Petrogenetic grid

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Figure 1. Petrogenetic grid for metapelites (several authors). Metamorphic facies included are: BS = Blueschist facies, EC = Eclogite facies, PP = Prehnite-Pumpellyite facies, GS = Granulite facies, EA = Epidote-Amphibolite facies, AM = Amphibolite facies, GRA = Granulite facies, UHT = Ultra-High Temperature facies, HAE = Hornfels-Albite-Epidote facies, Hbl = Hornblende-Hornfels facies, HPX = Hornfels-Pyroxene Facies, San = Sanidinite facies Petrogenetic grid for Metapelites.png
Figure 1. Petrogenetic grid for metapelites (several authors). Metamorphic facies included are: BS = Blueschist facies, EC = Eclogite facies, PP = Prehnite-Pumpellyite facies, GS = Granulite facies, EA = Epidote-Amphibolite facies, AM = Amphibolite facies, GRA = Granulite facies, UHT = Ultra-High Temperature facies, HAE = Hornfels-Albite-Epidote facies, Hbl = Hornblende-Hornfels facies, HPX = Hornfels-Pyroxene Facies, San = Sanidinite facies

A petrogenetic grid is a geological phase diagram that connects the stability ranges or metastability ranges of metamorphic minerals or mineral assemblages to the conditions of metamorphism. Experimentally determined mineral or mineral-assemblage stability ranges are plotted as metamorphic reaction boundaries in a pressure–temperature cartesian coordinate system to produce a petrogenetic grid for a particular rock composition. The regions of overlap of the stability fields of minerals form equilibrium mineral assemblages used to determine the pressure–temperature conditions of metamorphism. This is particularly useful in geothermobarometry. [3] [4] [5] [6]

Contents

Figure 1 is an example of a complex petrogenetic grid for metamorphosed pelitic rocks. It shows most of the important reactions that govern the development of aluminous mineral assemblages from the prehnite-pumpellyite facies to the granulite facies, as well as the blueschist facies and eclogite facies at higher pressures and the contact hornfels facies at lower pressures. As the rock undergoes higher temperatures and pressures, it follows the classic Barrovian sequence from the chlorite zone to the biotite zone to the garnet zone to the staurolite zone.

For a metapelitic rock containing chlorite, kaolinite, and quartz the petrogenetic grid for metapelites (Figure 1) shows that such a rock can only form at relatively low pressures and temperatures. However, if it had carpholite instead of chlorite, then it would have formed at higher pressures, and if it had pyrophyllite instead of kaolinite, it would have formed at higher temperatures. This assumes the rock has a KFMASH (K2O–FeO–MgO–Al2O3–SiO2–H2O) composition because that is what the experimental data was created with. If the composition of the rock differs from this, then the figure is less accurate.

Norman L. Bowen proposed the concept of petrogenetic grids in 1940. [7] At the time, he envisioned geologists eventually determining every possible metamorphic reaction and assemblage in nature, but realized that the magnitude of undertaking the necessary experiments was a huge task that would not be finished for a very long time. As such, modern petrogenetic grids are only partially complete. Depending on the level of precision and characterization needed, a petrogenetic grid may be simple, or it may be an extremely large system consisting of a hundred or more reactions.

Phase diagram of Al2SiO5
(aluminosilicates). [9]

See also

Related Research Articles

<span class="mw-page-title-main">Kyanite</span> Aluminosilicate mineral

Kyanite is a typically blue aluminosilicate mineral, found in aluminium-rich metamorphic pegmatites and sedimentary rock. It is the high pressure polymorph of andalusite and sillimanite, and the presence of kyanite in metamorphic rocks generally indicates metamorphism deep in the Earth's crust. Kyanite is also known as disthene or cyanite.

