Pure and Applied Chemistry

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<span class="mw-page-title-main">International Union of Pure and Applied Chemistry</span> International organization representing chemists

The International Union of Pure and Applied Chemistry is an international federation of National Adhering Organizations working for the advancement of the chemical sciences, especially by developing nomenclature and terminology. It is a member of the International Science Council (ISC). IUPAC is registered in Zürich, Switzerland, and the administrative office, known as the "IUPAC Secretariat", is in Research Triangle Park, North Carolina, United States. This administrative office is headed by IUPAC's executive director, currently Greta Heydenrych.

<span class="mw-page-title-main">Enantiomer</span> Stereoisomers which are non-superposable mirror images of each other

In chemistry, an enantiomer – also called optical isomer, antipode, or optical antipode – is one of two stereoisomers that are non-superposable onto their own mirror image. Enantiomers are much like one's right and left hands, when looking at the same face, they cannot be superposed onto each other. No amount of reorientation in three spatial dimensions will allow the four unique groups on the chiral carbon to line up exactly. The number of stereoisomers a molecule has can be determined by the number of chiral carbons it has. Stereoisomers include both enantiomers and diastereomers.

Relative atomic mass, also known by the deprecated synonym atomic weight, is a dimensionless physical quantity defined as the ratio of the average mass of atoms of a chemical element in a given sample to the atomic mass constant. The atomic mass constant is defined as being 1/12 of the mass of a carbon-12 atom. Since both quantities in the ratio are masses, the resulting value is dimensionless.

Natural hafnium (72Hf) consists of five stable isotopes (176Hf, 177Hf, 178Hf, 179Hf, and 180Hf) and one very long-lived radioisotope, 174Hf, with a half-life of 7.0×1016 years. In addition, there are 30 known synthetic radioisotopes, the most stable of which is 182Hf with a half-life of 8.9×106 years. This extinct radionuclide is used in hafnium–tungsten dating to study the chronology of planetary differentiation.

Natural holmium (67Ho) contains one observationally stable isotope, 165Ho. The below table lists 36 isotopes spanning 140Ho through 175Ho as well as 33 nuclear isomers. Among the known synthetic radioactive isotopes; the most stable one is 163Ho, with a half-life of 4,570 years. All other radioisotopes have half-lives not greater than 1.117 days in their ground states, and most have half-lives under 3 hours.

Naturally occurring praseodymium (59Pr) is composed of one stable isotope, 141Pr. Thirty-eight radioisotopes have been characterized with the most stable being 143Pr, with a half-life of 13.57 days and 142Pr, with a half-life of 19.12 hours. All of the remaining radioactive isotopes have half-lives that are less than 5.985 hours and the majority of these have half-lives that are less than 33 seconds. This element also has 15 meta states with the most stable being 138mPr, 142mPr and 134mPr.

Antimony (51Sb) occurs in two stable isotopes, 121Sb and 123Sb. There are 35 artificial radioactive isotopes, the longest-lived of which are 125Sb, with a half-life of 2.75856 years; 124Sb, with a half-life of 60.2 days; and 126Sb, with a half-life of 12.35 days. All other isotopes have half-lives less than 4 days, most less than an hour.

Naturally occurring rhodium (45Rh) is composed of only one stable isotope, 103Rh. The most stable radioisotopes are 101Rh with a half-life of 3.3 years, 102Rh with a half-life of 207 days, and 99Rh with a half-life of 16.1 days. Thirty other radioisotopes have been characterized with atomic weights ranging from 88.949 u (89Rh) to 121.943 u (122Rh). Most of these have half-lives that are less than an hour except 100Rh and 105Rh. There are also numerous meta states with the most stable being 102mRh (0.141 MeV) with a half-life of about 3.7 years and 101mRh (0.157 MeV) with a half-life of 4.34 days.

Naturally occurring zinc (30Zn) is composed of the 5 stable isotopes 64Zn, 66Zn, 67Zn, 68Zn, and 70Zn with 64Zn being the most abundant. Twenty-five radioisotopes have been characterised with the most abundant and stable being 65Zn with a half-life of 244.26 days, and 72Zn with a half-life of 46.5 hours. All of the remaining radioactive isotopes have half-lives that are less than 14 hours and the majority of these have half-lives that are less than 1 second. This element also has 10 meta states.

