Surface engineering

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Surface engineering is the sub-discipline of materials science which deals with the surface of solid matter. It has applications to chemistry, mechanical engineering, and electrical engineering (particularly in relation to semiconductor manufacturing).

Contents

Solids are composed of a bulk material covered by a surface. The surface which bounds the bulk material is called the surface phase. It acts as an interface to the surrounding environment. The bulk material in a solid is called the bulk phase.

The surface phase of a solid interacts with the surrounding environment. This interaction can degrade the surface phase over time. Environmental degradation of the surface phase over time can be caused by wear, corrosion, fatigue and creep.

Surface engineering involves altering the properties of the surface phase in order to reduce the degradation over time. This is accomplished by making the surface robust to the environment in which it will be used. It provides a cost-effective material for robust design. A spectrum of topics that represent the diverse nature of the field of surface engineering includes plating technologies, nano and emerging technologies and surface engineering, characterization and testing.

Applications

Surface engineering techniques are being used in the automotive, aerospace, missile, power, electronic, biomedical, textile, petroleum, petrochemical, chemical, steel, cement, machine tools and construction industries including road surfacing. Surface engineering techniques can be used to develop a wide range of functional properties, including physical, chemical, electrical, electronic, magnetic, mechanical, wear-resistant and corrosion-resistant properties at the required substrate surfaces. Almost all types of materials, including metals, ceramics, polymers, and composites can be coated on similar or dissimilar materials. It is also possible to form coatings of newer materials (e.g., met glass. beta-C3N4), graded deposits, multi-component deposits etc. The advanced materials and deposition processes including recent developments in ultra hard materials like BAM (AlMgB compound)are fully covered in a recent book[R. Chattopadhyay:Green Tribology,Green Surface Engineering and Global Warming,ASM International,USA,2014]

In 1995, surface engineering was a £10 billion market in the United Kingdom. Coatings, to make surface life robust from wear and corrosion, was approximately half the market.

In recent years, there has been a paradigm shift in surface engineering from age-old electroplating to processes such as vapor phase deposition, diffusion, thermal spray & welding using heat sources, such as, laser,plasma,solar beam.microwave;friction.pulsed combustion. ion, electron pulsed arc, spark, friction and induction.[Ref:R.Chattopadhyay:Advanced Thermally Assisted Surface Engineering Processes,Springer, New York, USA,2004]

It is estimated that loss due to wear and corrosion in the US is approximately $500 billion. In the US, there are around 9524 establishments (including automotive, aircraft, power and construction industries) who depend on engineered surfaces with support from 23,466 industries.

There are around 65 academic institutions world-wide engaged in surface engineering research and education.

Surface cleaning techniques

Surface cleaning, synonymously referred to as dry cleaning, is a mechanical cleaning technique used to reduce superficial soil, dust, grime, insect droppings, accretions, or other surface deposits. (Dry cleaning, as the term is used in paper conservation, does not employ the use of organic solvents.) Surface cleaning may be used as an independent cleaning technique, as one step (usually the first) in a more comprehensive treatment, or as a prelude to further treatments (e.g., aqueous immersion) which may cause dirt to set irreversibly in paper fibers.

Purpose

The purpose of surface cleaning is to reduce the potential for damage to paper artifacts by removing foreign material which can be abrasive, acidic, hygroscopic, or degradative. The decision to remove surface dirt is also for aesthetic reasons when it interferes with the visibility of the imagery or information. A decision must be made balancing the probable care of each object against the possible problems related to surface cleaning.

Environmental benefits

The application of surface engineering to components leads to improved lifetime (e.g., by corrosion resistance) and improved efficiency (e.g., by reducing friction) which directly reduces the emissions corresponding to those components. Applying innovative surface engineering technologies to the energy sector has the potential of reducing annual CO2-eq emissions by up to 1.8 Gt in 2050 and 3.4 Gt in 2100. This corresponds to 7% and 8.5% annual reduction in the energy sector in 2050 and 2100, respectively. [1] Despite those benefits, a major environmental drawback is the dissipative losses occurring throughout the life cycle of the components, and the associated environmental impacts of them. In thermal spray surface engineering applications, the majority of those dissipative losses occur at the coating stage (up to 39%), where part of the sprayed powders do not adhere to the substrate. [2]

See also

Related Research Articles

A lubricant is a substance that helps to reduce friction between surfaces in mutual contact, which ultimately reduces the heat generated when the surfaces move. It may also have the function of transmitting forces, transporting foreign particles, or heating or cooling the surfaces. The property of reducing friction is known as lubricity.