<span class="mw-page-title-main">Metamorphic rock</span> Rock that was subjected to heat and pressure

Metamorphic rocks arise from the transformation of existing rock to new types of rock in a process called metamorphism. The original rock (protolith) is subjected to temperatures greater than 150 to 200 °C and, often, elevated pressure of 100 megapascals (1,000 bar) or more, causing profound physical or chemical changes. During this process, the rock remains mostly in the solid state, but gradually recrystallizes to a new texture or mineral composition. The protolith may be an igneous, sedimentary, or existing metamorphic rock.

<span class="mw-page-title-main">Andalusite</span> Aluminium nesosilicate mineral

Andalusite is an aluminium nesosilicate mineral with the chemical formula Al2SiO5. This mineral was called andalousite by Delamétehrie, who thought it came from Andalusia, Spain. It soon became clear that it was a locality error, and that the specimens studied were actually from El Cardoso de la Sierra, in the Spanish province of Guadalajara, not Andalusia.

<span class="mw-page-title-main">Sillimanite</span> Nesosilicate mineral

Sillimanite or fibrolite is an aluminosilicate mineral with the chemical formula Al2SiO5. Sillimanite is named after the American chemist Benjamin Silliman (1779–1864). It was first described in 1824 for an occurrence in Chester, Connecticut.

<span class="mw-page-title-main">Metamorphism</span> Change of minerals in pre-existing rocks without melting into liquid magma

Metamorphism is the transformation of existing rock to rock with a different mineral composition or texture. Metamorphism takes place at temperatures in excess of 150 °C (300 °F), and often also at elevated pressure or in the presence of chemically active fluids, but the rock remains mostly solid during the transformation. Metamorphism is distinct from weathering or diagenesis, which are changes that take place at or just beneath Earth's surface.

<span class="mw-page-title-main">Amphibolite</span> A metamorphic rock containing mainly amphibole and plagioclase

Amphibolite is a metamorphic rock that contains amphibole, especially hornblende and actinolite, as well as plagioclase feldspar, but with little or no quartz. It is typically dark-colored and dense, with a weakly foliated or schistose (flaky) structure. The small flakes of black and white in the rock often give it a salt-and-pepper appearance.

<span class="mw-page-title-main">Staurolite</span> Reddish brown to black nesosilicate mineral

Staurolite is a reddish brown to black, mostly opaque, nesosilicate mineral with a white streak. It crystallizes in the monoclinic crystal system, has a Mohs hardness of 7 to 7.5 and the chemical formula: Fe2+2Al9O6(SiO4)4(O,OH)2. Magnesium, zinc and manganese substitute in the iron site and trivalent iron can substitute for aluminium.

<span class="mw-page-title-main">Granulite</span> Class of high-grade medium to coarse grained metamorphic rocks

Granulites are a class of high-grade metamorphic rocks of the granulite facies that have experienced high-temperature and moderate-pressure metamorphism. They are medium to coarse–grained and mainly composed of feldspars sometimes associated with quartz and anhydrous ferromagnesian minerals, with granoblastic texture and gneissose to massive structure. They are of particular interest to geologists because many granulites represent samples of the deep continental crust. Some granulites experienced decompression from deep in the Earth to shallower crustal levels at high temperature; others cooled while remaining at depth in the Earth.

<span class="mw-page-title-main">Hornfels</span>

Hornfels is the group name for a set of contact metamorphic rocks that have been baked and hardened by the heat of intrusive igneous masses and have been rendered massive, hard, splintery, and in some cases exceedingly tough and durable. These properties are due to fine grained non-aligned crystals with platy or prismatic habits, characteristic of metamorphism at high temperature but without accompanying deformation. The term is derived from the German word Hornfels, meaning "hornstone", because of its exceptional toughness and texture both reminiscent of animal horns. These rocks were referred to by miners in northern England as whetstones.

<span class="mw-page-title-main">Chlorite group</span> Type of mineral

The chlorites are the group of phyllosilicate minerals common in low-grade metamorphic rocks and in altered igneous rocks. Greenschist, formed by metamorphism of basalt or other low-silica volcanic rock, typically contains significant amounts of chlorite.

