Osumilite

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Osumilite
Osumilite tablets with Mullite - Ochtendung, Eifel, Germany.jpg
Osumilite tablets with mullite from Ochtendung, Eifel, Germany.
General
Category Cyclosilicate
Formula
(repeating unit)
(K,Na)(Fe,Mg)2(Al,Fe)3(Si,Al)12O30
IMA symbol Osm [1]
Strunz classification 9.CM.05
Dana classification63.02.01a.06
Crystal system Hexagonal
Crystal class Dihexagonal dipyramidal (6mmm)
H-M symbol: (6/m 2/m 2/m)
Space group P6/mcc
Unit cell a = 10.15, c = 14.25 [Å]; Z = 2
Identification
ColorBlack, dark blue, dark brown, pink, gray
Crystal habit Crystals tabular to prismatic also anhedral and massive
Twinning Rarely
Cleavage None
Fracture Subconchoidal
Mohs scale hardness5 - 6
Luster Vitreous
Streak Blue-gray
Diaphaneity Translucent
Specific gravity 2.62 - 2.64
Optical propertiesUniaxial (+) anomalously biaxial
Refractive index w=1.545-1.547, e=1.549-1.551
Birefringence 0.004
Pleochroism Strong
References [2] [3] [4]

Osumilite is a very rare potassium-sodium-iron-magnesium-aluminium silicate mineral. Osumilite is part of the milarite group (also known as the milarite-osumilite group) of cyclosilicates.

Contents

Characteristics

Osumilite chemical formula is (K,Na)(Fe,Mg)2(Al,Fe)3(Si,Al)12 O 30. [5] [6] It is translucent and the typical coloring is either blue, black, brown, or gray. It displays no cleavage and has a vitreous luster. Osumilite has a hardness between 5-6 on the Mohs hardness scale. [4]

The hexagonal crystal structure of osumilite is an unusual molecular make-up. The primary unit is a double ring, with a formula of Si12O30. Normal cyclosilicate have rings composed of six silicate tetrahedrons; Si6O18. In a double ring structure, two normal rings are linked by sharing six oxygens, one from each tetrahedron in each six membered ring. [7]

Occurrence

Osumilite, was first discovered as grains in volcanic rocks near Osumi, Japan. It was confused with a similar mineral cordierite because of their similar coloring. It can be found in high-grade metamorphic rocks, xenoliths and in the groundmass of rhyolite and dacite. [3]

Osumilite is found in the Obsidian Cliffs, Oregon; Sardinia, Italy; Kagoshima and Yamanashi Prefecture, Japan; and the Eifel district in Germany. [3] Osumilite pseudomorphs are known from a number of ultrahigh-temperature rocks, including those of southern Madagascar.

See also

Related Research Articles

<span class="mw-page-title-main">Mineral</span> Crystalline chemical element or compound formed by geologic processes

In geology and mineralogy, a mineral or mineral species is, broadly speaking, a solid chemical compound with a fairly well-defined chemical composition and a specific crystal structure that occurs naturally in pure form.

<span class="mw-page-title-main">Hornblende</span> Complex inosilicate series of minerals

Hornblende is a complex inosilicate series of minerals. It is not a recognized mineral in its own right, but the name is used as a general or field term, to refer to a dark amphibole. Hornblende minerals are common in igneous and metamorphic rocks.

<span class="mw-page-title-main">Actinolite</span>

Actinolite is an amphibole silicate mineral with the chemical formula Ca2(Mg4.5-2.5Fe2+0.5-2.5)Si8O22(OH)2.

<span class="mw-page-title-main">Sekaninaite</span> Mg, Fe, Al cyclosilicate mineral

Sekaninaite ((Fe+2,Mg)2Al4Si5O18) is a silicate mineral, the iron-rich analogue of cordierite.

