Tellurogallate

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Tellurogallates are chemical compounds which contain anionic units of tellurium connected to gallium. They can be considered as gallates where tellurium substitutes for oxygen. Similar compounds include the thiogallates, selenogallates, telluroaluminates, telluroindates and thiostannates. They are in the category of chalcogenotrielates or more broadly tellurometallates or chalcogenometallates.

Contents

Formation

Tellurogallates may be produced by heating a metal with gallium and tellurium in a sealed tube.


Properties

Some tellurogallates are semiconductors

Use

Tellurogallates are primarily of research interest. They are investigated for their infrared, thermoelectric and semiconductor characteristics.

List

namechemmwcrystal systemspace groupunit cell ÅvolumedensitycommentCAS

no

references
lithium tellurogallateLiGaTe2321.86tetragonalI42da=6.338 c=11.704 Z=16470.12.937orange to black; band gap 2.41 eV [1] [2]
sodium trigallium pentatellurideNaGa3Te5trigonalR32a=14.58 c=17.761 Z=123269.55.272black [3]
[(C6H5)4P]GaTe2(en)2 en = ethane-1,2-diaminemonoclinicC2/ca=20.680 b=5.3877 c=27.192 β=19.13°3029.61.720orange [4]
KGaTe2monoclinicC2/ca=11.768, b=11.775, c=16.503, β=100.36°, Z=16 [5]
KGaTe2triclinicP1 or P1a=8.34 b=8.34 c=64.4 αβγ~90°4479.44.30 [6]
hexapotassium di-μ-telluridobis (ditelluridogallate)K6Ga2Te6monoclinicP121/c1a = 8.616, b = 13.685, c = 11.290, β = 127.61°, Ζ = 21054.6 [7]
K[K([18]crown-6)]2[GaTe3] · 2CH3CNmonoclinicC2/ma=24.469 b=14.073 c=12.875 β=94.47 Z=443691.784yellow (@113K) [8]
CaGa6Te10monoclinicC2a=14.40 b=14.40 c=10.21 β=90.0 Z=42117.1 [9]
Cr3(GaTe3)2amorphous [10]
MnGa2Te4monoclinicC2/ca=11.999, b=11.999, c=24.922, β=104.01°, Z=16 [11]
MnGa2Te4orthorhombicPnmaa = 27.448, b = 4.192, c = 6.993 Z=4804.65.82 [12]
Fe3(GaTe3)2amorphous [10]
Co3(GaTe3)2amorphous [10]
Ni3-xGaTe2P63/mmca=3.9393 c=15.7933 Z=2 [13]
Ni2FeGaTeP63/mmca=3.962 c=15.868 Z=2215.7 [13]
CuGaTe2I42da = 6.02348, c = 11.93979433.2 [14]
ZnGa2Te4I4a=5.930, c=11.859 Z=25.7 [15]
ZnGa2Te4tetragonalI42ma=6.922 c=11.809 [16]
ZnGa2Te4F43ma=5.843 Z=1/2 [16]
AgGaTe2I42da=6.320 c=11.986 Z=26.052melt 725.7°C; heat of fusion= 104.8 J/g−1 [17] [18]
AgGa5Te8tetragonalI41/aa=8.415 c=47.877 [19] [20]
Ag2Ga6Te10 [19]
Ag9GaTe6hexagonalmelt 710°C Low thermal conductivity [21] [19] [22]
CdGa2Te4tetragonala=5.742 c=10.730 [23]
InGaTe2tetragonalI4/mcma = 8.412, c = 6.875; Z = 4; [24]
In2Ga6Te10trigonalR32a=10.34 alpha=89.7 Z=125.78 [25]
SnGa6Te10trigonalP3121/6a=14.408 c=17.678 Z=631785.684black [26]
SnxGa1-xTe x=1/2cubica=6.315251.84 [27]
β-BaGa2Te4orthorhombicImmaa = 23.813, b = 11.967, c = 6.7215 [28]
Ba5Ga2Ge3Te12monoclinicP21/ca = 13.6540, b = 9.6705, and c = 23.1134 β =91.829 [28]
LaGaITe2orthorhombicPmc21 [29]
CeGaITe2orthorhombicPmc21 [29]
PrGaITe2orthorhombicPmc21 [29]
NdGaITe2orthorhombicPmc21 [29]
Eu0.81Ga2Te4tetragonalI4/mcma = 8.2880, c = 6.744, Z = 2463.24 [30]
HgGa2Te4cubicF43ma=6.002 Z=1216.22 [31]
HgGa2Te4tetragonalI42ma=6.025 c=12.037 Z=2436.95black [31]
TlGaTe2tetragonalI4/mmm D184ha=8.429 c=6.865band gap 0.84 eV [32] [33]
Tl2InGaTe4tetragonalI4mcm [34]
PbGa6Te10trigonalP3221/6a=14.465 c=17.718 Z=632105.898black [35] [26]

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References

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