<span class="mw-page-title-main">Blueschist</span> Type of metavolcanic rock

Blueschist, also called glaucophane schist, is a metavolcanic rock that forms by the metamorphism of basalt and rocks with similar composition at high pressures and low temperatures, approximately corresponding to a depth of 15–30 km (9.3–18.6 mi). The blue color of the rock comes from the presence of the predominant minerals glaucophane and lawsonite.

<span class="mw-page-title-main">Pelite</span> Metamorphic rock

A pelite or metapelite is a metamorphosed fine-grained sedimentary rock, i.e. mudstone or siltstone. The term was earlier used by geologists to describe a clay-rich, fine-grained clastic sediment or sedimentary rock, i.e. mud or a mudstone, the metamorphosed version of which would technically have been a metapelite. It was equivalent to the now little-used Latin-derived term lutite. A semipelite is defined in part as having similar chemical composition but being of a crystalloblastic nature.

<span class="mw-page-title-main">Greenschist</span> Metamorphic rocks

Greenschists are metamorphic rocks that formed under the lowest temperatures and pressures usually produced by regional metamorphism, typically 300–450 °C (570–840 °F) and 2–10 kilobars (29,000–145,000 psi). Greenschists commonly have an abundance of green minerals such as chlorite, serpentine, and epidote, and platy minerals such as muscovite and platy serpentine. The platiness gives the rock schistosity Other common minerals include quartz, orthoclase, talc, carbonate minerals and amphibole (actinolite).

<span class="mw-page-title-main">Aluminium silicate</span> Chemical compound

Aluminium silicate (or aluminum silicate) is a name commonly applied to chemical compounds which are derived from aluminium oxide, Al2O3 and silicon dioxide, SiO2 which may be anhydrous or hydrated, naturally occurring as minerals or synthetic. Their chemical formulae are often expressed as xAl2O3·ySiO2·zH2O. It is known as E number E559.

An isograd is a concept used in the study of metamorphic rocks. The metamorphic grade of such a rock is a rough measure of the degree of metamorphism it has undergone, as characterised by the presence of certain index minerals. An isograd is a theoretical surface comprising points all at the same metamorphic grade, and thus separates metamorphic zones whose rocks contain different index minerals.

<span class="mw-page-title-main">Metamorphic facies</span> Set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures

A metamorphic facies is a set of mineral assemblages in metamorphic rocks formed under similar pressures and temperatures. The assemblage is typical of what is formed in conditions corresponding to an area on the two dimensional graph of temperature vs. pressure. Rocks which contain certain minerals can therefore be linked to certain tectonic settings, times and places in the geological history of the area. The boundaries between facies are wide because they are gradational and approximate. The area on the graph corresponding to rock formation at the lowest values of temperature and pressure is the range of formation of sedimentary rocks, as opposed to metamorphic rocks, in a process called diagenesis.

In geology ultrahigh-temperature metamorphism (UHT) is extreme crustal metamorphism with metamorphic temperatures exceeding 900 °C. Granulite-facies rocks metamorphosed at very high temperatures were identified in the early 1980s, although it took another decade for the geoscience community to recognize UHT metamorphism as a common regional phenomenon. Petrological evidence based on characteristic mineral assemblages backed by experimental and thermodynamic relations demonstrated that Earth's crust can attain and withstand very high temperatures (900–1000 °C) with or without partial melting.

<span class="mw-page-title-main">Metamorphic zone</span>

In geology, a metamorphic zone is an area where, as a result of metamorphism, the same combination of minerals occur in the bedrock. These zones occur because most metamorphic minerals are only stable in certain intervals of temperature and pressure.