<span class="mw-page-title-main">Corrosion</span> Gradual destruction of materials by chemical reaction with its environment

Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.

<span class="mw-page-title-main">Wear</span> Damaging, gradual removal or deformation of material at solid surfaces

Wear is the damaging, gradual removal or deformation of material at solid surfaces. Causes of wear can be mechanical or chemical. The study of wear and related processes is referred to as tribology.

Surface modification is the act of modifying the surface of a material by bringing physical, chemical or biological characteristics different from the ones originally found on the surface of a material.

Tribology is the science and engineering of understanding friction, lubrication and wear phenomena for interacting surfaces in relative motion. It is highly interdisciplinary, drawing on many academic fields, including physics, chemistry, materials science, mathematics, biology and engineering. The fundamental objects of study in tribology are tribosystems, which are physical systems of contacting surfaces. Subfields of tribology include biotribology, nanotribology and space tribology. It is also related to other areas such as the coupling of corrosion and tribology in tribocorrosion and the contact mechanics of how surfaces in contact deform. Approximately 20% of the total energy expenditure of the world is due to the impact of friction and wear in the transportation, manufacturing, power generation, and residential sectors.

<span class="mw-page-title-main">Galling</span> Form of wear caused by adhesion between sliding surfaces

Galling is a form of wear caused by adhesion between sliding surfaces. When a material galls, some of it is pulled with the contacting surface, especially if there is a large amount of force compressing the surfaces together. Galling is caused by a combination of friction and adhesion between the surfaces, followed by slipping and tearing of crystal structure beneath the surface. This will generally leave some material stuck or even friction welded to the adjacent surface, whereas the galled material may appear gouged with balled-up or torn lumps of material stuck to its surface.

<span class="mw-page-title-main">Superalloy</span> Alloy with higher durability than normal metals

A superalloy, or high-performance alloy, is an alloy with the ability to operate at a high fraction of its melting point. Key characteristics of a superalloy include mechanical strength, thermal creep deformation resistance, surface stability, and corrosion and oxidation resistance.

Fretting refers to wear and sometimes corrosion damage of loaded surfaces in contact while they encounter small oscillatory movements tangential to the surface. Fretting is caused by adhesion of contact surface asperities, which are subsequently broken again by the small movement. This breaking causes wear debris to be formed.

<span class="mw-page-title-main">Chromium(II) carbide</span> Chemical compound

Chromium(II) carbide is a ceramic compound that exists in several chemical compositions: Cr3C2, Cr7C3, and Cr23C6. At standard conditions it exists as a gray solid. It is extremely hard and corrosion resistant. It is also a refractory compound, which means that it retains its strength at high temperatures as well. These properties make it useful as an additive to metal alloys. When chromium carbide crystals are integrated into the surface of a metal it improves the wear resistance and corrosion resistance of the metal, and maintains these properties at elevated temperatures. The hardest and most commonly used composition for this purpose is Cr3C2.

<span class="mw-page-title-main">Physical vapor deposition</span> Method of coating solid surfaces with thin films

Physical vapor deposition (PVD), sometimes called physical vapor transport (PVT), describes a variety of vacuum deposition methods which can be used to produce thin films and coatings on substrates including metals, ceramics, glass, and polymers. PVD is characterized by a process in which the material transitions from a condensed phase to a vapor phase and then back to a thin film condensed phase. The most common PVD processes are sputtering and evaporation. PVD is used in the manufacturing of items which require thin films for optical, mechanical, electrical, acoustic or chemical functions. Examples include semiconductor devices such as thin-film solar cells, microelectromechanical devices such as thin film bulk acoustic resonator, aluminized PET film for food packaging and balloons, and titanium nitride coated cutting tools for metalworking. Besides PVD tools for fabrication, special smaller tools used mainly for scientific purposes have been developed.

<span class="mw-page-title-main">Thermal spraying</span> Coating process for applying heated materials to a surface

Thermal spraying techniques are coating processes in which melted materials are sprayed onto a surface. The "feedstock" is heated by electrical or chemical means.

