Spectroscopy is the field of study that measures and interprets the electromagnetic spectra that result from the interaction between electromagnetic radiation and matter as a function of the wavelength or frequency of the radiation. In simpler terms, spectroscopy is the precise study of color as generalized from visible light to all bands of the electromagnetic spectrum.
Time of flight (ToF) is the measurement of the time taken by an object, particle or wave to travel a distance through a medium. This information can then be used to measure velocity or path length, or as a way to learn about the particle or medium's properties. The traveling object may be detected directly or indirectly. Time of flight technology has found valuable applications in the monitoring and characterization of material and biomaterials, hydrogels included.
In physical chemistry and materials science, texture is the distribution of crystallographic orientations of a polycrystalline sample. A sample in which these orientations are fully random is said to have no distinct texture. If the crystallographic orientations are not random, but have some preferred orientation, then the sample has a weak, moderate or strong texture. The degree is dependent on the percentage of crystals having the preferred orientation.
Electron backscatter diffraction (EBSD) is a scanning electron microscopy (SEM) technique used to study the crystallographic structure of materials. EBSD is carried out in a scanning electron microscope equipped with an EBSD detector comprising at least a phosphorescent screen, a compact lens and a low-light camera. In the microscope an incident beam of electrons hits a tilted sample. As backscattered electrons leave the sample, they interact with the atoms and are both elastically diffracted and lose energy, leaving the sample at various scattering angles before reaching the phosphor screen forming Kikuchi patterns (EBSPs). The EBSD spatial resolution depends on many factors, including the nature of the material under study and the sample preparation. They can be indexed to provide information about the material's grain structure, grain orientation, and phase at the micro-scale. EBSD is used for impurities and defect studies, plastic deformation, and statistical analysis for average misorientation, grain size, and crystallographic texture. EBSD can also be combined with energy-dispersive X-ray spectroscopy (EDS), cathodoluminescence (CL), and wavelength-dispersive X-ray spectroscopy (WDS) for advanced phase identification and materials discovery.
Metallography is the study of the physical structure and components of metals, by using microscopy.
Laser-ultrasonics uses lasers to generate and detect ultrasonic waves. It is a non-contact technique used to measure materials thickness, detect flaws and carry out materials characterization. The basic components of a laser-ultrasonic system are a generation laser, a detection laser and a detector.
Selected area (electron) diffraction is a crystallographic experimental technique typically performed using a transmission electron microscope (TEM). It is a specific case of electron diffraction used primarily in material science and solid state physics as one of the most common experimental techniques. Especially with appropriate analytical software, SAD patterns (SADP) can be used to determine crystal orientation, measure lattice constants or examine its defects.
Nanoindentation, also called instrumented indentation testing, is a variety of indentation hardness tests applied to small volumes. Indentation is perhaps the most commonly applied means of testing the mechanical properties of materials. The nanoindentation technique was developed in the mid-1970s to measure the hardness of small volumes of material.
In materials science, grain growth is the increase in size of grains (crystallites) in a material at high temperature. This occurs when recovery and recrystallisation are complete and further reduction in the internal energy can only be achieved by reducing the total area of grain boundary. The term is commonly used in metallurgy but is also used in reference to ceramics and minerals. The behaviors of grain growth is analogous to the coarsening behaviors of grains, which implied that both of grain growth and coarsening may be dominated by the same physical mechanism.
The three-dimensional elastic constants of materials can be measured using the ultrasonic immersion method. This was pioneered by Zimmer and Cost from the National Physical Laboratory in the 1960s. It has mainly been used for polymer composite materials. Knowledge of the elastic constants can be used to feed back into models of the material's behaviour or that of the composite manufacturing process used.
Picosecond ultrasonics is a type of ultrasonics that uses ultra-high frequency ultrasound generated by ultrashort light pulses. It is a non-destructive technique in which picosecond acoustic pulses penetrate into thin films or nanostructures to reveal internal features such as film thickness as well as cracks, delaminations and voids. It can also be used to probe liquids. The technique is also referred to as picosecond laser ultrasonics or laser picosecond acoustics.
