Violarite | |
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General | |
Category | Sulfide mineral Thiospinel group Spinel structural group |
Formula (repeating unit) | (Fe2+Ni23+S4) |
IMA symbol | Vio [1] |
Strunz classification | 2.DA.05 |
Crystal system | Isometric |
Crystal class | Hexoctahedral (m3m) H-M symbol: (4/m 3 2/m) |
Space group | Fd3m |
Unit cell | a = 9.46 Å; Z = 8 |
Identification | |
References | [2] [3] [4] |
Violarite (Fe 2+ Ni 23+ S 4) is a supergene sulfide mineral associated with the weathering and oxidation of primary pentlandite nickel sulfide ore minerals.
Violarite crystallises in the isometric system, with a hardness of 4.5 to 5.5 and a specific gravity of about 4, is dark violet grey to copper-red, often with verdigris and patina from associated copper and arsenic sulfides, and is typically in amorphous to massive infill of lower saprolite ultramafic lithologies.
Violarite has a characteristic violet colour, hence the name from the Latin 'violaris' alluding to its colour especially when viewed in polished section under a microscope.
Violarite is formed by oxidisation of primary sulfide assemblages in nickel sulfide mineralisation. The process of formation involves oxidation of Ni2+ and Fe2+ which is contained within the primary pentlandite-pyrrhotite-pyrite assemblage.
Violarite is produced at the expense of both pentlandite and pyrrhotite, via the following basic reaction;
Pentlandite + Pyrrhotite --> Violarite + Acid
Violarite is also reported to be produced in low-temperature metamorphism of primary sulfides, though this is an unusual paragenetic indicator for the mineral.
Continued oxidation of violarite leads to replacement by goethite and formation of a gossanous boxwork, with nickel tending to remain as impurities within the goethite or haematite, or rarely as carbonate minerals.
Violarite is reported widely from the oxidised regolith above primary nickel sulfide ore systems worldwide. It is of particular note from the Mount Keith dunite body, Western Australia, where it forms an important ore mineral.
It is also reported from open cast mines around the Kambalda Dome, and Widgiemooltha Dome, in association with polydymite, gaspeite, widgiemoolthalite and hellyerite, among other supergene nickel minerals.
Violarite is an important transitional ore in many nickel sulfide mines, as it has increased nickel tenor (Ni% as a total of sulfide) and occupies a position within the mineralised profile where it must be extracted to pay for development down to the most valuable fresh mineralisation.
Violarite mineralisation requires different metallurgy to primary nickel sulfides, due to the different nature of its gangue and its flotation properties. This may require additional treatment and processing, so in some cases low-grade violarite mineralisation is considered refractory ore.
Ore is natural rock or sediment that contains one or more valuable minerals, typically containing metals, that can be mined, treated and sold at a profit. Ore is extracted from the earth through mining and treated or refined, often via smelting, to extract the valuable metals or minerals. The grade of ore refers to the concentration of the desired material it contains. The value of the metals or minerals a rock contains must be weighed against the cost of extraction to determine whether it is of sufficiently high grade to be worth mining, and is therefore considered an ore.
Pentlandite is an iron–nickel sulfide with the chemical formula (Fe,Ni)9S8. Pentlandite has a narrow variation range in Ni:Fe but it is usually described as having a Ni:Fe of 1:1. It also contains minor cobalt, usually at low levels as a fraction of weight.
Nickeline or niccolite is a mineral consisting primarily of nickel arsenide (NiAs). The naturally-occurring mineral contains roughly 43.9% nickel and 56.1% arsenic by mass, but composition of the mineral may vary slightly.
Copper extraction refers to the methods used to obtain copper from its ores. The conversion of copper ores consists of a series of physical, chemical and electrochemical processes. Methods have evolved and vary with country depending on the ore source, local environmental regulations, and other factors.
Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S. It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content increases, and troilite is non-magnetic.
Trevorite is a rare nickel iron oxide mineral belonging to the spinel group. It has the chemical formula NiFe3+2O4. It is a black mineral with the typical spinel properties of crystallising in the cubic system, black streaked, infusible and insoluble in most acids.
Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined.
Kambalda type komatiitic nickel ore deposits are a class of magmatic iron-nickel-copper-platinum-group element ore deposit in which the physical processes of komatiite volcanology serve to deposit, concentrate and enrich a Fe-Ni-Cu-(PGE) sulfide melt within the lava flow environment of an erupting komatiite volcano.
