Water vapor windows are wavelengths of infrared light that have little absorption by water vapor in Earth's atmosphere. Because of this weak absorption, these wavelengths are allowed to reach the Earth's surface barring effects from other atmospheric components. This process is highly impacted by greenhouse gases because of the effective emission temperature. The water vapor continuum and greenhouse gases are significantly linked due to water vapor's benefits on climate change.
Water vapor is a gas that absorbs many wavelengths of Infrared (IR) energy in the Earth's atmosphere, and these wavelength ranges that can partially reach the surface are coming through what is called 'water vapor windows'. [1] [2] However, these windows do not absorb all of the infrared light, and electromagnetic energy is allowed to freely flow as a result. [3] Astronomers can view the Universe with IR telescopes, called Infrared astronomy, because of these windows.
The mid-infrared window, which has a range of 800–1250 cm^-1, is one of the more significant windows, for it has a massive influence on radiation fluxes in high humidity areas of the atmosphere. [4] There has also been increased attention on the windows at 4700 cm^-1 and 6300 cm^-1 since their water vapor micro-windows confirm that uncertainties in water vapor window parameters only occur at the edges. [4] Moreover, the net incoming solar shortwave radiation and the net outgoing terrestrial longwave radiation at the top of the atmosphere keep the Earth's energy balance in check.
Water vapor windows are also impacted by greenhouse gases since the water cycle is greatly accelerated due to these gases. The global averaged value of emitted, longwave radiation is 238.5 Wm^-2. [5] One may get the effective emission temperature of the globe by assuming that the Earth-atmosphere system radiates as a blackbody in accordance with the Stefan-Boltzmann equation of blackbody radiation. The resultant temperature is -18.7 °C. Compared to +14.5 °C, the average worldwide temperature of the Earth's surface is 33 °C cooler. [5] Thus, the Earth's surface is up to 33 °C warmer than it would be without the atmosphere. Moreover, the observation of longwave radiation demonstrates that the greenhouse effect exists in the Earth's atmosphere. These windows also allow orbiting satellites to measure the IR energy leaving the planet, the SSTs, and other important matters. See Electromagnetic absorption by water: Atmospheric effects .
Water vapor absorbing these wavelengths of IR energy is mainly attributed to water being a polar molecule. Water's polarity allows it to absorb and release radiation at far, near and mid-infrared wavelengths. [6] The polarity also largely impacts how water interacts with nature, for it allows complexes of water, such as the water dimer. [6]
Being one of the planet's most significant gases in the atmosphere, water vapor is important to study due to its benefits to climate change. Water vapor absorption mostly occurs in what is called the water vapor continuum, which is a combination of bands and windows that heavily influence radiation in the atmosphere. This continuum has two parts, which are the self-continuum and the foreign continuum. [7] The self-continuum has a negative dependence on temperature, and the self-continuum is significantly stronger at the edges of the windows. [7]
These windows were originally discovered by John Tyndall. [8] He disocvered that most of the infrared coming from the Universe is being blocked and then absorbed by water vapor and other greenhouse gases in the Earth's atmosphere.
The greenhouse effect occurs when greenhouse gases in a planet's atmosphere insulate the planet from losing heat to space, raising its surface temperature. Surface heating can happen from an internal heat source as in the case of Jupiter, or from its host star as in the case of the Earth. In the case of Earth, the Sun emits shortwave radiation (sunlight) that passes through greenhouse gases to heat the Earth's surface. In response, the Earth's surface emits longwave radiation that is mostly absorbed by greenhouse gases. The absorption of longwave radiation prevents it from reaching space, reducing the rate at which the Earth can cool off.
Global Warming Potential (GWP) is an index to measure of how much infrared thermal radiation a greenhouse gas would absorb over a given time frame after it has been added to the atmosphere. The GWP makes different greenhouse gases comparable with regards to their "effectiveness in causing radiative forcing". It is expressed as a multiple of the radiation that would be absorbed by the same mass of added carbon dioxide, which is taken as a reference gas. Therefore, the GWP has a value of 1 for CO2. For other gases it depends on how strongly the gas absorbs infrared thermal radiation, how quickly the gas leaves the atmosphere, and the time frame being considered.