Electromagnetic acoustic transducer (EMAT) is a transducer for non-contact acoustic wave generation and reception in conducting materials. Its effect is based on electromagnetic mechanisms, which do not need direct coupling with the surface of the material. Due to this couplant-free feature, EMATs are particularly useful in harsh, i.e., hot, cold, clean, or dry environments. EMATs are suitable to generate all kinds of waves in metallic and/or magnetostrictive materials. Depending on the design and orientation of coils and magnets, shear horizontal (SH) bulk wave mode, surface wave, plate waves such as SH and Lamb waves, and all sorts of other bulk and guided-wave modes can be excited. After decades of research and development, EMAT has found its applications in many industries such as primary metal manufacturing and processing, automotive, railroad, pipeline, boiler and pressure vessel industries, in which they are typically used for nondestructive testing (NDT) of metallic structures.
Atomic force acoustic microscopy (AFAM) is a type of scanning probe microscopy (SPM). It is a combination of acoustics and atomic force microscopy. The principal difference between AFAM and other forms of SPM is the addition of a transducer at the bottom of the sample which induces longitudinal out-of-plane vibrations in the specimen. These vibrations are sensed by a cantilever and tip called a probe. The figure shown here is the clear schematic of AFAM principle here B is the magnified version of the tip and sample placed on the transducer and tip having some optical coating generally gold coating to reflect the laser light on to the photodiode.
Brillouin spectroscopy is an empirical spectroscopy technique which allows the determination of elastic moduli of materials. The technique uses inelastic scattering of light when it encounters acoustic phonons in a crystal, a process known as Brillouin scattering, to determine phonon energies and therefore interatomic potentials of a material. The scattering occurs when an electromagnetic wave interacts with a density wave, photon-phonon scattering.
Resonant ultrasound spectroscopy (RUS) is a laboratory technique used in geology and material science to measure fundamental material properties involving elasticity. This technique relies on the fact that solid objects have natural frequencies at which they vibrate when mechanically excited. The natural frequency depends on the elasticity, size, and shape of the object—RUS exploits this property of solids to determine the elastic tensor of the material. The great advantage of this technique is that the entire elastic tensor is obtained from a single crystal sample in a single rapid measurement. At lower or more general frequencies, this method is known as acoustic resonance spectroscopy.
Active thermography is an advanced nondestructive testing procedure, which uses a thermography measurement of a tested material thermal response after its external excitation. This principle can be used also for non-contact infrared non-destructive testing (IRNDT) of materials.
Dislocation avalanches are rapid discrete events during plastic deformation, in which defects are reorganized collectively. This intermittent flow behavior has been observed in microcrystals, whereas macroscopic plasticity appears as a smooth process. Intermittent plastic flow has been observed in several different systems. In AlMg Alloys, interaction between solute and dislocations can cause sudden jump during dynamic strain aging. In metallic glass, it can be observed via shear banding with stress localization; and single crystal plasticity, it shows up as slip burst. However, analysis of the events with orders-magnitude difference in sizes with different crystallographic structure reveals power-law scaling between the number of events and their magnitude, or scale-free flow.
Crystal plasticity is a mesoscale computational technique that takes into account crystallographic anisotropy in modelling the mechanical behaviour of polycrystalline materials. The technique has typically been used to study deformation through the process of slip, however, there are some flavors of crystal plasticity that can incorporate other deformation mechanisms like twinning and phase transformations. Crystal plasticity is used to obtain the relationship between stress and strain that also captures the underlying physics at the crystal level. Hence, it can be used to predict not just the stress-strain response of a material, but also the texture evolution, micromechanical field distributions, and regions of strain localisation. The two widely used formulations of crystal plasticity are the one based on the finite element method known as Crystal Plasticity Finite Element Method (CPFEM), which is developed based on the finite strain formulation for the mechanics, and a spectral formulation which is more computationally efficient due to the fast Fourier transform, but is based on the small strain formulation for the mechanics.
CrysTBox is a suite of computer tools designed to accelerate material research based on transmission electron microscope images via highly accurate automated analysis and interactive visualization. Relying on artificial intelligence and computer vision, CrysTBox makes routine crystallographic analyses simpler, faster and more accurate compared to human evaluators. The high level of automation together with sub-pixel precision and interactive visualization makes the quantitative crystallographic analysis accessible even for non-crystallographers allowing for an interdisciplinary research. Simultaneously, experienced material scientists can take advantage of advanced functionalities for comprehensive analyses.
Dark-field X-ray microscopy is an imaging technique used for multiscale structural characterisation. It is capable of mapping deeply embedded structural elements with nm-resolution using synchrotron X-ray diffraction-based imaging. The technique works by using scattered X-rays to create a high degree of contrast, and by measuring the intensity and spatial distribution of the diffracted beams, it is possible to obtain a three-dimensional map of the sample's structure, orientation, and local strain.
