Ti-6Al-4V (UNS designation R56400), also sometimes called TC4, Ti64, [1] or ASTM Grade 5, is an alpha-beta titanium alloy with a high specific strength and excellent corrosion resistance. It is one of the most commonly used titanium alloys and is applied in a wide range of applications where low density and excellent corrosion resistance are necessary such as e.g. aerospace industry and biomechanical applications (implants and prostheses).
Studies of titanium alloys used in armors began in the 1950s at the Watertown Arsenal, which later became a part of the Army Research Laboratory. [2] [3]
A 1948 graduate of MIT, Stanley Abkowitz (1927-2017) was a pioneer in the titanium industry and is credited for the invention of the Ti-6Al-4V during his time at the US Army’s Watertown Arsenal Laboratory in the early 1950s. [4]
Titanium/Aluminum/Vanadium alloy was hailed as a major breakthrough with strategic military significance. It is the most commercially successful titanium alloy and is still in use today, having shaped numerous industrial and commercial applications. [5]
Increased use of titanium alloys as biomaterials is occurring due to their lower modulus, superior biocompatibility and enhanced corrosion resistance when compared to more conventional stainless steels and cobalt-based alloys. [6] These attractive properties were a driving force for the early introduction of α (cpTi) and α+β (Ti—6Al—4V) alloys as well as for the more recent development of new Ti-alloy compositions and orthopaedic metastable b titanium alloys. The latter possess enhanced biocompatibility, reduced elastic modulus, and superior strain-controlled and notch fatigue resistance. [7] However, the poor shear strength and wear resistance of titanium alloys have nevertheless limited their biomedical use. Although the wear resistance of b-Ti alloys has shown some improvement when compared to a#b alloys, the ultimate utility of orthopaedic titanium alloys as wear components will require a more complete fundamental understanding of the wear mechanisms involved.
(in wt. %) [8]
V | Al | Fe | O | C | N | H | Y | Ti | Remainder Each | Remainder Total | |
---|---|---|---|---|---|---|---|---|---|---|---|
Min | 3.5 | 5.5 | -- | -- | -- | -- | -- | -- | -- | -- | -- |
Max | 4.5 | 6.75 | .3 | .2 | .08 | .05 | .015 | .005 | Balance | .1 | .3 |
Ti-6Al-4V titanium alloy commonly exists in alpha, with hcp crystal structure, (SG : P63/mmc) and beta, with bcc crystal structure, (SG : Im-3m) phases. While mechanical properties are a function of the heat treatment condition of the alloy and can vary based upon properties, typical property ranges for well-processed Ti-6Al-4V are shown below. [9] [10] [11] Aluminum stabilizes the alpha phase, while vanadium stabilizes the beta phase. [12] [13]
Density | Young's Modulus | Shear Modulus | Bulk Modulus | Poisson's Ratio | Tensile Yield Stress | Tensile Ultimate Stress | Hardness | Uniform Elongation | |
---|---|---|---|---|---|---|---|---|---|
Min | 4.429 g/cm3 (0.160 lb/cu in) | 104 GPa (15.1×10 6 psi) | 40 GPa (5.8×10 6 psi) | 96.8 GPa (14.0×10 6 psi) | 0.31 | 880 MPa (128,000 psi) | 900 MPa (130,000 psi) | 36 Rockwell C (Typical) | 5% |
Max | 4.512 g/cm3 (0.163 lb/cu in) | 113 GPa (16.4×10 6 psi) | 45 GPa (6.5×10 6 psi) | 153 GPa (22.2×10 6 psi) | 0.37 | 920 MPa (133,000 psi) | 950 MPa (138,000 psi) | -- | 18% |
Ti-6Al-4V has a very low thermal conductivity at room temperature of 6.7 to 7.5 W/m·K, [14] [15] which contributes to its relatively poor machinability. [15]
The alloy is vulnerable to cold dwell fatigue. [16] [17]
Ti-6Al-4V is heat treated to vary the amounts of and microstructure of and phases in the alloy. The microstructure will vary significantly depending on the exact heat treatment and method of processing. Three common heat treatment processes are mill annealing, duplex annealing, and solution treating and aging. [18]
Stainless steel, also known as inox, corrosion-resistant steel (CRES) and rustless steel, is an alloy of iron that is resistant to rusting and corrosion. It contains iron with chromium and other elements such as molybdenum, carbon, nickel and nitrogen depending on its specific use and cost. Stainless steel's resistance to corrosion results from the 10.5%, or more, chromium content which forms a passive film that can protect the material and self-heal in the presence of oxygen.