Naturally occurring scandium (21Sc) is composed of one stable isotope, 45Sc. Twenty-five radioisotopes have been characterized, with the most stable being 46Sc with a half-life of 83.8 days, 47Sc with a half-life of 3.35 days, and 48Sc with a half-life of 43.7 hours and 44Sc with a half-life of 3.97 hours. All the remaining isotopes have half-lives that are less than four hours, and the majority of these have half-lives that are less than two minutes, the least stable being proton unbound 39Sc with a half-life shorter than 300 nanoseconds. This element also has 13 meta states with the most stable being 44m2Sc.

A chemical nomenclature is a set of rules to generate systematic names for chemical compounds. The nomenclature used most frequently worldwide is the one created and developed by the International Union of Pure and Applied Chemistry (IUPAC).

<span class="mw-page-title-main">Standard atomic weight</span> Relative atomic mass as defined by IUPAC (CIAAW)

The standard atomic weight of a chemical element (symbol Ar°(E) for element "E") is the weighted arithmetic mean of the relative isotopic masses of all isotopes of that element weighted by each isotope's abundance on Earth. For example, isotope 63Cu (Ar = 62.929) constitutes 69% of the copper on Earth, the rest being 65Cu (Ar = 64.927), so

In chemical nomenclature, a preferred IUPAC name (PIN) is a unique name, assigned to a chemical substance and preferred among the possible names generated by IUPAC nomenclature. The "preferred IUPAC nomenclature" provides a set of rules for choosing between multiple possibilities in situations where it is important to decide on a unique name. It is intended for use in legal and regulatory situations.

<i>Nomenclature of Organic Chemistry</i> Book describing the nomenclature of organic compounds

Nomenclature of Organic Chemistry, commonly referred to by chemists as the Blue Book, is a collection of recommendations on organic chemical nomenclature published at irregular intervals by the International Union of Pure and Applied Chemistry (IUPAC). A full edition was published in 1979, an abridged and updated version of which was published in 1993 as A Guide to IUPAC Nomenclature of Organic Compounds. Both of these are now out-of-print in their paper versions, but are available free of charge in electronic versions. After the release of a draft version for public comment in 2004 and the publication of several revised sections in the journal Pure and Applied Chemistry, a fully revised edition was published in print in 2013 and its online version is also available.

<i>Compendium of Analytical Nomenclature</i>

The Compendium of Analytical Nomenclature is an IUPAC nomenclature book published by the International Union of Pure and Applied Chemistry (IUPAC) containing internationally accepted definitions for terms in analytical chemistry. It has traditionally been published in an orange cover, hence its informal name, the Orange Book.

The International Union of Pure and Applied Chemistry (IUPAC) publishes many books which contain its complete list of definitions. The definitions are divided initially into seven IUPC Colour Books: Gold, Green, Blue, Purple, Orange, White, and Red. There is also an eighth book, the "Silver Book".

The International IUPAC Conferences on Green Chemistry (ICGCs) gather several hundreds scientists, technologists, and experts from all over the world with the aim to exchange and disseminate new ideas, discoveries, and projects on green chemistry and a sustainable development. After mid twentieth century, an increasingly general consensus acknowledges that these subjects play a unique role in mapping the way ahead for the humankind progress. Typical topics discussed in these IUPAC Conferences are:

<span class="mw-page-title-main">IUPAC nomenclature of chemistry</span> Systematic method of naming organic and inorganic chemical compounds

The International Union of Pure and Applied Chemistry (IUPAC) has published four sets of rules to standardize chemical nomenclature.

Mary Jean Garson is an organic chemist and academic in Australia. She currently works for the University of Queensland.

Chemistry International is a news magazine published by the International Union of Pure and Applied Chemistry (IUPAC). According to its website, it was published in editions covering two months at a time. In 2017 the magazine began to be published quarterly.

References

  1. Seeman, Jeffrey I. (1 January 2017). "Taking IUPAC Literally: Woodward's Pure and Applied Chemistry Words". Chemistry International. 39 (1). doi: 10.1515/ci-2017-0103 .