<span class="mw-page-title-main">Thermal barrier coating</span> Form of exhaust heat management

Thermal barrier coatings (TBCs) are advanced materials systems usually applied to metallic surfaces on parts operating at elevated temperatures, such as gas turbine combustors and turbines, and in automotive exhaust heat management. These 100 μm to 2 mm thick coatings of thermally insulating materials serve to insulate components from large and prolonged heat loads and can sustain an appreciable temperature difference between the load-bearing alloys and the coating surface. In doing so, these coatings can allow for higher operating temperatures while limiting the thermal exposure of structural components, extending part life by reducing oxidation and thermal fatigue. In conjunction with active film cooling, TBCs permit working fluid temperatures higher than the melting point of the metal airfoil in some turbine applications. Due to increasing demand for more efficient engines running at higher temperatures with better durability/lifetime and thinner coatings to reduce parasitic mass for rotating/moving components, there is significant motivation to develop new and advanced TBCs. The material requirements of TBCs are similar to those of heat shields, although in the latter application emissivity tends to be of greater importance.

Dry lubricants or solid lubricants are materials that, despite being in the solid phase, are able to reduce friction between two surfaces sliding against each other without the need for a liquid oil medium.

<span class="mw-page-title-main">Tribocorrosion</span> Material degradation due to corrosion and wear.

Tribocorrosion is a material degradation process due to the combined effect of corrosion and wear. The name tribocorrosion expresses the underlying disciplines of tribology and corrosion. Tribology is concerned with the study of friction, lubrication and wear and corrosion is concerned with the chemical and electrochemical interactions between a material, normally a metal, and its environment. As a field of research tribocorrosion is relatively new, but tribocorrosion phenomena have been around ever since machines and installations are being used.

<span class="mw-page-title-main">Ceramic matrix composite</span> Composite material consisting of ceramic fibers in a ceramic matrix

In materials science ceramic matrix composites (CMCs) are a subgroup of composite materials and a subgroup of ceramics. They consist of ceramic fibers embedded in a ceramic matrix. The fibers and the matrix both can consist of any ceramic material, including carbon and carbon fibers.

Mechanically stimulated gas emission (MSGE) is a complex phenomenon embracing various physical and chemical processes occurring on the surface and in the bulk of a solid under applied mechanical stress and resulting in emission of gases. MSGE is a part of a more general phenomenon of mechanically stimulated neutral emission. MSGE experiments are often performed in ultra-high vacuum.

<span class="mw-page-title-main">Superhydrophobic coating</span> Water-repellant coating

A superhydrophobic coating is a thin surface layer that repels water. It is made from superhydrophobic (ultrahydrophobicity) materials. Droplets hitting this kind of coating can fully rebound. Generally speaking, superhydrophobic coatings are made from composite materials where one component provides the roughness and the other provides low surface energy.

<span class="mw-page-title-main">Detonation spraying</span> Method of thermal spraying

Detonation spraying is one of the many forms of thermal spraying techniques that are used to apply a protective coating at supersonic velocities to a material in order to change its surface characteristics. This is primarily to improve the durability of a component. It was first invented in 1955 by H.B. Sargent, R.M. Poorman and H. Lamprey and is applied to a component using a specifically designed detonation gun (D-gun). The component being sprayed must be prepared correctly by removing all surface oils, greases, debris and roughing up the surface in order to achieve a strongly bonded detonation spray coating. This process involves the highest velocities and temperatures (≈4000 °C) of coating materials compared to all other forms of thermal spraying techniques. Which means detonation spraying is able to apply low porous and low oxygen content protective coatings that protect against corrosion, abrasion and adhesion under low load.

Extreme tribology refers to tribological situations under extreme operating conditions which can be related to high loads and/or temperatures, or severe environments. Also, they may be related to high transitory contact conditions, or to situations with near-impossible monitoring and maintenance opportunities. In general, extreme conditions can typically be categorized as involving abnormally high or excessive exposure to e.g. cold, heat, pressure, vacuum, voltage, corrosive chemicals, vibration, or dust. The extreme conditions should include any device or system requiring a lubricant operating under any of the following conditions:

Plastic coating is a term that is commonly used in technology but is nevertheless ambiguous. It can be understood to mean the coating of plastic or the coating of other materials with plastics.

References

  1. Kaddoura, Mohamad; Majeau-Bettez, Guillaume; Amor, Ben; Moreau, Christian; Margni, Manuele (2022). "Investigating the role of surface engineering in mitigating greenhouse gas emissions of energy technologies: An outlook towards 2100". Sustainable Materials and Technologies. 32: 425. doi:10.1016/j.susmat.2022.e00425. S2CID   247751439.
  2. Kaddoura, Mohamad; Majeau-Bettez, Guillaume; Amor, Ben; Poirier, Dominique; Margni, Manuele (2024). "Estimating and reducing dissipative losses in thermal spray: A parametrized material flow analysis approach". Journal of Cleaner Production. 450: 141978. doi:10.1016/j.jclepro.2024.141978.