Infrared is electromagnetic radiation (EMR) with wavelengths longer than that of visible light but shorter than microwaves. The infrared spectral band begins with waves that are just longer than those of red light, the longest waves in the visible spectrum, so IR is invisible to the human eye. IR is generally understood to include wavelengths from around 750 nm to 1000 μm. IR is commonly divided between longer-wavelength thermal IR, emitted from terrestrial sources, and shorter-wavelength IR or near-IR, part of the solar spectrum. Longer IR wavelengths (30–100 μm) are sometimes included as part of the terahertz radiation band. Almost all black-body radiation from objects near room temperature is in the IR band. As a form of electromagnetic radiation, IR carries energy and momentum, exerts radiation pressure, and has properties corresponding to both those of a wave and of a particle, the photon.
Numerical climate models are mathematical models that can simulate the interactions of important drivers of climate. These drivers are the atmosphere, oceans, land surface and ice. Scientists use climate models to study the dynamics of the climate system and to make projections of future climate and of climate change. Climate models can also be qualitative models and contain narratives, largely descriptive, of possible futures.
Water vapor, water vapour or aqueous vapor is the gaseous phase of water. It is one state of water within the hydrosphere. Water vapor can be produced from the evaporation or boiling of liquid water or from the sublimation of ice. Water vapor is transparent, like most constituents of the atmosphere. Under typical atmospheric conditions, water vapor is continuously generated by evaporation and removed by condensation. It is less dense than most of the other constituents of air and triggers convection currents that can lead to clouds and fog.
Thermal radiation is electromagnetic radiation emitted by the thermal motion of particles in matter. Thermal radiation transmits as an electromagnetic wave through both matter and vacuum. When matter absorbs thermal radiation its temperature will tend to rise. All matter with a temperature greater than absolute zero emits thermal radiation. The emission of energy arises from a combination of electronic, molecular, and lattice oscillations in a material. Kinetic energy is converted to electromagnetism due to charge-acceleration or dipole oscillation. At room temperature, most of the emission is in the infrared (IR) spectrum. Thermal radiation is one of the fundamental mechanisms of heat transfer, along with conduction and convection.
A microwave radiometer (MWR) is a radiometer that measures energy emitted at one millimeter-to-metre wavelengths (frequencies of 0.3–300 GHz) known as microwaves. Microwave radiometers are very sensitive receivers designed to measure thermally-emitted electromagnetic radiation. They are usually equipped with multiple receiving channels to derive the characteristic emission spectrum of planetary atmospheres, surfaces or extraterrestrial objects. Microwave radiometers are utilized in a variety of environmental and engineering applications, including remote sensing, weather forecasting, climate monitoring, radio astronomy and radio propagation studies.
Black-body radiation is the thermal electromagnetic radiation within, or surrounding, a body in thermodynamic equilibrium with its environment, emitted by a black body. It has a specific, continuous spectrum of wavelengths, inversely related to intensity, that depend only on the body's temperature, which is assumed, for the sake of calculations and theory, to be uniform and constant.
The emissivity of the surface of a material is its effectiveness in emitting energy as thermal radiation. Thermal radiation is electromagnetic radiation that most commonly includes both visible radiation (light) and infrared radiation, which is not visible to human eyes. A portion of the thermal radiation from very hot objects is easily visible to the eye.
Earth's energy budget accounts for the balance between the energy that Earth receives from the Sun and the energy the Earth loses back into outer space. Smaller energy sources, such as Earth's internal heat, are taken into consideration, but make a tiny contribution compared to solar energy. The energy budget also accounts for how energy moves through the climate system. The Sun heats the equatorial tropics more than the polar regions. Therefore, the amount of solar irradiance received by a certain region is unevenly distributed. As the energy seeks equilibrium across the planet, it drives interactions in Earth's climate system, i.e., Earth's water, ice, atmosphere, rocky crust, and all living things. The result is Earth's climate.
In physics, absorption of electromagnetic radiation is how matter takes up a photon's energy — and so transforms electromagnetic energy into internal energy of the absorber.