<span class="mw-page-title-main">Cordierite</span> Mg, Fe, Al cyclosilicate mineral

Cordierite (mineralogy) or iolite (gemology) is a magnesium iron aluminium cyclosilicate. Iron is almost always present and a solid solution exists between Mg-rich cordierite and Fe-rich sekaninaite with a series formula: (Mg,Fe)2Al3(Si5AlO18) to (Fe,Mg)2Al3(Si5AlO18). A high-temperature polymorph exists, indialite, which is isostructural with beryl and has a random distribution of Al in the (Si,Al)6O18 rings.

<span class="mw-page-title-main">Silicate mineral</span> Rock-forming minerals with predominantly silicate anions

Silicate minerals are rock-forming minerals made up of silicate groups. They are the largest and most important class of minerals and make up approximately 90 percent of Earth's crust.

<span class="mw-page-title-main">Glaucophane</span>

Glaucophane is the name of a mineral and a mineral group belonging to the sodic amphibole supergroup of the double chain inosilicates, with the chemical formula ☐Na2(Mg3Al2)Si8O22(OH)2.

<span class="mw-page-title-main">Cummingtonite</span> Silicate mineral

Cummingtonite is a metamorphic amphibole with the chemical composition (Mg,Fe2+
)
2
(Mg,Fe2+
)
5
Si
8
O
22
(OH)
2
, magnesium iron silicate hydroxide.

<span class="mw-page-title-main">Illite</span> Group of related non-expanding clay minerals

Illite is a group of closely related non-expanding clay minerals. Illite is a secondary mineral precipitate, and an example of a phyllosilicate, or layered alumino-silicate. Its structure is a 2:1 sandwich of silica tetrahedron (T) – alumina octahedron (O) – silica tetrahedron (T) layers. The space between this T-O-T sequence of layers is occupied by poorly hydrated potassium cations which are responsible for the absence of swelling. Structurally, illite is quite similar to muscovite with slightly more silicon, magnesium, iron, and water and slightly less tetrahedral aluminium and interlayer potassium. The chemical formula is given as (K,H3O)(Al,Mg,Fe)2(Si,Al)4O10[(OH)2·(H2O)], but there is considerable ion (isomorphic) substitution. It occurs as aggregates of small monoclinic grey to white crystals. Due to the small size, positive identification usually requires x-ray diffraction or SEM-EDS analysis. Illite occurs as an altered product of muscovite and feldspar in weathering and hydrothermal environments; it may be a component of sericite. It is common in sediments, soils, and argillaceous sedimentary rocks as well as in some low grade metamorphic rocks. The iron-rich member of the illite group, glauconite, in sediments can be differentiated by x-ray analysis.

<span class="mw-page-title-main">Chloritoid</span>

Chloritoid is a silicate mineral of metamorphic origin. It is an iron magnesium manganese alumino-silicate hydroxide with formula (Fe, Mg, Mn)
2
Al
4
Si
2
O
10
(OH)
4
. It occurs as greenish grey to black platy micaceous crystals and foliated masses. Its Mohs hardness is 6.5, unusually high for a platy mineral, and it has a specific gravity of 3.52 to 3.57. It typically occurs in phyllites, schists and marbles.

<span class="mw-page-title-main">Kornerupine</span>

Kornerupine (also called Prismatine) is a rare boro-silicate mineral with the chemical formula (Mg,Fe2+)4(Al,Fe3+)6(SiO4,BO4)5(O,OH)2. It crystallizes in the orthorhombic - dipyramidal crystal system as brown, green, yellow to colorless slender tourmaline like prisms or in massive fibrous forms. It has a Mohs hardness of 7 and a specific gravity of 3.3 to 3.34. Its indices of refraction are nα=1.660 - 1.671, nβ=1.673 - 1.683 and nγ=1.674 - 1.684.

<span class="mw-page-title-main">Pabstite</span>

Pabstite is a barium tin titanium silicate mineral that is found in contact metamorphosed limestone. It belongs to the benitoite group of minerals. The chemical formula of pabstite is Ba(Sn,Ti)Si3O9. It is found in Santa Cruz, California. The crystal system of the mineral is hexagonal.