In ore deposit geology, supergene processes or enrichment are those that occur relatively near the surface as opposed to deep hypogene processes. Supergene processes include the predominance of meteoric water circulation (i.e. water derived from precipitation) with concomitant oxidation and chemical weathering. The descending meteoric waters oxidize the primary (hypogene) sulfide ore minerals and redistribute the metallic ore elements. Supergene enrichment occurs at the base of the oxidized portion of an ore deposit. Metals that have been leached from the oxidized ore are carried downward by percolating groundwater, and react with hypogene sulfides at the supergene-hypogene boundary. The reaction produces secondary sulfides with metal contents higher than those of the primary ore. This is particularly noted in copper ore deposits where the copper sulfide minerals chalcocite (Cu2S), covellite (CuS), digenite (Cu18S10), and djurleite (Cu31S16) are deposited by the descending surface waters.
Gaspéite, a very rare nickel carbonate mineral, with the formula (Ni,Fe,Mg)CO3, is named for the place it was first described, in the Gaspé Peninsula, Québec, Canada.
Kambaldaite, NaNi4(CO3)3(OH)3·3H2O, is an extremely rare hydrated sodium nickel carbonate mineral described from gossanous material associated with Kambalda type komatiitic nickel ore deposits at Kambalda, Western Australia, and Widgie Townsite nickel gossan, Widgiemooltha, Western Australia.
Polydymite, Ni2+Ni23+S4, is a supergene thiospinel sulfide mineral associated with the weathering of primary pentlandite nickel sulfide.
In geology, a redox buffer is an assemblage of minerals or compounds that constrains oxygen fugacity as a function of temperature. Knowledge of the redox conditions (or equivalently, oxygen fugacities) at which a rock forms and evolves can be important for interpreting the rock history. Iron, sulfur, and manganese are three of the relatively abundant elements in the Earth's crust that occur in more than one oxidation state. For instance, iron, the fourth most abundant element in the crust, exists as native iron, ferrous iron (Fe2+), and ferric iron (Fe3+). The redox state of a rock affects the relative proportions of the oxidation states of these elements and hence may determine both the minerals present and their compositions. If a rock contains pure minerals that constitute a redox buffer, then the oxygen fugacity of equilibration is defined by one of the curves in the accompanying fugacity-temperature diagram.
The Widgiemooltha Komatiite is a formation of komatiite in the Yilgarn Craton of Western Australia.
Mackinawite is an iron nickel sulfide mineral with the chemical formula (Fe,Ni)
1+xS. The mineral crystallizes in the tetragonal crystal system and has been described as a distorted, close packed, cubic array of S atoms with some of the gaps filled with Fe. Mackinawite occurs as opaque bronze to grey-white tabular crystals and anhedral masses. It has a Mohs hardness of 2.5 and a specific gravity of 4.17. It was first described in 1962 for an occurrence in the Mackinaw mine, Snohomish County, Washington for which it was named.
The Browns polymetallic ore deposit is a large ore deposit located at Mount Fitch, near Batchelor, 64 kilometres south of Darwin, Northern Territory, Australia.
Cubanite is a copper iron sulfide mineral that commonly occurs as a minor alteration mineral in magmatic sulfide deposits. It has the chemical formula CuFe2S3 and when found, it has a bronze to brass-yellow appearance. On the Mohs hardness scale, cubanite falls between 3.5 and 4 and has a orthorhombic crystal system. Cubanite is chemically similar to chalcopyrite, however it is the less common copper iron sulfide mineral due to crystallization requirements.
Iron oxide copper gold ore deposits (IOCG) are important and highly valuable concentrations of copper, gold and uranium ores hosted within iron oxide dominant gangue assemblages which share a common genetic origin.
Saprolite is a chemically weathered rock. Saprolites form in the lower zones of soil profiles and represent deep weathering of the bedrock surface. In most outcrops its color comes from ferric compounds. Deeply weathered profiles are widespread on the continental landmasses between latitudes 35°N and 35°S.
Millerite is a nickel sulfide mineral, NiS. It is brassy in colour and has an acicular habit, often forming radiating masses and furry aggregates. It can be distinguished from pentlandite by crystal habit, its duller colour, and general lack of association with pyrite or pyrrhotite.