Titanium is a chemical element; it has symbol Ti and atomic number 22. Found in nature only as an oxide, it can be reduced to produce a lustrous transition metal with a silver color, low density, and high strength, resistant to corrosion in sea water, aqua regia, and chlorine.
Refractory metals are a class of metals that are extraordinarily resistant to heat and wear. The expression is mostly used in the context of materials science, metallurgy and engineering. The definition of which elements belong to this group differs. The most common definition includes five elements: two of the fifth period and three of the sixth period. They all share some properties, including a melting point above 2000 °C and high hardness at room temperature. They are chemically inert and have a relatively high density. Their high melting points make powder metallurgy the method of choice for fabricating components from these metals. Some of their applications include tools to work metals at high temperatures, wire filaments, casting molds, and chemical reaction vessels in corrosive environments. Partly due to the high melting point, refractory metals are stable against creep deformation to very high temperatures.
In modern Western body piercing, a wide variety of materials are used. Some cannot be autoclaved, and others may induce allergic reactions, or harbour bacteria. Certain countries, such as those belonging to the EU, have legal regulations specifying which materials can be used in new piercings.
Inconel is a nickel-chromium-based superalloy often utilized in extreme environments where components are subjected to high temperature, pressure or mechanical loads. Inconel alloys are oxidation- and corrosion-resistant. When heated, Inconel forms a thick, stable, passivating oxide layer protecting the surface from further attack. Inconel retains strength over a wide temperature range, attractive for high-temperature applications where aluminum and steel would succumb to creep as a result of thermally-induced crystal vacancies. Inconel's high-temperature strength is developed by solid solution strengthening or precipitation hardening, depending on the alloy.
Titanium alloys are alloys that contain a mixture of titanium and other chemical elements. Such alloys have very high tensile strength and toughness. They are light in weight, have extraordinary corrosion resistance and the ability to withstand extreme temperatures. However, the high cost of processing limits their use to military applications, aircraft, spacecraft, bicycles, medical devices, jewelry, highly stressed components such as connecting rods on expensive sports cars and some premium sports equipment and consumer electronics.
Microstructure is the very small scale structure of a material, defined as the structure of a prepared surface of material as revealed by an optical microscope above 25× magnification. The microstructure of a material can strongly influence physical properties such as strength, toughness, ductility, hardness, corrosion resistance, high/low temperature behaviour or wear resistance. These properties in turn govern the application of these materials in industrial practice.
An archwire in orthodontics is a wire conforming to the alveolar or dental arch that can be used with dental braces as a source of force in correcting irregularities in the position of the teeth. An archwire can also be used to maintain existing dental positions; in this case it has a retentive purpose.
Titanium powder metallurgy (P/M) offers the possibility of creating net shape or near net shape parts without the material loss and cost associated with having to machine intricate components from wrought billet. Powders can be produced by the blended elemental technique or by pre-alloying and then consolidated by metal injection moulding, hot isostatic pressing, direct powder rolling or laser engineered net shaping.
Dr. Ramulu Mamidala is a mechanical engineering professor at University of Washington. Usually goes by the name 'Ram', or 'M.R.', he is recognized for his leadership and outstanding record in promoting collaborative education and research with industry. He is currently the director of Manufacturing Science and Technology Laboratory (MSTL) at Mechanical Engineering Department, University of Washington. He has designed and developed manufacturing methods for a wide range of systems, from the B2 bomber to the Boeing 787. Additionally, in collaboration with industry, he established and directed two interdisciplinary graduate educational programs in engineering and management and a certificate program in composites tooling and manufacturing. His exemplary collaborative efforts motivated working engineers to pursue doctoral studies and he is a leader in using emerging technologies in distance education to reach non-traditional students.
An aluminium alloy (UK/IUPAC) or aluminum alloy is an alloy in which aluminium (Al) is the predominant metal. The typical alloying elements are copper, magnesium, manganese, silicon, tin, nickel and zinc. There are two principal classifications, namely casting alloys and wrought alloys, both of which are further subdivided into the categories heat-treatable and non-heat-treatable. About 85% of aluminium is used for wrought products, for example rolled plate, foils and extrusions. Cast aluminium alloys yield cost-effective products due to the low melting point, although they generally have lower tensile strengths than wrought alloys. The most important cast aluminium alloy system is Al–Si, where the high levels of silicon (4–13%) contribute to give good casting characteristics. Aluminium alloys are widely used in engineering structures and components where light weight or corrosion resistance is required.