<span class="mw-page-title-main">Tschermakite</span> Amphibole, double chain inosilicate mineral

The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.

Zussmanite is a hydrated iron-rich silicate mineral with the chemical formula K(Fe2+,Mg,Mn)13[AlSi17O42](OH)14. It occurs as pale green crystals with perfect cleavage.

Almarudite is an extremely rare alkaline manganese beryllium silicate mineral of the cyclosilicates class, with the chemical formula K([ ],Na)2(Mn2+,Fe2+,Mg)2(Be,Al)3[Si12O30], from the volcanic environment of the Eifel Mountains in Germany.

<span class="mw-page-title-main">Fluor-liddicoatite</span>

Fluor-liddicoatite is a rare member of the tourmaline group of minerals, elbaite subgroup, and the theoretical calcium endmember of the elbaite-fluor-liddicoatite series; the pure end-member has not yet been found in nature. Fluor-liddicoatite is indistinguishable from elbaite by X-ray diffraction techniques. It forms a series with elbaite and probably also with olenite. Liddiocoatite is currently a non-approved mineral name, but Aurisicchio et al. (1999) and Breaks et al. (2008) found OH-dominant species. Formulae are

<span class="mw-page-title-main">Fluor-uvite</span>

Fluor-uvite is a tourmaline mineral with the chemical formula CaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3F. It is a rare mineral that is found in calcium rich contact metamorphic rocks with increased amounts of boron. Uvite is trigonal hexagonal, which means that it has three equal length axes at 120 degrees, all perpendicular to its fourth axis which has a different length. Uvite is part of the space group 3m. Uvite's hardness has been measured to be 7.5 on the Mohs hardness scale. The color of uvite widely varies, depending on the sample, but is mostly deep green or brown. In regard to uvite's optical properties, it is uniaxial (-) and anisotropic, meaning that the velocity of light in the mineral depends on the path that it takes. In plane polarized light, uvite is colorless to pale yellow and shows weak pleochroism.

<span class="mw-page-title-main">Jimthompsonite</span>

Jimthompsonite is a magnesium iron silicate mineral with chemical formula (Mg,Fe2+)5Si6O16(OH)2. It is a triple chain silicate (or inosilicate) along with clinojimthompsonite and chesterite. They were described in 1977 by Burham and Veblen. They attracted great mineralogical attention because they were the first examples of new chain silicate structures among a large group known as biopyriboles whose name is derived from the words biotite, pyroxene, and amphiboles.

Yagiite is a cyclosilicate mineral belonging to the osumilite group. It was discovered in 1968 in the iron meteorite that fell in Colomera in the province of Granada (Spain). Named after the Japanese mineralogist Kenzo Yagi, its CAS Registry Number is IMA1968-020.

Elgoresyite, first discovered during the crystallographic study of the Suizhou meteorite, is a naturally occurring, high-pressure iron-magnesium silicate mineral. High-pressure poly morphs of magnesium silicates have been rarely discovered on Earth, due to retrograding as they ascend to the surface. It is named after Ahmed El Goresy.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. "Osumilite: Mineral information, data and localities". www.mindat.org.
  3. 1 2 3 http://www.handbookofmineralogy.org/pdfs/osumilite.pdf Handbook of Mineralogy
  4. 1 2 "Osumilite-(Mg) Mineral Data". webmineral.com.
  5. Don S. Goldman, George R. Rossman (1978): The site distribution of iron and anomalous biaxiality in osumilite, In: American Mineralogist, 63, S. 490-498 ((PDF, 961 kB) [ permanent dead link ])
  6. E. Olsen, T. E. Bunch (1970): Compositions Of Natural Osumilites, In: The American Mineralogiste, 55, S. 875 - 879 ((PDF, 328 kB))
  7. http://www.galleries.com/minerals/silicate/osumilit/osumilit.htm Mineral Galleries