<span class="mw-page-title-main">Subduction zone metamorphism</span> Changes of rock due to pressure and heat near a subduction zone

A subduction zone is a region of the earth's crust where one tectonic plate moves under another tectonic plate; oceanic crust gets recycled back into the mantle and continental crust gets created by the formation of arc magmas. Arc magmas account for more than 20% of terrestrially produced magmas and are produced by the dehydration of minerals within the subducting slab as it descends into the mantle and are accreted onto the base of the overriding continental plate. Subduction zones host a unique variety of rock types created by the high-pressure, low-temperature conditions a subducting slab encounters during its descent. The metamorphic conditions the slab passes through in this process creates and destroys water bearing (hydrous) mineral phases, releasing water into the mantle. This water lowers the melting point of mantle rock, initiating melting. Understanding the timing and conditions in which these dehydration reactions occur, is key to interpreting mantle melting, volcanic arc magmatism, and the formation of continental crust.

<span class="mw-page-title-main">Pressure-temperature-time path</span>

The Pressure-Temperature-time path is a record of the pressure and temperature (P-T) conditions that a rock experienced in a metamorphic cycle from burial and heating to uplift and exhumation to the surface. Metamorphism is a dynamic process which involves the changes in minerals and textures of the pre-existing rocks (protoliths) under different P-T conditions in solid state. The changes in pressures and temperatures with time experienced by the metamorphic rocks are often investigated by petrological methods, radiometric dating techniques and thermodynamic modeling.

References

  1. Wei, Chunjing; Powell, Roger (2003). "Phase relations in high-pressure metapelites in the system KFMASH (K2O–FeO–MgO–Al2O3–SiO2–H2O) with application to natural rocks". Contributions to Mineralogy and Petrology. 145 (3): 301–315. doi:10.1007/s00410-003-0454-1.
  2. Wei, Chunjing; Powell, Roger; Clarke, Gordon (2004). "Calculated phase equilibria for low‐ and medium‐pressure metapelites in the KFMASH and KMnFMASH systems". Journal of Metamorphic Geology. 22 (5): 495–508. doi:10.1111/j.1525-1314.2004.00530.x.
  3. Proyer, A (2003). "Metamorphism of pelites in NKFMASH — A new petrogenetic grid with implications for the preservation of high-pressure mineral assemblages during exhumation". Journal of Metamorphic Geology. 22 (5): 493–509. doi:10.1046/j.1525-1314.2003.00457.x.
  4. Spear, Frank; Cheney, John (1989). "A petrogenetic grid for pelitic schists in the system SiO2-Al2O3-FeO-MgO-K2O-H2O". Contributions to Mineralogy and Petrology. 101 (2): 149–164. doi:10.1007/BF00375302.
  5. Carrington, D; Harley, S (1995). "Partial melting and phase relations in high-grade metapelites: an experimental petrogenetic grid in the KFMASH system". Contributions to Mineralogy and Petrology. 120 (3–4): 270–291. doi:10.1007/BF00306508.
  6. Pattison, David; Spear, Frank (2018). "Kinetic control of staurolite–Al2SiO5 mineral assemblages: Implications for Barrovian and Buchan metamorphism". Journal of Metamorphic Geology. 36 (6): 667–690. doi:10.1111/jmg.12302.
  7. Bowen, Norman (1940). "Progressive Metamorphism of Siliceous Limestone and Dolomite". The Journal of Geology. 48 (3): 225–274. doi:10.1086/624885.
  8. Whitney, D.L. (2002). "Coexisting andalusite, kyanite, and sillimanite: Sequential formation of three Al2SiO5 polymorphs during progressive metamorphism near the triple point, Sivrihisar, Turkey". American Mineralogist. 87 (4): 405–416. doi:10.2138/am-2002-0404.
  9. Whitney, D.L. (2002). "Coexisting andalusite, kyanite, and sillimanite: Sequential formation of three Al2SiO5 polymorphs during progressive metamorphism near the triple point, Sivrihisar, Turkey". American Mineralogist. 87 (4): 405–416. doi:10.2138/am-2002-0404.

Further reading

Winter, John (2013). Principles of Igneous and Metamorphic Petrology. Pearson Education Limited. ISBN   978-0321592576.