6061 aluminium alloy is a precipitation-hardened aluminium alloy, containing magnesium and silicon as its major alloying elements. Originally called "Alloy 61S", it was developed in 1935. It has good mechanical properties, exhibits good weldability, and is very commonly extruded. It is one of the most common alloys of aluminium for general-purpose use.
7075 aluminium alloy (AA7075) is an aluminium alloy with zinc as the primary alloying element. It has excellent mechanical properties and exhibits good ductility, high strength, toughness, and good resistance to fatigue. It is more susceptible to embrittlement than many other aluminium alloys because of microsegregation, but has significantly better corrosion resistance than the alloys from the 2000 series. It is one of the most commonly used aluminium alloys for highly stressed structural applications and has been extensively used in aircraft structural parts.
Titanium Beta C refers to Ti Beta-C, a trademark for an alloy of titanium originally filed by RTI International. It is a metastable "beta alloy" which was originally developed in the 1960s; Ti-3Al-8V-6Cr-4Mo-4Zr, nominally 3% aluminum, 8% vanadium, 6% chromium, 4% molybdenum, 4% zirconium and balance (75%): titanium.
An Electrochemical Fatigue Crack Sensor (EFCS) is a type of low cost electrochemical nondestructive dynamic testing method used primarily in the aerospace and transportation infrastructure industries. The method is used to locate surface-breaking and slightly subsurface defects in all metallic materials. In bridge structures, EFCS is used at known fatigue susceptible areas, such as sharp-angled coped beams, stringer to beam attachments, and the toe of welds. This dynamic testing can be a form of short term or long-term monitoring, as long as the structure is undergoing dynamic cyclic loading.
Ti-6Al-2Sn-4Zr-2Mo, also known as Ti 6-2-4-2, is a near alpha titanium alloy known for its high strength and excellent corrosion resistance. It is often used in the aerospace industry for creating high-temperature jet engines and the automotive industry to create high performance automotive valves.
Inconel Alloy 625 is a nickel-based superalloy that possesses high strength properties and resistance to elevated temperatures. It also demonstrates remarkable protection against corrosion and oxidation. Its ability to withstand high stress and a wide range of temperatures, both in and out of water, as well as being able to resist corrosion while being exposed to highly acidic environments makes it a fitting choice for nuclear and marine applications.
Ti-6Al-7Nb is an alpha-beta titanium alloy first synthesized in 1977 containing 6% aluminum and 7% niobium. It features high strength and has similar properties as the cytotoxic vanadium containing alloy Ti-6Al-4V. Ti-6Al-7Nb is used as a material for hip prostheses.
Titanium adhesive bonding is an engineering process used in the aerospace industry, medical-device manufacture and elsewhere. Titanium alloy is often used in medical and military applications because of its strength, weight, and corrosion resistance characteristics. In implantable medical devices, titanium is used because of its biocompatibility and its passive, stable oxide layer. Also, titanium allergies are rare and in those cases mitigations like Parylene coating are used. In the aerospace industry titanium is often bonded to save cost, touch times, and the need for mechanical fasteners. In the past, Russian submarines' hulls were completely made of titanium because the non-magnetic nature of the material went undetected by the defense technology at that time. Bonding adhesive to titanium requires preparing the surface beforehand, and there is not a single solution for all applications. For example, etchant and chemical methods are not biocompatible and cannot be employed when the device will come into contact with blood and tissue. Mechanical surface roughness techniques like sanding and laser roughening may make the surface brittle and create micro-hardness regions that would not be suitable for cyclic loading found in military applications. Air oxidation at high temperatures will produce a crystalline oxide layer at a lower investment cost, but the increased temperatures can deform precision parts. The type of adhesive, thermosetting or thermoplastic, and curing methods are also factors in titanium bonding because of the adhesive's interaction with the treated oxide layer. Surface treatments can also be combined. For example, a grit blast process can be followed by a chemical etch and a primer application.
Aluminium 7050 alloy is a heat treatable alloy. It has high toughness, high strength. It has high stress corrosion cracking resistance. It has electric conductivity of value having 40 percent of copper. 7050 aluminium is known as a commercial aerospace alloy.