delta sedimentary organic rocks: a new insight. International Journal of Earth Science. Vol. 100. pp.1401–1410.
  9. Runnegar, B., 1991, Precambrian oxygen levels estimated from the biochemistry and physiology of early eukaryotes, pp. 97, 97–111
  10. Hamilton T.L., Bryant D.A., Macalady J.L., 2016, The role of biology in planetary evolution: cyanobacterial primary production in low-oxygen Proterozoic oceans, Environmental Microbiology, 18(2),pp. 325–340
  11. Sancetta, C., 1992, Primary production in the glacial North Atlantic and North Pacific oceans, Nature, 360, pp. 249–251