The infrared atmospheric window refers to a region of the infrared spectrum where there is relatively little absorption of terrestrial thermal radiation by atmospheric gases. The window plays an important role in the atmospheric greenhouse effect by maintaining the balance between incoming solar radiation and outgoing IR to space. In the Earth's atmosphere this window is roughly the region between 8 and 14 μm although it can be narrowed or closed at times and places of high humidity because of the strong absorption in the water vapor continuum or because of blocking by clouds. It covers a substantial part of the spectrum from surface thermal emission which starts at roughly 5 μm. Principally it is a large gap in the absorption spectrum of water vapor. Carbon dioxide plays an important role in setting the boundary at the long wavelength end. Ozone partly blocks transmission in the middle of the window.
A runaway greenhouse effect will occur when a planet's atmosphere contains greenhouse gas in an amount sufficient to block thermal radiation from leaving the planet, preventing the planet from cooling and from having liquid water on its surface. A runaway version of the greenhouse effect can be defined by a limit on a planet's outgoing longwave radiation which is asymptotically reached due to higher surface temperatures evaporating water into the atmosphere, increasing its optical depth. This positive feedback means the planet cannot cool down through longwave radiation and continues to heat up until it can radiate outside of the absorption bands of the water vapour.
The anti-greenhouse effect is a process that occurs when energy from a celestial object's sun is absorbed or scattered by the object's upper atmosphere, preventing that energy from reaching the surface, which results in surface cooling – the opposite of the greenhouse effect. In an ideal case where the upper atmosphere absorbs all sunlight and is nearly transparent to infrared (heat) energy from the surface, the surface temperature would be reduced by 16%, which is a significant amount of cooling.
In climate science, longwave radiation (LWR) is electromagnetic thermal radiation emitted by Earth's surface, atmosphere, and clouds. It may also be referred to as terrestrial radiation. This radiation is in the infrared portion of the spectrum, but is distinct from the shortwave (SW) near-infrared radiation found in sunlight.
The absorption of electromagnetic radiation by water depends on the state of the water.
An atmospheric window is a region of the electromagnetic spectrum that can pass through the atmosphere of Earth. The optical, infrared and radio windows comprise the three main atmospheric windows. The windows provide direct channels for Earth's surface to receive electromagnetic energy from the Sun, and for thermal radiation from the surface to leave to space. Atmospheric windows are useful for astronomy, remote sensing, telecommunications and other science and technology applications.
The temperatures of a planet's surface and atmosphere are governed by a delicate balancing of their energy flows. The idealized greenhouse model is based on the fact that certain gases in the Earth's atmosphere, including carbon dioxide and water vapour, are transparent to the high-frequency solar radiation, but are much more opaque to the lower frequency infrared radiation leaving Earth's surface. Thus heat is easily let in, but is partially trapped by these gases as it tries to leave. Rather than get hotter and hotter, Kirchhoff's law of thermal radiation says that the gases of the atmosphere also have to re-emit the infrared energy that they absorb, and they do so, also at long infrared wavelengths, both upwards into space as well as downwards back towards the Earth's surface. In the long-term, the planet's thermal inertia is surmounted and a new thermal equilibrium is reached when all energy arriving on the planet is leaving again at the same rate. In this steady-state model, the greenhouse gases cause the surface of the planet to be warmer than it would be without them, in order for a balanced amount of heat energy to finally be radiated out into space from the top of the atmosphere.
Greenhouse gases (GHGs) are the gases in the atmosphere that raise the surface temperature of planets such as the Earth. What distinguishes them from other gases is that they absorb the wavelengths of radiation that a planet emits, resulting in the greenhouse effect. The Earth is warmed by sunlight, causing its surface to radiate heat, which is then mostly absorbed by greenhouse gases. Without greenhouse gases in the atmosphere, the average temperature of Earth's surface would be about −18 °C (0 °F), rather than the present average of 15 °C (59 °F).
In the study of heat transfer, Schwarzschild's equation is used to calculate radiative transfer through a medium in local thermodynamic equilibrium that both absorbs and emits radiation.