Thermal capillary wave

Last updated

Thermal motion is able to produce capillary waves at the molecular scale. At this scale, gravity and hydrodynamics can be neglected, and only the surface tension contribution is relevant.

Capillary wave theory (CWT) is a classic account of how thermal fluctuations distort an interface. It starts from some intrinsic surface that is distorted. Its energy will be proportional to its area:

where the first equality is the area in this (de Monge) representation, and the second applies for small values of the derivatives (surfaces not too rough). The constant of proportionality, , is the surface tension.

By performing a Fourier analysis treatment, normal modes are easily found. Each contributes an energy proportional to the square of its amplitude; therefore, according to classical statistical mechanics, equipartition holds, and the mean energy of each mode will be . Surprisingly, this result leads to a divergent surface (the width of the interface is bound to diverge with its area). This divergence is nevertheless very mild: even for displacements on the order of meters the deviation of the surface is comparable to the size of the molecules. Moreover, the introduction of an external field removes the divergence: the action of gravity is sufficient to keep the width fluctuation on the order of one molecular diameter for areas larger than about 1 mm2 (Ref. 2). [1]

Related Research Articles

The beam diameter or beam width of an electromagnetic beam is the diameter along any specified line that is perpendicular to the beam axis and intersects it. Since beams typically do not have sharp edges, the diameter can be defined in many different ways. Five definitions of the beam width are in common use: D4σ, 10/90 or 20/80 knife-edge, 1/e2, FWHM, and D86. The beam width can be measured in units of length at a particular plane perpendicular to the beam axis, but it can also refer to the angular width, which is the angle subtended by the beam at the source. The angular width is also called the beam divergence.

Kinetic theory of gases Historical physical model of gases

The kinetic theory of gases is a simple, historically significant classical model of the thermodynamic behavior of gases, with which many principal concepts of thermodynamics were established. The model describes a gas as a large number of identical submicroscopic particles, all of which are in constant, rapid, random motion. Their size is assumed to be much smaller than the average distance between the particles. The particles undergo random elastic collisions between themselves and with the enclosing walls of the container. The basic version of the model describes the ideal gas, and considers no other interactions between the particles.

Gravity wave Wave in or at the interface between fluids where gravity is the main equilibrium force

In fluid dynamics, gravity waves are waves generated in a fluid medium or at the interface between two media when the force of gravity or buoyancy tries to restore equilibrium. An example of such an interface is that between the atmosphere and the ocean, which gives rise to wind waves.

The calculus of variations is a field of mathematical analysis that uses variations, which are small changes in functions and functionals, to find maxima and minima of functionals: mappings from a set of functions to the real numbers. Functionals are often expressed as definite integrals involving functions and their derivatives. Functions that maximize or minimize functionals may be found using the Euler–Lagrange equation of the calculus of variations.

In physics, Wick rotation, named after Italian physicist Gian Carlo Wick, is a method of finding a solution to a mathematical problem in Minkowski space from a solution to a related problem in Euclidean space by means of a transformation that substitutes an imaginary-number variable for a real-number variable. This transformation is also used to find solutions to problems in quantum mechanics and other areas.

In multivariate calculus, a differential or differential form is said to be exact or perfect, as contrasted with an inexact differential, if it is equal to the general differential for some differentiable function  in an orthogonal coordinate system.

A continuity equation or transport equation is an equation that describes the transport of some quantity. It is particularly simple and powerful when applied to a conserved quantity, but it can be generalized to apply to any extensive quantity. Since mass, energy, momentum, electric charge and other natural quantities are conserved under their respective appropriate conditions, a variety of physical phenomena may be described using continuity equations.

In information geometry, the Fisher information metric is a particular Riemannian metric which can be defined on a smooth statistical manifold, i.e., a smooth manifold whose points are probability measures defined on a common probability space. It can be used to calculate the informational difference between measurements.

Capillary wave Wave on the surface of a fluid, dominated by surface tension

A capillary wave is a wave traveling along the phase boundary of a fluid, whose dynamics and phase velocity are dominated by the effects of surface tension.

The Nambu–Goto action is the simplest invariant action in bosonic string theory, and is also used in other theories that investigate string-like objects. It is the starting point of the analysis of zero-thickness string behavior, using the principles of Lagrangian mechanics. Just as the action for a free point particle is proportional to its proper time — i.e., the "length" of its world-line — a relativistic string's action is proportional to the area of the sheet which the string traces as it travels through spacetime.

In mathematical statistics, the Kullback–Leibler divergence, denoted , is a type of statistical distance: a measure of how one probability distribution P is different from a second, reference probability distribution Q. A simple interpretation of the KL divergence of P from Q is the expected excess surprise from using Q as a model when the actual distribution is P. While it is a distance, it is not a metric, the most familiar type of distance: it is not symmetric in the two distributions, and does not satisfy the triangle inequality. Instead, in terms of information geometry, it is a type of divergence, a generalization of squared distance, and for certain classes of distributions, it satisfies a generalized Pythagorean theorem.

In general relativity, the Gibbons–Hawking–York boundary term is a term that needs to be added to the Einstein–Hilbert action when the underlying spacetime manifold has a boundary.

In quantum field theory and statistical mechanics, the Mermin–Wagner theorem states that continuous symmetries cannot be spontaneously broken at finite temperature in systems with sufficiently short-range interactions in dimensions d ≤ 2. Intuitively, this means that long-range fluctuations can be created with little energy cost and since they increase the entropy they are favored.

Shallow water equations Set of partial differential equations that describe the flow below a pressure surface in a fluid

The shallow-water equations are a set of hyperbolic partial differential equations that describe the flow below a pressure surface in a fluid. The shallow-water equations in unidirectional form are also called Saint-Venant equations, after Adhémar Jean Claude Barré de Saint-Venant.

Contact mechanics Study of the deformation of solids that touch each other

Contact mechanics is the study of the deformation of solids that touch each other at one or more points. A central distinction in contact mechanics is between stresses acting perpendicular to the contacting bodies' surfaces and frictional stresses acting tangentially between the surfaces. This page focuses mainly on the normal direction, i.e. on frictionless contact mechanics. Frictional contact mechanics is discussed separately. Normal stresses are caused by applied forces and by the adhesion present on surfaces in close contact even if they are clean and dry.

The intent of this article is to highlight the important points of the derivation of the Navier–Stokes equations as well as its application and formulation for different families of fluids.

The Cauchy momentum equation is a vector partial differential equation put forth by Cauchy that describes the non-relativistic momentum transport in any continuum.

In fluid dynamics, Airy wave theory gives a linearised description of the propagation of gravity waves on the surface of a homogeneous fluid layer. The theory assumes that the fluid layer has a uniform mean depth, and that the fluid flow is inviscid, incompressible and irrotational. This theory was first published, in correct form, by George Biddell Airy in the 19th century.

Radiation stress Term in physical oceanography

In fluid dynamics, the radiation stress is the depth-integrated – and thereafter phase-averaged – excess momentum flux caused by the presence of the surface gravity waves, which is exerted on the mean flow. The radiation stresses behave as a second-order tensor.

In mathematics, the Łukaszyk–Karmowski metric is a function defining a distance between two random variables or two random vectors. This function is not a metric as it does not satisfy the identity of indiscernibles condition of the metric, that is for two identical arguments its value is greater than zero. The concept is named after Szymon Łukaszyk and Wojciech Karmowski.

References

  1. J.S. Rowlinson and B. Widom "Molecular theory of capillarity" 2002

See also